The Thermodynamics of Phase and Reaction Equilibria
- 2nd Edition - June 17, 2021
- Imprint: Elsevier
- Author: Ismail Tosun
- Language: English
- Hardback ISBN:9 7 8 - 0 - 1 2 - 8 2 0 5 3 0 - 3
- eBook ISBN:9 7 8 - 0 - 1 2 - 8 2 0 5 3 1 - 0
The Thermodynamics of Phase and Reaction Equilibria, Second Edition, provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g., partia… Read more
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Request a sales quoteThe Thermodynamics of Phase and Reaction Equilibria, Second Edition, provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g., partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. Available computational software has made it possible for students to tackle realistic and challenging problems from industry. The second edition incorporates phase equilibrium problems dealing with nonideal mixtures containing more than two components and chemical reaction equilibrium problems involving multiple reactions. Computations are carried out with the help of Mathcad®.
- Clear layout, coherent and logical organization of the content, and presentation suitable for self-study
- Provides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients
- All chapters have been updated primarily through new examples
- Includes many well-organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving
- Provides Mathcad worksheets and subroutines
- Includes a new chapter linking thermodynamics with reaction engineering
- A complete Instructor’s Solutions Manual is available as a textbook resource
Upper undergraduate and graduate students as well as researchers from different disciplines. Chemical, Environmental, Petroleum, and Metallurgical Engineering Departments; Departments of Chemistry, Biotechnology, Food Science and Technology, and Materials Science
- Cover image
- Title page
- Table of Contents
- Copyright
- Dedication
- Preface
- Preface to the first edition
- Notation
- Chapter 1: Review of the first and second laws of thermodynamics
- Abstract
- 1.1. Definitions
- 1.2. Concepts of the “abstract world” of thermodynamics
- 1.3. Work
- 1.4. Paths followed during a process
- 1.5. The first law of thermodynamics
- 1.6. The second law of thermodynamics
- 1.7. Equation of state
- 1.8. Heat capacity
- References
- Chapter 2: Thermodynamic property relations
- Abstract
- 2.1. Work functions
- 2.2. Fundamental equations
- 2.3. Differential changes in internal energy, enthalpy, and entropy
- 2.4. Relationship between partial derivatives
- 2.5. Coefficient of thermal expansion and isothermal compressibility
- 2.6. Relationship between heat capacities
- Problems
- References
- Chapter 3: Pressure–volume–temperature properties of pure substances
- Abstract
- 3.1. Compressibility factor
- 3.2. Virial equation of state
- 3.3. Cubic equations of state
- 3.4. Principle of corresponding states
- 3.5. Which equation of state to use?
- Problems
- References
- Chapter 4: Calculations of changes in internal energy, enthalpy, and entropy
- Abstract
- 4.1. Liquids and solids
- 4.2. Gases
- Problems
- Chapter 5: Equilibrium and phase stability in one-component systems
- Abstract
- 5.1. Equilibrium criteria for closed systems
- 5.2. Equilibrium criteria for open systems
- 5.3. Phase stability
- 5.4. Clapeyron equation
- 5.5. Gibbs–Helmholtz equation
- Problems
- References
- Chapter 6: Fugacity of a pure component
- Abstract
- 6.1. Fugacity and fugacity coefficient
- 6.2. Fugacity of a pure gas
- 6.3. Fugacity of a pure liquid
- 6.4. Fugacity of a pure solid
- 6.5. Change in fugacity with temperature and pressure
- Problems
- References
- Chapter 7: Thermodynamics of mixtures
- Abstract
- 7.1. Partial molar quantity
- 7.2. Property change on mixing
- 7.3. The Gibbs–Duhem equation
- Problems
- References
- Chapter 8: Equations of state for mixtures
- Abstract
- 8.1. Ideal gas mixture
- 8.2. Virial equation of state
- 8.3. Cubic equations of state
- 8.4. Calculation of ΔU, ΔH, and ΔS using the departure functions
- 8.5. Which equation of state to use?
- Problems
- References
- Chapter 9: Fugacity of a component in a mixture
- Abstract
- 9.1. Fundamental equations for a multicomponent mixture
- 9.2. Fugacity of a component in a mixture
- 9.3. Ideal mixture
- 9.4. Fugacity of a component in a gas mixture
- 9.5. Fugacity of a component in a liquid mixture
- 9.6. Change in component fugacity with temperature and pressure
- 9.7. The use of fugacity in phase equilibrium calculations
- Problems
- References
- Chapter 10: Excess mixture properties and activity coefficients
- Abstract
- 10.1. Property change on mixing for an ideal mixture
- 10.2. Excess property
- 10.3. Activity and activity coefficient
- 10.4. Binary activity coefficient models
- 10.5. Regular mixture
- 10.6. UNIFAC
- 10.7. Infinite dilution activity coefficients
- 10.8. Testing consistency of experimental data
- 10.9. Activity coefficients for multicomponent mixtures
- 10.10. Which activity coefficient model to use?
- Problems
- References
- Chapter 11: Vapor–liquid equilibrium
- Abstract
- 11.1. Principles of distillation calculations
- 11.2. Raoult's law
- 11.3. VLE calculations for ideal mixtures
- 11.4. VLE calculations for nonideal mixtures
- 11.5. Azeotrope
- 11.6. VLE calculations using equations of state
- 11.7. Gibbs energy minimization
- Problems
- References
- Chapter 12: Solubility of gases in liquids
- Abstract
- 12.1. Principles of gas absorption calculations
- 12.2. Factors affecting gas solubility
- 12.3. Applications of Henry's law
- Problems
- References
- Chapter 13: Liquid–liquid and vapor–liquid–liquid equilibrium
- Abstract
- 13.1. Mathematical preliminaries
- 13.2. Stability of liquid mixtures
- 13.3. Liquid–liquid equilibrium (LLE) calculations
- 13.4. Liquid–liquid extraction
- 13.5. Vapor–liquid–liquid equilibrium (VLLE)
- Problems
- References
- Chapter 14: Solid–liquid equilibrium
- Abstract
- 14.1. Pure solid–liquid mixture equilibrium
- 14.2. Colligative properties
- Problems
- References
- Chapter 15: Chemical reaction equilibrium
- Abstract
- 15.1. Stoichiometry of a chemical reaction
- 15.2. The law of combining proportions
- 15.3. Chemical reaction equilibrium
- 15.4. Gas phase reactions
- 15.5. Liquid phase reactions
- 15.6. Determination of independent reactions
- 15.7. Gibbs energy minimization
- 15.8. Heterogeneous reactions
- 15.9. Feasibility of a chemical reaction
- 15.10. Simultaneous phase and reaction equilibria
- Problems
- References
- Chapter 16: The conservation equations for chemical reactors
- Abstract
- 16.1. Rate of a reaction
- 16.2. Species and energy balances for reacting systems
- 16.3. Batch reactor
- 16.4. Continuous stirred tank reactor (CSTR)
- References
- Appendix A: Critical constants and acentric factors
- Compiled from
- Appendix B: Molar heat capacities of ideal gases
- Compiled from
- Appendix C: Antoine constants
- Compiled from
- Appendix D: Matrix operations using Mathcad
- D.1. Addition and subtraction
- D.2. Multiplication
- D.3. Transpose and inverse of a matrix
- D.4. Operations with column vectors
- D.5. Solution of a system of linear algebraic equations
- D.6. Reduced row echelon form of a matrix
- Appendix E: Enthalpy and Gibbs energy of formation at 298.15 K and 1 bar
- Compiled from
- Appendix F: Mathcad subroutines
- Subroutine Virial-Pure-V(T,P)
- Subroutine VDW-Pure-P(T,V)
- Subroutine RK-Pure-P(T,V)
- Subroutine SRK-Pure-P(T,V)
- Subroutine PR-Pure-P(T,V)
- Subroutine VDW-Pure-Z(T,P)
- Subroutine RK-Pure-Z(T,P)
- Subroutine SRK-Pure-Z(T,P)
- Subroutine PR-Pure-Z(T,P)
- Subroutine LK-Pure-Z
- Subroutine Virial-Pure-DF(T,P)
- Subroutine VDW-Pure-DF(T,P)
- Subroutine RK-Pure-DF(T,P)
- Subroutine SRK-Pure-DF(T,P)
- Subroutine PR-Pure-DF(T,P)
- Subroutine LK-Pure-DF
- Subroutine VDW-Pure-HVAP(T,P)
- Subroutine RK-Pure-HVAP(T,P)
- Subroutine SRK-Pure-HVAP(T,P)
- Subroutine PR-Pure-HVAP(T,P)
- Subroutine Virial-Pure-ϕV(T,P)
- Subroutine VDW-Pure-ϕV(T,P)
- Subroutine RK-Pure-ϕV(T,P)
- Subroutine SRK-Pure-ϕV(T,P)
- Subroutine PR-Pure-ϕV(T,P)
- Subroutine VDW-Pure-ϕL(T,P)
- Subroutine RK-Pure-ϕL(T,P)
- Subroutine SRK-Pure-ϕL(T,P)
- Subroutine PR-Pure-ϕL(T,P)
- Subroutine CPIGM(T)
- Subroutine Virial-Mix-B
- Subroutine PR-Mix-BIP
- Subroutine VDW-Mix-ZVmix(T,P,y)
- Subroutine RK-Mix-ZVmix(T,P,y)
- Subroutine SRK-Mix-ZVmix(T,P,y)
- Subroutine PR-Mix-ZVmix(T,P,y)
- Subroutine VDW-Mix-DFmix(T,P,y)
- Subroutine RK-Mix-DFmix(T,P,y)
- Subroutine SRK-Mix-DFmix(T,P,y)
- Subroutine PR-Mix-DFmix(T,P,y)
- Subroutine PR-Pure(Multiple)-ϕV(T,P)
- Subroutine Virial-Mix-ϕVmix(T,y)
- Subroutine VDW-Mix-ϕVmix(T,P,y)
- Subroutine RK-Mix-ϕVmix(T,P,y)
- Subroutine SRK-Mix-ϕVmix(T,P,y)
- Subroutine PR-Mix-ϕVmix(T,P,y)
- Subroutine VDW-Mix-ϕLmix(T,P,x)
- Subroutine RK-Mix-ϕLmix(T,P,x)
- Subroutine SRK-Mix-ϕLmix(T,P,x)
- Subroutine PR-Mix-ϕLmix(T,P,x)
- Appendix G: Databanks, simulation programs, books, websites
- Databanks
- Simulation programs
- Books
- Websites
- Appendix H: Constants and conversion factors
- Physical constants
- Conversion factors
- Index
- Edition: 2
- Published: June 17, 2021
- Imprint: Elsevier
- No. of pages: 858
- Language: English
- Hardback ISBN: 9780128205303
- eBook ISBN: 9780128205310
IT
Ismail Tosun
The author has been teaching undergraduate and graduate level thermodynamics courses for over 40 years. Since 1980 he has been a faculty member at the Middle East Technical University (METU), Ankara, Turkey. He has also taught at the Turkish Military Academy and the University of Akron, Ohio. Professor Tosun received his BS and MS degrees from METU, and a PhD degree from the University of Akron, all in chemical engineering. His research interests include mathematical modeling and transport phenomena.
Professor Tosun is the author of the following books:
• Modeling in Transport Phenomena – A Conceptual Approach, 2nd ed., Elsevier, 2007.
• Fundamental Mass Transfer Concepts in Engineering Applications, CRC Press, 2019.
• Thermodynamics – Principles and Applications, 2nd ed., World Scientific, 2020.
Affiliations and expertise
Middle East Technical University, Department of Chemical Engineering, Ankara, TurkeyRead The Thermodynamics of Phase and Reaction Equilibria on ScienceDirect