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The Determination of Organic Peroxides
Monographs in Organic Functional Group Analysis
- 1st Edition - January 1, 1970
- Authors: R. M. Johnson, I. W. Siddiqi
- Editors: R. Belcher, D. M. W. Anderson
- Language: English
- Paperback ISBN:9 7 8 - 1 - 4 8 3 1 - 2 7 7 7 - 4
- Hardback ISBN:9 7 8 - 0 - 0 8 - 0 1 5 5 8 6 - 9
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 6 0 1 9 - 1
Monographs in Organic Functional Group Analysis, Volume 4: The Determination of Organic Peroxides focuses on the analytical chemistry of organic peroxides. The monograph first… Read more
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Request a sales quoteMonographs in Organic Functional Group Analysis, Volume 4: The Determination of Organic Peroxides focuses on the analytical chemistry of organic peroxides. The monograph first offers information on the compositions, properties, and reactions of lipid peroxides, polymers, and petrochemicals. The text then reviews the iodometric methods, including choice of solvents, reaction conditions, and titration with thiosulfate. The ferrous ion methods are also discussed. Considerations include choice of reagents and solvents and titration with titanous, dichromate, and mercurous ions. The book also focuses on titrimetric methods, including arsenious, stannous, and titanous methods, titration with anions, and sulfides and mercaptans. Numerical representations are provided. The text puts emphasis on colorimetric and polarographic methods. Polarographic techniques for peroxides; nature and concentration of peroxides; leuco base of methylene blue; and ferrous ions are described. The book also discusses paper, thin-layer, and gas chromatography. The monograph is an important guide for readers interested in the analytical chemistry of organic peroxides.
Contents
Preface
1. Introduction
1. Lipid Peroxides
2. Polymers
3. Petrochemicals
4. Irradiation
5. Miscellaneous
References
2. Structure and Reactivity
1. Classification of Peroxides
2. Reactivity
References
3. Iodometric Methods
1. General Comments
2. Choice of Solvent
3. Reaction Conditions
4. Titration with Thiosulphate
References
4. Ferrous Ion Methods
1. Introduction
2. Choice of Reagent
3. Choice of Solvent
4. Titration with Titanous Ions
5. Titration with Dichromate Ions
6. Titration with Mercurous Ions
References
5 . Futher Titrimetric Reagents
1. Introduction
2. Arsenious Methods
3. Stannous Methods
4. Titanous Methods
5. Titration with Anions
6. Sulphides and Mercaptans
References
6 . Colorimetric Methods
1. Introduction
2. Ferrous Ions
3. Leuco Base of Methylene Blue
4. Iodine
5. N, N'-Dimethyl-p-Phenylenediamine
6. Other Colorimetric Reagents
References
7. Polarographic Methods
1. Introduction
2. Electrode Reaction
3. Polarographic Techniques For Peroxides
4. Nature And Concentration of Peroxide
5. Solvents And Supporting Electrolytes
References
8. Spectroscopic Techniques
1. Introduction
2. Ultraviolet And Visible Absorption
3. Infrared Absorption
4. Raman Spectroscopy
References
9. Chromatographic Methods. (A) Column Chromatography
1. Introduction
2. Column Techniques
3. Solvent Medium
4. Stationary Phase
5. Type of Peroxide
References
10. Chromatographic Methods. (B) Paper Chromatography
1. Introduction
2. Choice Of Paper
3. Mobile Phase
4. General Techniques
5. Chemical Structure
6. Detection
7. Class of Peroxide
References
11. Chromatographic Methods. (C) Thin-Layer Chromatography
1. Introduction
2. Adsorbents
3. Solvent Systems
4. Detection
5. Techniques
6. Applications
References
12. Chromatographic Methods. (D) Gas Chromatography
1. Introduction
2. Solid Support
3. Stationary Phase
4. Column Temperature
5. Functional Groups
6. Quantitative Analysis
References
13. Choice of Method
1. Introduction
2. Concentration of Peroxide
3. Reactivity of Peroxide
4. Nature of The Sample
Index
- No. of pages: 130
- Language: English
- Edition: 1
- Published: January 1, 1970
- Imprint: Pergamon
- Paperback ISBN: 9781483127774
- Hardback ISBN: 9780080155869
- eBook ISBN: 9781483160191
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