
Structural Chemistry of Glasses
- 1st Edition - June 26, 2002
- Imprint: Elsevier Science
- Author: K.J. Rao
- Language: English
- Paperback ISBN:9 7 8 - 0 - 4 4 4 - 5 4 4 6 3 - 6
- Hardback ISBN:9 7 8 - 0 - 0 8 - 0 4 3 9 5 8 - 7
- eBook ISBN:9 7 8 - 0 - 0 8 - 0 5 1 8 0 3 - 9
Structural Chemistry of Glasses provides detailed coverage of the subject for students and professionals involved in the physical chemistry aspects of glass research. Starti… Read more

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Glass transition is considered, as well as the wide range of theoretical approaches that are used to understand this phenomenon. The author provides a detailed discussion of Boson peaks, FSDP, Polymorphism, fragility, structural techniques, and theoretical modelling methods such as Monte Carlo and Molecular Dynamics simulation. The book covers ion and electron transport in glasses, mixed-alkali effect, fast ion conduction, power law and scaling behaviour, electron localization, charged defects, photo-structural effects, elastic properties, pressure-induced transitions, switching behaviour, colour, and optical properties of glasses. Special features of a variety of oxide, chalcogenide, halide, oxy-nitride and metallic gasses are discussed.
With over 140 sections, this book captures most of the important and topical aspects of glass science, and will be useful for both newcomers to the subject and the experienced practitioner.
The World Of Inorganic Glasses
.
Natural glasses. Glasses through the centuries: a historical perspective. Glass in modern times. In this book.
The Glassy State.
Structural approach to glass formation.
Continuous random network model.
Random close packing model.
Bonding theories.
The Glass Transition Phenomenon.
Structural frustration model.
Cluster model of glasses and glass transition.
Polyamorphism.
Fragility and glass forming liquids.
Structural Techniques.
Nuclear Magnetic Resonance.
Vibrational spectroscopy.
IR spectroscopy.
Raman spectroscopy.
Theoretical Studies.
Monte Carlo and Reverse Monte Carlo methods.
MD simulation.
Quantum chemical calculations.
D.C. Conductivity.
Optical basicity and ionic conductivity.
Mixed Alkali Effect.
Theories of MAE.
Mixed ionic effect.
A.C. Conductivity.
Alternate formulation of dielectric data.
Theoretical models of a.c. conductivity.
Jump relaxation model.
Diffusion Controlled Relaxation model.
Semiconducting Glasses.
Variable Range Hopping.
Thermoelectric power.
Hall coefficient.
Polaronic transport.
Relaxation Phenomena.
Thermodynamics in the region of glass transition.
Two Level States and relaxation.
Enthalpy relaxation.
Enthalpy relaxation and a.c. heat capacities.
Elastic Properties And Pressure Effects.
Elastic constants.
Measurement of elastic moduli.
Structure of glasses and elastic constants.
Microhardness.
Optical Properties.
Colour due to transition metal ions.
Fluorescence spectra.
Glass lasers.
Colour from particle scattering.
Oxide Glasses.
Bridging, non-bridging and terminal oxygens.
Complex oxide glasses.
Glasses with dissolved salts.
Glasses containing transition metal oxides.
Chalcogenide Glasses.
Chalcogen and inter-chalcogen glasses.
Group V chalcogenides.
Chemical ordering.
Group IV chalcogenides.
Other Glasses.
Halide glasses.
Heavy metal fluoride glasses.
Oxy-halide glasses.
Glasses of mixed salts: discrete anion glasses.
- Edition: 1
- Published: June 26, 2002
- Imprint: Elsevier Science
- No. of pages: 584
- Language: English
- Paperback ISBN: 9780444544636
- Hardback ISBN: 9780080439587
- eBook ISBN: 9780080518039
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