The Porphyrins V4

List of Contributors

General Preface

Preface

Contents of Other Volumes


1 Nuclear Magnetic Resonance Spectroscopy of Diamagnetic Porphyrins

I. Introduction

II. 1H NMR Spectra of Diamagnetic Porphyrins

III. Other Nuclei

References


2 Nuclear Magnetic Resonance of Paramagnetic Metalloporphyrins

I. Introduction

II. Principles

III. Spectral Analysis

IV. Structural Properties

V. Dynamic Properties

References


3 ENDOR Spectroscopy of the Chlorophylls and the Photosynthetic Light Conversion Apparatus

I. Introduction

II. Theory of ENDOR Spectroscopy

III. Experimental Aspects of ENDOR Spectroscopy

IV. Effect of State of Chlorophyll Aggregation on Hyperfine Interactions and ESR Linewidth

V. In Vitro ENDOR of Chlorophyll Cations

VI. In Vivo ENDOR of the Photosynthetic Apparatus

VII. Conclusion

References


4 Electron Spin Resonance of Porphyrin TT Cations and Anions

I. Introduction

II. Cations

III. Anions

IV. Theoretical Appendix

References


5 Electron Spin Resonance of Porphyrin Excited States

I. Introduction

II. The Spin Levels of the Triplet State

III. Experimental Results

References


6 Electron Paramagnetic Resonance of Hemoproteins

I. Introduction

II. EPR of Low-Spin Hemoproteins

III. EPRof High-Spin Ferrihemoproteins

IV. Quantum Mechanical Spin-State Mixing

V. Thermal Mixing

VI. Hyperfine Interactions

VII. New Techniques

Applications

References


7 Electron Spin Resonance and Electronic Structure of Metalloporphyrins

I. Introduction

II. Copper Porphyrins

III. Silver Porphyrins

IV. Vanadylporphyrins

V. Cobalt Porphyrins

References


8 Mossbauer Spectra of Hemoproteins

I. Introduction

II. Paramagnetic Mossbauer Spectra

III. High-Spin Ferric Heme Proteins

IV. Low-Spin Ferric Heme Proteins

V. High-Spin Ferrous Heme Proteins: Measurements in Strong Magnetic Fields

VI. Diamagnetic Compounds: Low-Spin Ferrous Heme Proteins and Oxygenated Complexes

VII. Less Common Charge and Spin States

VIII. Mossbauer Emission Spectroscopy

Appendix

References


9 Mossbauer Spectroscopy of Iron Porphyrins

I. Introduction

II. Mossbauer Parameters and Theoretical Considerations

III. Iron(III) Porphyrin Complexes

IV. Iron(II) Porphyrin Complexes

V. Other Formal Oxidation States and High-Pressure Studies

VI. Conclusion

References

Author Index

Subject Index