Spectroscopic Measurement
An Introduction to the Fundamentals
- 2nd Edition - January 10, 2024
- Imprint: Academic Press
- Author: Mark A. Linne
- Language: English
- Paperback ISBN:9 7 8 - 0 - 4 4 3 - 1 5 4 7 4 - 4
- eBook ISBN:9 7 8 - 0 - 4 4 3 - 1 5 4 7 5 - 1
Spectroscopic Measurement: An Introduction to the Fundamentals, Second Edition contains the foundational topics associated with optical spectroscopic techniques, covering the ba… Read more
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Request a sales quoteSpectroscopic Measurement: An Introduction to the Fundamentals, Second Edition contains the foundational topics associated with optical spectroscopic techniques, covering the basic theory of applied spectroscopy and presenting alternative approaches to understand physical processes. Electromagnetism, quantum mechanics, statistical mechanics, molecular spectroscopy, optics, and radiation form the foundations of the field are all thoroughly covered. On top of these rest the techniques applying the fundamentals, including Emission Spectroscopy, Laser Induced Fluorescence, and Raman Spectroscopy. This comprehensive and fully updated second edition includes additional coaching and covers new material online broadening, nonlinear techniques such as coherent anti-Stokes Raman spectroscopy, and more.
Researchers not formally trained in these topics, but who apply spectroscopy in their work, will appreciate the detail contained in this book to ensure accuracy of their technique and/or to develop more sophisticated measurements.
Researchers not formally trained in these topics, but who apply spectroscopy in their work, will appreciate the detail contained in this book to ensure accuracy of their technique and/or to develop more sophisticated measurements.
- Presents measurement techniques in a concise treatment that other available literature lacks to explain
- Provides the audience with engineering analogues written by an engineer to explain basic physics to engineers
- Includes many new and useful graphics in the margins and boxes with supplementary material to immensely facilitate learning
Engineers (grad students, postdocs, faculty, researchers) and Analytical Chemists needing to understand the fundamentals of spectroscopy; PhD-level graduate courses. Physical chemists, atmospheric scientists, industrial researchers, etc. in the areas of combustion as well as many other areas such as CVD reactors, oxidation reactors, plasmas, chemical processing, supercritical processing, fine powder generation, exhaled human breath etc.
- Cover image
- Title page
- Table of Contents
- Copyright
- Dedication
- Preface
- Acknowledgments
- Chapter 1: Introduction
- Abstract
- 1.1. Spectroscopic techniques
- 1.2. Overview of the book
- 1.3. How to use this book
- 1.4. Concluding remarks and warnings
- References
- Chapter 2: A brief review of statistical mechanics
- Abstract
- 2.1. Introduction
- 2.2. The Maxwellian velocity distribution
- 2.3. The Boltzmann population distribution
- 2.4. Molecular energy distributions
- 2.5. Example distributions
- 2.6. Conclusions
- References
- Chapter 3: The equation of radiative transfer
- Abstract
- 3.1. Introduction
- 3.2. Some definitions
- 3.3. Development of the ERT
- 3.4. Implications of the ERT
- 3.5. Photon statistics
- 3.6. Conclusions
- References
- Chapter 4: Optical electromagnetics
- Abstract
- 4.1. Introduction
- 4.2. Maxwell's equations in vacuum
- 4.3. Basic conclusions from Maxwell's equations
- 4.4. Material interactions
- 4.5. Brief mention of nonlinear effects
- 4.6. Irradiance
- 4.7. Conclusions
- References
- Chapter 5: The Lorentz atom
- Abstract
- 5.1. Classical dipole oscillator
- 5.2. Wave propagation through transmitting media
- 5.3. Dipole emission
- 5.4. Conclusions
- References
- Chapter 6: Classical Hamiltonian dynamics
- Abstract
- 6.1. Introduction
- 6.2. Overview of Hamiltonian dynamics
- 6.3. Hamiltonian dynamics and the Lorentz atom
- 6.4. Conclusions
- References
- Chapter 7: An introduction to quantum mechanics
- Abstract
- 7.1. Introduction
- 7.2. Historical perspective
- 7.3. Additional components of quantum mechanics
- 7.4. Postulates of quantum mechanics
- 7.5. Quantum dynamics
- 7.6. Conclusions
- References
- Chapter 8: Atomic spectroscopy
- Abstract
- 8.1. Introduction
- 8.2. The one-electron atom
- 8.3. Multi-electron atoms
- 8.4. Conclusion
- References
- Chapter 9: Molecular spectroscopy
- Abstract
- 9.1. Introduction
- 9.2. Diatomic molecules
- 9.3. Polyatomic molecules
- 9.4. Conclusions
- References
- Chapter 10: Resonance response
- Abstract
- 10.1. Introduction
- 10.2. Einstein coefficients
- 10.3. Oscillator strengths
- 10.4. Absorption cross-sections
- 10.5. Band oscillator strengths
- 10.6. Conclusions
- References
- Chapter 11: Line broadening
- Abstract
- 11.1. Introduction
- 11.2. A spectral formalism
- 11.3. General description of optical spectra
- 11.4. Homogeneous broadening
- 11.5. Inhomogeneous broadening
- 11.6. The Voigt profile
- 11.7. Collisional narrowing
- 11.8. Further details on collisional broadening
- 11.9. Observations and conclusions
- References
- Chapter 12: The density matrix equations
- Abstract
- 12.1. Introduction
- 12.2. Development of the DME
- 12.3. Interaction with an electromagnetic field
- 12.4. Multiple levels and polarization in the DME
- 12.5. Two-level DME in the steady-state limit
- 12.6. The optical Bloch equations
- 12.7. Conclusions
- References
- Chapter 13: Polarization
- Abstract
- 13.1. Introduction
- 13.2. Polarization of the resonance response
- 13.3. Absorption and polarization
- 13.4. Polarized radiant emission
- 13.5. Photons and polarization
- 13.6. Conclusions
- References
- Chapter 14: Rayleigh and Raman scattering
- Abstract
- 14.1. Introduction
- 14.2. Polarizability
- 14.3. Classical molecular scattering
- 14.4. Rayleigh scattering
- 14.5. Raman scattering
- 14.6. Vibrational Raman
- 14.7. Rotational and rotational-vibrational Raman
- 14.8. Raman lineshapes
- 14.9. Raman flowfield measurements
- 14.10. Conclusions
- References
- Chapter 15: Nonlinear optics: coherent anti-Stokes Raman spectroscopy
- Abstract
- 15.1. Introduction
- 15.2. Introduction to nonlinear optics and CARS
- 15.3. Material polarization of CARS
- 15.4. Additional issues
- 15.5. Conclusions
- References
- Appendix A: Constants
- Appendix B: Nomenclature
- Abbreviations
- Variables
- Subscripts
- Superscripts
- Other
- Appendix C: Units
- References
- Appendix D: Regularly used Dirac mathematics
- D.1. Dirac bra ket notation
- D.2. Operators
- D.3. Time evolution operator and trace
- Index
- Edition: 2
- Published: January 10, 2024
- Imprint: Academic Press
- No. of pages: 490
- Language: English
- Paperback ISBN: 9780443154744
- eBook ISBN: 9780443154751
ML
Mark A. Linne
Professor Mark Linne earned a Mechanical Engineering PhD at Stanford University in 1985 and as part of his thesis work he developed fiberoptic probes for laser-based absorption and fluorescence measurements of reactive species inside enclosed combustion reactors. He has been developing and using laser diagnostics for combustion, the atmosphere, and for electrochemistry ever since. He worked for 5 years as a laser development scientist at Spectra-Physics, the world’s largest manufacturer of scientific lasers.
Affiliations and expertise
Professor of Combustion Engines, University of Edinburgh, UKRead Spectroscopic Measurement on ScienceDirect