Advances in Alicyclic Chemistry
- 1st Edition, Volume 3 - November 14, 2013
- Imprint: Academic Press
- Editors: Harold Hart, G. J. Karabatsos
- Language: English
- Paperback ISBN:9 7 8 - 1 - 4 8 3 2 - 0 1 2 6 - 9
- eBook ISBN:9 7 8 - 1 - 4 8 3 2 - 1 4 6 9 - 6
Advances in Alicyclic Chemistry, Volume 3 covers papers about the advances in alicyclic chemistry. The book presents a paper on the synthetic application of carbocyclic ring… Read more
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Advances in Alicyclic Chemistry, Volume 3 covers papers about the advances in alicyclic chemistry. The book presents a paper on the synthetic application of carbocyclic ring contraction reaction, with topics about rearrangements via carbonium ions, ring contractions via anionic intermediates or divalent carbon intermediates, photochemical ring contractions, and thermal rearrangements. The text also provides papers on the conformational analysis of cyclohexane and cyclohexene derivatives and on the review and analysis of modern theory about eliminations from cycloaliphatic derivatives. Chemists will find the book invaluable.
List of Contributors
Preface
Contents of Previous Volumes
Carbocyclic Ring Contraction Reactions
Introduction
I. Rearrangements via Carbonium Ions
II. Ring Contractions via Anionic Intermediates
III. Photochemical Ring Contractions
IV. Thermal Rearrangements
V. Ring Contractions Involving Divalent Carbon Intermediates
VI. Miscellaneous Rearrangements
Conformational Preferences in Cyclohexanes and Cyclohexenes
I. Introduction
II. Evaluation of Methods
III. Enthalpy and Entropy Changes for the Axial ⇌ Equatorial Equilibrium in Monosubstituted Cyclohexanes
IV. A Values
V. Disubstituted Cyclohexanes and the Additivity of A Values
VI. Cyclohexene Derivatives
Eliminations from Alicyclic Derivatives
Introduction
I. Cyclopropane Derivatives
II. Cyclobutane Derivatives
III. Cyclopentane Derivatives
IV. Cyclohexane Derivatives
V. Cycloheptane Derivatives
VI. Medium-Sized and Large Ring Compounds
VII. Bridged Ring Compounds
Author Index
Subject Index
- Edition: 1
- Volume: 3
- Published: November 14, 2013
- Imprint: Academic Press
- Language: English
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