The Porphyrins V4
Physical Chemistry, Part B
- 1st Edition - November 13, 2012
- Latest edition
- Editor: David Dolphin
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 4 1 4 3 1 7 - 3
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 1 4 6 3 3 - 3
The Porphyrins, Volume IV: Physical Chemistry, Part B focuses on the physical chemistry of porphyrins, their precursors, catabolic derivatives, and related compounds. The book… Read more
The Porphyrins, Volume IV: Physical Chemistry, Part B focuses on the physical chemistry of porphyrins, their precursors, catabolic derivatives, and related compounds. The book covers nuclear magnetic resonance (NMR) spectroscopy of diamagnetic and paramagnetic porphyrins and electron nuclear double resonance (ENDOR) spectroscopy of chlorophylls and related systems. It also encompasses electron spin resonance (ESR) spectroscopy of porphyrin pi cations and anions, porphyrin excited states, metalloporphyrins, hemoproteins, and hemes. This volume is organized into nine chapters and begins with an overview of NMR theory and the use of NMR spectroscopy to study diamagnetic porphyrins and paramagnetic metalloporphyrins. The discussion then shifts to the theory of ENDOR spectroscopy and the application of ENDOR spectroscopy to analysis of chlorophylls, ESR of pi cations and anions of porphyrins as well as porphyrin excited states, and electron paramagnetic resonance and Mossbauer spectra of hemoproteins. The reader is also introduced to ESR and the electronic structure of metalloporphyrins. A chapter on Mossbauer spectroscopy of iron porphyrins concludes the book. This book is a valuable resource for inorganic, organic, physical, and biochemists interested in the physical chemistry of porphyrins.
List of Contributors
General Preface
Preface
Contents of Other Volumes
1 Nuclear Magnetic Resonance Spectroscopy of Diamagnetic Porphyrins
I. Introduction
II. 1H NMR Spectra of Diamagnetic Porphyrins
III. Other Nuclei
References
2 Nuclear Magnetic Resonance of Paramagnetic Metalloporphyrins
I. Introduction
II. Principles
III. Spectral Analysis
IV. Structural Properties
V. Dynamic Properties
References
3 ENDOR Spectroscopy of the Chlorophylls and the Photosynthetic Light Conversion Apparatus
I. Introduction
II. Theory of ENDOR Spectroscopy
III. Experimental Aspects of ENDOR Spectroscopy
IV. Effect of State of Chlorophyll Aggregation on Hyperfine Interactions and ESR Linewidth
V. In Vitro ENDOR of Chlorophyll Cations
VI. In Vivo ENDOR of the Photosynthetic Apparatus
VII. Conclusion
References
4 Electron Spin Resonance of Porphyrin TT Cations and Anions
I. Introduction
II. Cations
III. Anions
IV. Theoretical Appendix
References
5 Electron Spin Resonance of Porphyrin Excited States
I. Introduction
II. The Spin Levels of the Triplet State
III. Experimental Results
References
6 Electron Paramagnetic Resonance of Hemoproteins
I. Introduction
II. EPR of Low-Spin Hemoproteins
III. EPRof High-Spin Ferrihemoproteins
IV. Quantum Mechanical Spin-State Mixing
V. Thermal Mixing
VI. Hyperfine Interactions
VII. New Techniques
Applications
References
7 Electron Spin Resonance and Electronic Structure of Metalloporphyrins
I. Introduction
II. Copper Porphyrins
III. Silver Porphyrins
IV. Vanadylporphyrins
V. Cobalt Porphyrins
References
8 Mossbauer Spectra of Hemoproteins
I. Introduction
II. Paramagnetic Mossbauer Spectra
III. High-Spin Ferric Heme Proteins
IV. Low-Spin Ferric Heme Proteins
V. High-Spin Ferrous Heme Proteins: Measurements in Strong Magnetic Fields
VI. Diamagnetic Compounds: Low-Spin Ferrous Heme Proteins and Oxygenated Complexes
VII. Less Common Charge and Spin States
VIII. Mossbauer Emission Spectroscopy
Appendix
References
9 Mossbauer Spectroscopy of Iron Porphyrins
I. Introduction
II. Mossbauer Parameters and Theoretical Considerations
III. Iron(III) Porphyrin Complexes
IV. Iron(II) Porphyrin Complexes
V. Other Formal Oxidation States and High-Pressure Studies
VI. Conclusion
References
Author Index
Subject Index
- Edition: 1
- Latest edition
- Published: November 13, 2012
- Language: English
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