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Theory and Ion Chemistry concentrates on the fundamental aspects of a set of 13 carefully chosen topics covering the whole field of mass spectrometry. It covers both primary (basic… Read more
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Chapter 1 Theory (Reactions)
Ion–Molecule Collision Theory (D P Ridge)
Statistical Theories in Mass Spectrometry (J C Lorquet and B Leyh)
Kinetic Energy Release Distributions in Mass Spectrometry (B Leyh and J C Lorquet)
Non-adiabatic Reactions (J C Lorquet and B Leyh)
Classical Trajectory Simulations (W L Hase)
Chapter 2 Theory (Energies and Potential Energy Surfaces)
Theoretical Methods (M S Gordon)
Anions (J Simons)
Organics (M Yanez)
Transition Metals (M C Holthausen)
Chapter 3 Instrumentation
Metastable Ions (J L Holmes)
Flow Tubes (V M Bierbaum)
Multiquadrupoles (C Rolando and M Sablier)
TOF and RTOF (A Uphoff and J Grotemeyer)
Fourier Transform Ion Cyclotron Resonance (A G Marshall)
Ion Traps (R E March)
Crossed Beam Methods for Ion Collisions (J M Farrar)
Merged Beams (W R Gentry)
RF Ion Guides (D Gerlich)
Ion Storage Rings (M Larsson)
High-temperature Studies (A A Viggiano)
Chapter 4 Ion Spectroscopy
Spectroscopy of Molecular Ions in Noble Gas Matrices (L Andrews)
Microwave and Infrared Spectroscopy of Molecular Ions (T Oka)
Ion Fluorescence (T G Wright)
Photoelectron Spectroscopy, Threshold Photoelectron Spectroscopy, and Pulsed Field Ionization (T Baer)
Threshold Ion-pair Production Spectroscopy (TIPPS) (J W Hepburn)
Photodissociation Spectroscopy (R C Dunbar)
Infrared Photodissociation (J M Riveros)
Vibrational Predissociation (M A Johnson)
Product State Distributions (S Kato)
Vibrational State Selection (S L Anderson)
Ion Imaging Techniques for the Measurement of Ion Velocities (D W Chandler and C C Hayden)
Chapter 5 Thermochemistry: Methods
Thermochemistry Definitions and Tabulations (K M Ervin and P B Armentrout)
The Bracketing Method for Determining the Thermochemistry of Ion–Molecule Reactions (J E Bartmess)
Ion–Molecule Equilibria at High Pressure (P Kebarle)
Low-pressure Ion–Molecule Equilibrium (K A Kellersberger and D V Dearden)
Charge Transfer Equilibria and Complexes (M Mautner)
The Kinetic Method: Thermochemical Determinations and Chiral Analysis (X Zheng, R Augusti, W A Tao and G Cooks)
Radiative Association Kinetics: Ion–Ligand Binding Thermochemistry (R C Dunbar)
Black-body Infrared Radiative Dissociation (BIRD) (R C Dunbar)
Measuring Fragment Ion Appearance Energies by Photoionization Methods (T Baer)
Photoelectron Spectroscopy of Negative Ion Beams: Measurements of Electron Affinities (G B Ellison)
Thermochemistry from Threshold Ion-pair Production Spectroscopy (J W Hepburn)
Photodissociation Studies of Ion Thermochemistry (R C Dunbar)
Reaction Threshold Energy Measurements (P B Armentrout)
Collision-induced Dissociation (P B Armentrout)
The Correlation of Thermochemical Data (J L Holmes)
Chapter 6 Collisional Activation and Dissociation
Methodology (J Mitchell and S A McLuckey)
Single Collisions (P B Armentrout)
Multiply Charged Ions (P Scheier)
Collisional Activation for Structural Analysis (D Schröder)
Via Ion-Neutral Complexes (T H Morton)
Collisions of Ions with Surfaces at Hyperthermal Energies (R G Cooks, V Grill, N Wade, S-C Jo and B Gologan)
Chapter 7 Mobilities
Transport Properties (L A Viehland)
Small Systems (J Husband and S R Leone)
Drift Tubes: Instrumentation and Applications to Biomolecules (A E Hilderbrand, S J Valentine and D E Clemmer)
Chapter 8 Neutralization, Charge Reversal
Charge Reversal (D Schroder)
Generation and Characterization of Transient Intermediates by Neutralization–Reionization Mass Spectrometry (F Turecek)
Electron–Ion Recombination (N G Adams, L M Babcock and J L McLain)
Ion–Ion Recombination (N G Adams, L M Babcock and C D Molek)
Chapter 9 Organic Ion Chemistry (Positive)
Unimolecular Organic Reactions (N M M Nibbering)
Bimolecular Reactions (N M M Nibbering)
Aliphatic Substitution (D Kuck)
Eletrophilic Aromatic Substitution (D Kuck)
SN2 and Related Reactions (R A J O’Hair)
Distonic Radical Cations (H I Kenttamaa)
Gas-phase H/D Exchange of Organic Compounds for Structural Elucidation (M K Green and C B Lebrilla)
Chapter 10 Organic Ion Chemistry (Negative)
Unimolecular Rearrangements of Carbanions (S R Kass)
Nucleophilic Substitution and Elimination Reactions (S Gronert )
Addition/Elimination Reactions (S Gronert )
Oxidation/Reduction Reactions of Negative Ions in the Gas Phase (P G Wenthold)
Strained Ring and Highly Basic Carbanions (S R Kass)
Negative Distonic Ions (N M M Nibbering)
H/D Exchange Reactions (C H DePuy and S Kato)
Organoaluminium, -silicon, -phosphorus, and -sulfur Chemistry (R Damrauer and R A J O’Hair)
Chapter 11 Solvation and Clusters
The Ionic Hydrogen Bond: Clusters and Ion Solvation (M Mautner)
Charge Transfer Complexes (M Mautner)
Small Molecular Clusters (R L DeLeon and J F Garvey)
Covalent Clusters of Group 14 Elements (C Lifshitz)
Endohedral Complexes of Fullerenes and Mass Spectrometry (D E Giblin and M L Gross)
Cluster Anions (Experiments) (K H Bowen Jr and E W Schlag)
Metal Ion Solvation (P B Armentrout)
Host–Guest Chemistry in the Gas Phase (D V Dearden)
Metal Clusters (K Hansen and L Schweikhard)
Chapter 12 Inorganic Chemistry
Alkali Metal Ion Chemistry (J D Anderson and D V Dearden)
Silicon Ion Chemistry (D K Bohme)
Transition Metal Ion Chemistry (P B Armentrout)
Transition Metal Oxides (D Schröder)
Photoelectron Spectroscopy of Inorganic Molecules (N E Gruhn and D L Lichtenberger)
Chapter 13 Biopolymers
The Ionic Hydrogen Bond in Complex Organics and Biomolecules (M Mautner)
H/D Exchange Reactions of Biological Molecules in the Gas Phase (J L Beauchamp)
Ion–Ion reactions: Biopolymers (S A McLuckey)
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