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Smart Anticorrosive Materials

Trends and Opportunities

1st Edition - March 28, 2023

Editors: Chandrabhan Verma, Vandana Srivastava, Taiwo W. Quadri, Chaudhery Mustansar Hussain, Eno E. Ebenso

eBook ISBN:

9 7 8 - 0 - 3 2 3 - 9 5 1 5 9 - 3

Smart Anticorrosive Materials: Trends and Opportunities covers new developments in nanoscale coatings and their current applications. The book addresses fundamental… Read more

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Smart Anticorrosive Materials: Trends and Opportunities covers new developments in nanoscale coatings and their current applications. The book addresses fundamental characteristics, synthesis, inhibition mechanisms and applications of green nanomaterials for educational (academic) as well as industrial purposes and provides a chronological overview of the growth of the field. The book concludes with discussions about commercialization, economics and environmental considerations. This will be an indispensable reference for scholars, chemical engineers, chemists and materials scientists working in R&D and academia who want to understand corrosion systems and modern advancements on smart coatings.

Cover image
Title page
Table of Contents
Copyright
List of contributors
About the editors
Preface
Section 1: Basics of corrosion and nanomaterials
Chapter 1. An overview of corrosion
Abstract
1.1 Introduction
1.2 Classification of corrosion
1.3 Hydrogen damage
1.4 Cost of corrosion
1.5 Corrosion’s thermodynamics
1.6 Calculation of thermodynamic parameters
1.7 Adsorption isotherm
1.8 Calculation of synergism parameter of the inhibitors+additives system
1.9 Corrosion measurement methods
1.10 Metallic ion analysis of solution
1.11 Gasometric technique
1.12 Electrical resistance probe technique
1.13 Potentiodynamic polarization measurement
1.14 Linear polarization resistance
1.15 Electrochemical impedance spectroscopy
1.16 Conclusion
References
Chapter 2. Nanomaterials
Abstract
2.1 Introduction
2.2 Concept of nanomaterials
2.3 Classification of nanomaterials
2.4 Smart nanomaterials
2.5 Synthesis of nanomaterials
2.6 Characterization of nanomaterials
2.7 Properties of nanomaterials
2.8 Applications of nanomaterials
2.9 Anticorrosion applications of nanomaterials
2.10 Smart anticorrosive nanocoating formulation
2.11 Future outlooks and opportunities in the utilization of smart anticorrosive nanomaterials
2.12 Conclusion
References
Chapter 3. Nanocomposites
Abstract
3.1 Introduction
3.2 Concept of nanocomposites
3.3 Smart nanocomposites
3.4 Synthesis of nanocomposites
3.5 Characterization of nanocomposites
3.6 Chemical and structural characterization
3.7 Utilization and formulation of smart nanocomposite coatings and film for corrosion protection
3.8 Future trends and opportunities for the utilization of anticorrosive nanocomposites
3.9 Conclusions
References
Chapter 4. Corrosion monitoring of nanocomposites coatings
Abstract
4.1 Introduction
4.2 Nanocomposites: introduction and types/classification
4.3 Different routes of synthesis and application
4.4 Application of the nanocomposites
4.5 Conclusion
Author’s contributions
References
Section 2: Organic nanomaterials as anticorrosive agents
Chapter 5. Production and corrosion protection properties of carbon nanotubes
Abstract
5.1 Introduction
5.2 Production of CNTs for corrosion inhibition
5.3 Roles of CNTs in corrosion inhibiting composites
5.4 Corrosion inhibition potentials of CNTs containing coatings
5.5 Conclusion and future perspective
References
Chapter 6. Fullerenes as anticorrosive coating materials
Abstract
6.1 Introduction
6.2 Methods of preparing fullerenes
6.3 Applications of fullerenes as anticorrosive coating materials for different substrates
6.4 C60 as protective coatings against corrosion of oil and gas pipelines
6.5 Conclusion
References
Chapter 7. Synthesis and anticorrosive application of graphene and graphene-based materials
Abstract
7.1 Introduction
7.2 Preparation methods of graphene, graphene oxide, and reduced graphene oxide
7.3 Application of graphene and graphene-based materials as anticorrosive coating materials for steel surface in saline medium
7.4 Summary and outlook
References
Chapter 8. Graphene-based nanomaterials as corrosion inhibitors
Abstract
8.1 Introduction
8.2 An introduction to corrosion and corrosion inhibitors
8.3 Significance of graphene and graphene oxide in corrosion protection
8.4 Synthesis of graphene oxide–based corrosion inhibitors
8.5 Application of graphene oxide–based corrosion inhibitors
8.6 Conclusions
Future prospective
References
Chapter 9. Graphene-based 2D materials: recent progress in corrosion inhibition
Abstract
9.1 Introduction
9.2 Synthesis of graphene and graphene oxide
9.3 Graphene and graphene-based materials for corrosion protection
9.4 Coating methods
9.5 Improve adhesion of graphene-based coatings on substrate
9.6 Protective mechanism of graphene coatings, problems resulting from coating preparation, and the effects of these problems on corrosion resistance
9.7 Conclusion
References
Chapter 10. Carbon quantum dots as corrosion inhibitors
Abstract
Highlights
Graphical abstract
10.1 Introduction
10.2 Carbon quantum dots from biological sources as green corrosion inhibitors
10.3 Ecofriendly carbon quantum dots as corrosion inhibitors from organic compounds
10.4 Metal-incorporated carbon quantum dots as corrosion inhibitors
10.5 Siloxane-based nanoparticles as corrosion inhibitors
10.6 Epoxy nanocomposite–based graphene quantum dots as corrosion inhibitors
10.7 Imidazole-based carbon dots as corrosion inhibitors
10.8 Challenges
10.9 Conclusion
References
SECTION 3: Inorganic nanomaterials as anticorrosive coatings
Chapter 11. Corrosion resistance of gold and gold oxide nanomaterials
Abstract
11.1 Introduction
11.2 Corrosion mechanisms in vivo
11.3 Metallic implants
References
Chapter 12. Anticorrosive properties of copper oxide nanomaterials in aggressive media
Abstract
12.1 Introduction
12.2 Copper oxide nanoparticles
12.3 Corrosion
12.4 Nanoparticles used as corrosion inhibitors
12.5 Copper/copper oxide as corrosion inhibitors
12.6 Conclusion and prospects
References
Chapter 13. Development of titanium dioxides for anticorrosive coatings for corrosion protection
Abstract
13.1 Introduction
13.2 TiO2/conducting polymer coatings
13.3 Sol–gel coatings
13.4 Electrodeposition of TiO2 layer-by-layer assembled composite coating
13.5 Self-healing coatings of TiO2
13.6 TiO2 hydrophobic coatings
13.7 Conclusion
References
Section 4: Hybrid nanocomposites as anticorrosive materials
Chapter 14. Organic–organic mixed nanocomposites as anticorrosive coatings
Abstract
14.1 Introduction
References
Chapter 15. Organic–inorganic mixed nanocomposite as protective coating for corrosion inhibition
Abstract
15.1 Introduction
15.2 Corrosion and its inhibition mechanism with coating technique
15.3 Organic–inorganic mixed nanocomposite as protective coating for corrosion inhibition
Acknowledgments
References
Chapter 16. Inorganic–inorganic mixed nanocomposites as anticorrosive coatings
Abstract
16.1 Introduction
16.2 Nanocomposite
16.3 General methods of preparation of nanocomposites
16.4 Preparation of inorganic–inorganic nanocomposites
16.5 Properties of inorganic–inorganic nanocomposites
16.6 Applications of inorganic–inorganic nanocomposites—focus on corrosive properties
16.7 Corrosion protection mechanism
16.8 Conclusions
References
Section 5: Environmental friendly aspects of corrosion inhibition
Chapter 17. Anticorrosion with green ionic liquids additives
Abstract
17.1 Introduction
17.2 Ionic liquids as corrosion inhibitors
17.3 Ionic liquids as anticorrosion gels
17.4 Ionic liquids anticorrosion composite coating
References
Chapter 18. Phthalocyanines as corrosion inhibitors
Abstract
18.1 Phthalocyanines
18.2 Corrosion inhibition
18.3 Phthalocyanine anticorrosive composites and coatings
18.4 Conclusion
References
Chapter 19. The role of vegetal tannins in metal corrosion inhibition vis-à-vis agricultural wastes
Abstract
19.1 Introduction
19.2 Agricultural wastes in the environment—tannin contents
19.3 Applications of tannins
19.4 The role of tannins in metal corrosion inhibition
19.5 Conclusion and future perspective
References
Further reading
Chapter 20. Biobased anticorrosive materials for the mitigation of corrosion
Abstract
Graphical abstract
20.1 Introduction
20.2 Economic impact of the corrosion
20.3 Lignin and its composite as an anticorrosive coatings
20.4 Chitosan composite as anticorrosive coatings
20.5 Some examples of graphene/graphene oxide as anticorrosive coatings
20.6 Other biobased material as an anticorrosive material
20.7 Conclusion
References
Chapter 21. Environmentally responsible and sustainable polymer nanocomposites as anticorrosive coatings
Abstract
21.1 Introduction
21.2 Environment and materials
21.3 Corrosion principles and characterization of anticorrosion organic barrier coating
21.4 Protective mechanism of anticorrosive coatings
21.5 Plants mucilages and gums used in anticorrosive nanocoatings
21.6 Cellulose and derivatives used in anticorrosive nanocoatings
21.7 Starch used in anticorrosive nanocoatings
21.8 Chitosan used in anticorrosive nanocoatings
21.9 Carrageenan used in anticorrosive nanocoatings
21.10 Alginate used in anticorrosive nanocoatings
21.11 Conclusion
References
Chapter 22. Green nanomaterials and their anticorrosive properties
Abstract
22.1 Introduction
22.2 Corrosion problems on metallic surfaces
22.3 Green anticorrosive nanomaterials
22.4 Synthesis of green anticorrosive nanomaterials
22.5 Characterization of green anticorrosive nanomaterials
22.6 Application methods of green anticorrosive nanomaterials
22.7 Mechanism of green corrosion inhibitors
22.8 Environmental and economic benefits of green anticorrosive nanomaterials
22.9 Recent trends
22.10 Conclusion
Acknowledgment
References
SECTION 6: Smart materials and cathodic protection
Chapter 23. Nanocontainer-loaded smart functional anticorrosion coatings
Abstract
23.1 Introduction
23.2 Nanocontainers: an introduction
23.3 Loading of the active agents into the nanocontainers
23.4 Release of the active agents from nanocontainers
23.5 Triggers required for the sustained release of active agents
23.6 Nanocontainer-based anticorrosion coatings
23.7 Limitations associated with the applicability of nanocontainers
23.8 Recent trends in the field
23.9 Conclusion
Acknowledgments
References
Chapter 24. Corrosion inhibition of materials at nanoscale
Abstract
24.1 Introduction
24.2 Corrosion environment
24.3 Classifications of corrosion
24.4 Corrosion control and prevention techniques
24.5 Nanocoating and its role in corrosion prevention
24.6 Ceramic nanocoating
24.7 Nanocomposite coating
24.8 Corrosion of photovoltaic devices
24.9 Discussion
24.10 Conclusion and future perspective
References
Chapter 25. Anticorrosion by triboelectric cathodic protection
Abstract
25.1 Introduction
25.2 Anticorrosion by triboelectric cathodic protection
References
Further reading
Chapter 26. Anticorrosion by photocatalytic cathodic protection
Abstract
26.1 Introduction
26.2 TiO2 photoelectrode
26.3 Zinc oxide photoelectrode
26.4 Graphitic carbon nitride photoelectrode
26.5 Bismuth vanadate photoelectrode
26.6 Strontium titanate photoelectrode
26.7 Hematite photoelectrode
26.8 Conclusion and future perspectives
References
Index

Chandrabhan Verma

Chandrabhan Verma, PhD, works at the Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia. He is a member of the American Chemical Society (ACS). His research is mainly focused on the synthesis and designing of environmentally friendly corrosion inhibitors useful for several industrial applications. Dr. Verma is the author of several research and review articles in peer-reviewed international journals of ACS, Elsevier, RSC, Wiley, Springer, etc. Recently, Dr. Verma also edits a few books on different platforms including RSC, ACS, Elsevier, Wiley, CRC, Tailor & Francis, Bentham Science etc. Dr. Verma received several national and international awards for his academic achievements

Affiliations and expertise

Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia

Vandana Srivastava

Vandana Srivastava is a Full Professor in the Department of Chemistry, Indian Institute of Technology (Banaras Hindu University), Varanasi-221005, India. Her research areas include Synthetic Organic Chemistry, Carbohydrate Chemistry, Immunochemistry and Tribology. She has attended various national and international conferences and seminars as an invited speaker. She has received various awards for her academic achievements and is also a member of editorial boards of several journals. She has successfully guided many PhD students.

Affiliations and expertise

Full Professor, Department of Chemistry, Indian Institute of Technology (Banaras Hindu University), Varanasi, India

Taiwo W. Quadri

Taiwo W. Quadri is a research scholar in the Department of Chemistry, Faculty of Natural and Agricultural Sciences, School of Chemical and Physical Sciences, North-West University, Private Bag X2046, Mmabatho 2735, South Africa. His research interest is development of effective anticorrosive materials for metallic corrosion control in various aggressive media. He has published various research articles in peer-reviewed international journals. He has also received several awards. He is a member of International Union of Pure and Applied Chemistry (IUPAC)

Affiliations and expertise

Research Scholar, Department of Chemistry, Faculty of Natural and Agricultural Sciences, School of Chemical and Physical Sciences, North-West University, Mmabatho, South Africa

Chaudhery Mustansar Hussain

Prof Chaudhery Mustansar Hussain, PhD is an Adjunct Professor, Academic Advisor and Lab Director in the Department of Chemistry & Environmental Sciences at the New Jersey Institute of Technology (NJIT), Newark, New Jersey, USA. His research is focused on Application of Nanotechnology & Advanced Materials, in environment and analytical chemistry and Various Industries. Dr. Hussain is the author of numerous papers in peer-reviewed journals as well as prolific author and editor of several scientific monographs and books in his research areas published with Elsevier and other esteemed publishers.

Affiliations and expertise

Adjunct Professor, Academic Advisor and Director of Chemistry and EVSc Labs, Department of Chemistry and Environmental Sciences, New Jersey Institute of Technology (NJIT), Newark, New Jersey, USA

Eno E. Ebenso

Eno E. Ebenso, PhD is a Full Professor in the Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Johannesburg, South Africa. His research is focused on inhibition of metallic corrosion inhibition using synthetic and natural corrosion inhibitors. Prof. Ebenso is author of more than 450 articles in peer-reviewed journals of Elsevier, Royal Society of Chemistry, Wiley and Springer etc. Prof. Ebenso has received several national and international awards for his academic achievements, and he is a member of editorial boards of several journals.

Affiliations and expertise

Full Professor, Institute for Nanotechnology and Water Sustainability, College of Science, Engineering and Technology, University of South Africa, Johannesburg, South Africa