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Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed… Read more
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Contributors
Chapter One. Homogeneous Organometallic Chemistry of Methane
1 Introduction
2 Inspiration: The Early Days of Hydrocarbon Activation
3 Oxidative Addition
4 σ-Bond Metathesis
5 1,2-Addition
6 Metalloradicals
7 1,3-Addition
8 Electrophilic Carbene Insertion
9 Conclusions
References
Chapter Two. Supramolecular Self-assembly of Transition Metal Carbonyl Molecules Through M–CO(Lone Pair)…π(Arene) Interactions
1 Introduction
2 Data Mining
3 Supramolecular Aggregation Based on M–CO(Lone Pair)…π(Arene) Interactions
4 Thio- and Selenocarbonyl Analogues
5 Strength and Correlations
6 Conclusions and Outlook
References
Chapter Three. Metallabenzenes and Metallabenzenoids
1 Introduction
2 Synthetic Routes to Metallabenzenes and Metallabenzenoids
3 The Chemistry of Metallabenzenes and Metallabenzenoids
4 Structural and Spectroscopic Studies
5 Bonding in Metallabenzenes
6 Concluding Remarks
References
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