The Determination of Hydrazino-Hydrazide Groups
Monographs in Organic Functional Group Analysis
- 1st Edition - November 9, 2013
- Latest edition
- Author: Hugh E. Malone
- Editors: R. Belcher, D. M. W. Anderson
- Language: English
The Determination of Hydrazino-Hydrazide Groups discusses the analytical methods for the analysis of hydrazino, hydrazide, hydrazine, substituted hydrazines, and hydrazine… Read more
The Determination of Hydrazino-Hydrazide Groups discusses the analytical methods for the analysis of hydrazino, hydrazide, hydrazine, substituted hydrazines, and hydrazine derivatives. It also shows the usefulness of hydrazines and its derivatives as analytical reagents. The book presents a detailed examination of a variety of analytical methods used in determining hydrazines and hydrazides derivatives. These methods include oxidation, colorimetry and spectrophotometry, coulometry, polarography, and gasometric and acid-based methods. The book concludes by discussing the use of hydrazines as analytical reagents. The text is invaluable for everyone interested in hydrazides and hydrazines and their applications.
Preface
General Introduction
Chapter 1 Oxidation Methods
1. Use of Bromate
(a) Hydrazine
(b) Phenylhydrazine and Semicarbazide
2. Use of Bromine
(a) Hydrazine
3. Use of JV-Bromosuccinimide
(a) Hydrazine
(b) Phenylhydrazine
(c) Phenylhydrazine-p-Sulfonic Acid
(d) Isonicotinic Acid Hydrazide
4. Use of Ceric Sulfate
(a) Hydrazine
5. Use of Ceric Sulfate-Iodine Monochloride
(a) Hydrazine, Semicarbazide, Phenylhydrazine, 2,4-Dinitrophenylhydrazine, Monomethylhydrazine, and 1,1-Dimethylhydrazine
6. Use of Diethylenetetraammonium Ceric Sulfate
(a) Hydrazine
7. Use of Chloramine-T
(a) Hydrazine
8. Use of Chloramine-T-Iodine Monochloride
(a) Hydrazine
9. Use of Chloramine-B
(a) Hydrazine
10. Use of Chloramine-B-Iodine Monochloride
(a) Hydrazine
11. Use of Copper Oxide
(a) Hydrazine
(b) Phenylhydrazine
12. Use of Copper Oxide-Fehling's Solution
(a) Hydrazine
(b) Phenylhydrazine
13. Use of Copper Sulfate
(a) Hydrazine
14. Use of Dichromate
(a) Hydrazine
15. Use of Potassium Ferricyanide-Ascorbic Acid
(a) Hydrazine
16. Use of Ferricyanide-Ceric Sulfate
(a) Hydrazine
17. Use of Ferricyanide-Zine Sulfate
(a) Hydrazine
18. Use of Hypochlorous Acid
(a) Hydrazine
19. Use of Hypochlorite
(a) Semicarbazides and Semicarbazones
20. Use of Iodic Acid
(a) Hydrazine
21. Use of Iodine
(a) 1,1-Dimethylhydrazine (UDMH)
(b) Disubstituted Hydrazines
(c) Hydrazine
(d) Phenylhydrazine
(e) Isonicotinic Acid Hydrazide
(f) Semicarbazide
(g) Diaminodimethylguanidinium Nitrate
22. Useoflodate
(a) 1,1 -Dimethylhydrazine
(b) 2,4-Dinitrophenylhydrazine
(c) Phenylhydrazine and Semicarbazide
(d) Di- and Triaminoguanidine and Carbohydrazide
(e) Hydrazine
(f) Isonicotinic Acid Hydrazide
(g) Monomethylhydrazine
(h) Semicarbazides, Semicarbazones, and Hydrazines
(i) Monosubstituted Hydrazines, Their Hydrazones, and Acyl Derivatives
23. Use of Periodate
(a) Hydrazine
(b) Phenylhydrazine, Isonicotinic Acid Hydrazide, Semicarbazide, and Thiosemicarbazide
24. Use of Periodate-Iodine Bromide
(a) Hydrazine and Phenylhydrazine
25. Use of Periodate-Iodine Cyanide
(a) Hydrazine
26. Use of Permanganate
(a) Hydrazine
27. Use of Selenious Acid
28. Use of Thallium
(a) Hydrazine
29. Use of Vanadic Acid
References
Chapter 2 Gasometric Methods
1. Use of Bromate
(a) Semicarbazide
(b) Oxalylhydrazide, Thiosemicarbazide, Aminoguanidine, Semicarbazide, and Semioxamazide
2. Use of Bromine-Hypobromite
(a) Semicarbazide, Semioxamazide and Oxalylhydrazide
3. Use of Cupric—Fehling's Solution
(a) Hydrazine
4. Use of Cupric Sulfate
(a) Hydrazine Derivatives
5. Use of Ferricyanide
(a) Hydrazine
6. Use of Iodate
(a) Semicarbazide
(b) Semicarbazide, Semioxamazide, Oxalylhydrazide, and Aminoguanidine
(c) Isonicotinic Acid Hydrazide
(d) Hydrazino Nitrogen in Biological Materials
(e) Hydrazine, Hydrazine Derivatives, and Hydrazides
(f) Hydrazino-Boron Compounds
7. Use of Lead Oxide
(a) Hydrazine, Isonicotinic Acid Hydrazide, and Benzoylhydrazide
8. Use of Mercuric Chloride
(a) Hydrazine
References
Chapter 3 Colorimetric and Spectrophoto Metric Methods
1. Determination of Isonicotinic Acid Hydrazide (INH)
(a) In Tablets
(b) In the Presence of ^-Aminosalicylate
(c) In Serum, Blood, or Urine
(d) In Blood and Urine
(e) In the Presence of ^-Aminosalicylic Acid
(f) In the Presence of Acetyl Isonicotinic Acid Hydrazide
2. Determination of Maleic Hydrazide
(a) In Plant and Animal Tissue
3. Determination of Hydrazine
(a) In Biological Materials
(b) In Urine
4. Determination of Hydrazine and Benzylhydrazine
(a) In Organs and Urine
5. Determination of 1,1-Dimethylhydrazine (UDMH)
(a) In Urine
(b) In Blood, Water, and Air
6. Determination of Monomethylhydrazine
(a) In Blood Serum
References
Chapter 4 Chromatographic Methods
1. Ion Exchange Chromatography
(a) Acetylated Isonicotinic Acid Hydrazide
2. Paper Chromatography
(a) Hydrazides
(b) Isonicotinic Acid Hydrazide
(c) INH in Blood
(d) INH in Isolation from Biological Materials
3. Thin Layer Chromatography
(a) Hydrazides
References
Chapter 5 Coulometric Methods
1. Determination of Hydrazine and Substituted Hydrazines
(a) Hydrazides
(b) Hydrazine
(c) 1,1-Dimethylhydrazine
References
Chapter 6 Polarographic Methods
1. Determination of Hydrazine, Phenylhydrazine, and Semicarbazide
2. Determination of Isonicotinic Acid Hydrazide
3. Determination of p,p-Oxybis (Benzenesulfonyl) Hydrazide
References
Chapter 7 Acid-Base Methods
1. Aqueous Methods
(a) Hydrazine
2. Non-aqueous Methods
(a) Nitroguanidines
(b) Isonicotinic Acid Hydrazide
(c) Primary Hydrazides
References
Chapter 8 The Analysis of Mixtures
1. Hydrazine-l,l-Dimethylhydrazine Mixtures
(a) Acid-Base—Oxidation Method
(b) Acid-Base—Salicylaldehyde Method
(c) Chromatographic Methods
(d) Gravimetric Oxidation Method
(e) Potentiometric-Spectrophotometric Acid-Base Method
(f) Spectrophotometric Method
2. Hydrazine-Monomethylhydrazine Mixtures
(a) Acid Base-Salicylaldehyde Methods
(b) Chromatographic Methods
(c) Oxidation (Differential) Method
3. Hydrazine-l,l-Dimethylhydrazine and Monomethylhydrazine- 1,1 -Dimethylhydrazine Mixtures
(a) Acid-Base-Acetic Anhydride Methods
4. Hydrazine-Monomethylhydrazine-1,1 -Dimethylhydrazine Mixtures
(a) Chromatographic Method
5. Hydrazine-Aniline Mixtures
(a) Acid-Base (Differential) Method
6. Hydrazine-Ammonia Mixtures
(a) Oxidation Methods
(b) Oxidation-Kjeldahl Method
(c) Thermogravimetric Method
7. Hydrazine-Ammonia-Hydrogen-Nitrogen-Argon Mixtures
(a) Mass Spectrometric Method
8. Hydrazine-Hydroxylamine Mixtures
(a) Bromate Oxidation Method
(b) Chronopotentiometric Method
(c) Potentiometric Oxidation Method
(d) Zinc Sulfate Oxidation—Ferricyanide Method
9. Hydrazine-Ammonium Hydroxide—Hydroxylamine Mixtures
(a) Mass Spectrometric Method
10. Hydrazine-Hydrazine Nitrate Mixtures
(a) Acid-Base Method
11. Determination of Diethylenetriamine (DETA) with either Hydrazine, Monomethylhydrazine, or 1,1-Dimethylhydrazine
(a) Acid-Base-Salicylaldehyde Method
12. Determination of Hydrazine-l,l-Dimethylhydrazine-Diethylenetriamine
(a) Acid-base (Two Titrants)-Salicylaldehyde Method
13. Determination of Hydrazine-Ammonium Thiocyanate Mixtures
(a) Iodate Oxidation—Volhard Method
References
Chapter 9 Other Qualitative and Quantitative Tests
1. Spot Tests
(a) Hydrazine and Hydrazine-Hydroxylamine
(b) Nitrophenylhydrazine, 2,4-Dinitrophenylhydrazine, and Nitrophenylhydrazine Derivatives
(c) Semicarbazides, Thiosemicarbazide, and Nitrophenylhydrazine
2. Microbiological Tests
(a) Isonicotinic Acid Hydrazide
3. Field Tests
(a) 1,1-Dimethylhydrazine in JP-4
(b) Hydrazine
References
Chapter 10 the Use of Hydrazines as Analytical Reagents
1. Use of 1,1 -Dimethylhydrazine
(a) Determination of Aldehydes
2. Use of 2,4-Dinitrophenylhydrazine
(a) Determination of Carbonyl Compounds
3. Use of 1,5-Diphenylcarbazide
(a) Determination of Chromium
(b) Determination of Technetium
4. Use of Hydrazine
(a) Determination of Alkali
(b) Determination of Bromate
(c) Determination of Iodide
(d) Determination of Mercuric Salts
(e) Determination of Iodates
(f) Determination of Selenium Dioxide
(g) Determination of Levulinic Acid
5. Use of 2-Hydrazinobenzothiazole
(a) Determination of Aliphatic Aldehydes
6. Use of Isonicotinic Acid Hydrazide
7. Use of Oxalyldihydrazide
(a) Determination of Copper
8. Use of Phenylhydrazine
(a) Determination of Carbonyl Compounds
(b) Determination of Molybdenum
9. Use of Salicyloylhydrazide
(a) Determination of Hydrazones
(b) Determination of Palladium
10. Use of Semicarbazide
(a) Determination of Carbonyl Compounds
References
Author Index
Subject Index
Other Titles in the Series
- Edition: 1
- Latest edition
- Published: November 9, 2013
- Language: English
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