Silicon Anode Systems for Lithium-Ion Batteries
- 1st Edition - September 10, 2021
- Imprint: Elsevier
- Editors: Prashant N. Kumta, Aloysius F. Hepp, Moni K. Datta, Oleg I. Velikokhatnyi
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 8 1 9 6 6 0 - 1
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 8 5 1 8 1 - 7
Silicon Anode Systems for Lithium-Ion Batteries is an introduction to silicon anodes as an alternative to traditional graphite-based anodes. The book provides a comprehen… Read more
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Request a sales quoteSilicon Anode Systems for Lithium-Ion Batteries is an introduction to silicon anodes as an alternative to traditional graphite-based anodes. The book provides a comprehensive overview including abundance, system voltage, and capacity. It provides key insights into the basic challenges faced by the materials system such as new configurations and concepts for overcoming the expansion and contraction related problems. This book has been written for the practitioner, researcher or developer of commercial technologies.
- Provides a thorough explanation of the advantages, challenge, materials science, and commercial prospects of silicon and related anode materials for lithium-ion batteries
- Provides insights into practical issues including processing and performance of advanced Si-based materials in battery-relevant materials systems
- Discusses suppressants in electrolytes to minimize adverse effects of solid electrolyte interphase (SEI) formation and safety limitations associated with this technology
Advanced students, researchers, practitioners, or developers of commercial technologies
- Cover image
- Title page
- Table of Contents
- Copyright
- Contributors
- Preface
- Part I: Introduction and background
- Part II: Mechanical properties
- Part III: Electrolytes and surface electrolyte interphase issues
- Part IV: Achieving high(er) performance: Modeling and experimental perspectives
- Part V: Future directions: Novel devices and space applications
- Part I: Introduction and background
- Chapter 1: Silicon anode systems for lithium-ion batteries
- Abstract
- 1.1: Introduction
- 1.2: The SiLi alloy: A material perspective
- 1.3: The SiLi alloy: An electrode perspective
- 1.4: Conclusions: Summary and perspective
- Chapter 2: Recent advances in silicon materials for Li-ion batteries: Novel processing, alternative raw materials, and practical considerations
- Abstract
- 2.1: Introduction
- 2.2: Hybrid and alloy-based silicon-containing materials
- 2.3: Alternative raw materials and novel processing methods
- 2.4: Conclusions
- Part II: Mechanical properties
- Chapter 3: Computational study on the effects of mechanical constraint on the performance of silicon nanosheets as anode materials for lithium-ion batteries
- Abstract
- 3.1: Introduction
- 3.2: Realization of lithiation and delithiation of silicon (Si) in molecular dynamics (MD) simulation
- 3.3: Predicting properties of lithiated Si with MD simulation
- 3.4: Effects of mechanical constraint on the performance of Si nanosheets as the anode materials for LIB
- 3.5: Conclusions
- Chapter 4: Mechanical properties of silicon-based electrodes
- Abstract
- 4.1: Introduction
- 4.2: Process of volume expansion and crack formation
- 4.3: Measuring volume change of Si-based battery electrodes
- 4.4: Improving stability of Si electrodes
- 4.5: Concluding remarks
- Chapter 5: Effect of insertion of an elastic buffer layer on stability of patterned amorphous silicon thin film Li-ion anode
- Abstract
- Acknowledgments
- 5.1: Introduction
- 5.2: Model description
- 5.3: Computational method
- 5.4: Problem description
- 5.5: Results and discussion
- 5.6: Discussion
- 5.7: Conclusions
- Appendix
- Part III: Electrolytes and surface electroyle interphase (SEI) issues
- Chapter 6: SEI layer and impact on Si-anodes for Li-ion batteries
- Abstract
- 6.1: Introduction
- 6.2: Energetics of SEI
- 6.3: SEI compositions via electrolyte and salt decomposition
- 6.4: Electrolyte additives and their roles during SEI formation
- 6.5: SEI layer properties
- 6.6: SEI formation on Si/SiOx electrodes
- 6.7: SEI growth model
- 6.8: Mechanical deformation and associated strain of SEI layer
- 6.9: Computational work on SEI formation
- 6.10: Coating strategies and core-shell/yolk-shell morphology for stable SEI formation
- 6.11: Binders
- 6.12: Conclusions and future outlook
- Chapter 7: Active/inactive phases, binders, and impact of electrolyte
- Abstract
- 7.1: Active and inactive phases of Si-based materials
- 7.2: Silicon electrode binders
- 7.3: Electrolytes and additives
- 7.4: Conclusions
- Part IV: Achieving high performance
- Chapter 8: Performance degradation modeling in silicon anodes
- Abstract
- Acknowledgments
- 8.1: Introduction
- 8.2: Morphology performance interactions in silicon anodes
- 8.3: Degradation phenomena in silicon anodes
- 8.4: Summary and outlook
- Chapter 9: Nanostructured 3D (three dimensional) electrode architectures of silicon for high-performance Li-ion batteries
- Abstract
- 9.1: Introduction
- 9.2: Structure and electrochemistry of silicon
- 9.3: The failure mechanism of silicon anodes
- 9.4: Mitigation strategies
- 9.5: Nanostructured 3D electrode architectures
- 9.6: Conclusions
- Chapter 10: Processing and properties of silicon anode materials
- Abstract
- Acknowledgments
- 10.1: Introduction
- 10.2: Experimental methods
- 10.3: Results and discussion
- 10.4: Conclusions
- Part V: Applications and future directions
- Chapter 11: Advanced silicon-based electrodes for high-energy lithium-ion batteries
- Abstract
- 11.1: Introduction
- 11.2: Silicon as a low-cost anode material
- 11.3: Mechanically milled silicon nanopowder
- 11.4: Silicon nanospheres using induced plasma
- 11.5: Nano-structured SiOx and its use as a lithium-ion battery anode
- 11.6: Binder selection
- 11.7: Reducing surface reactivity of nano-silicon
- 11.8: Conclusion
- Chapter 12: Batteries for integrated power and CubeSats: Recent developments and future prospects
- Abstract
- Acknowledgments
- 12.1: Introduction
- 12.2: Integrated micropower source in space: Starshine 3
- 12.3: Integrated power technologies—2005–2020
- 12.4: Energy storage options for CubeSats
- 12.5: Conclusions
- Index
- Edition: 1
- Published: September 10, 2021
- Imprint: Elsevier
- No. of pages: 536
- Language: English
- Paperback ISBN: 9780128196601
- eBook ISBN: 9780323851817
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Prashant N. Kumta
Prashant N. Kumta holds the Edward R. Weidlein Endowed Chair and Distinguished Professor with Tenure at the University of Pittsburgh Swanson School of Engineering and School of Dental Medicine, and is also a Professor in the Departments of BioEngineering, Chemical and Petroleum Engineering, Mechanical Engineering and Materials Science, and Oral and Craniofacial Sciences. His research focuses on lithium-ion batteries, fuel cells, supercapacitors, electrolysis, and metallic biomaterials.
Affiliations and expertise
Edward R. Weidlein Chair Professor, University of Pittsburgh, United StatesAH
Aloysius F. Hepp
Aloysius F. Hepp is Chief Technologist at Nanotech Innovations and an independent consultant based in Cleveland, Ohio. He earned a PhD in Inorganic Photochemistry in 1983 from MIT and retired in December 2016 from the Photovoltaic & Electrochemical Systems Branch of the NASA Glenn Research Center (Cleveland). He was a visiting fellow at Harvard University from 1992–3. He was awarded the NASA Exceptional Achievement medal in 1997. He has served as an adjunct faculty member at the University of Albany and Cleveland State University. Dr. Hepp has co-authored nearly 200 publications (including six patents) focused on processing of thin film and nanomaterials for I–III–VI solar cells, Li-ion batteries, integrated power devices and flight experiments, and precursors and spray pyrolysis deposition of sulfides and carbon nanotubes. He has co-edited twelve books on advanced materials processing, energy conversion and electronics, biomimicry, and aerospace technologies. He is Editor-in-Chief Emeritus of Materials Science in Semiconductor Processing (MSSP) and is currently the chair of the International Advisory Board of MSSP, as well as serving on the Editorial Advisory Boards of Mater. Sci. and Engin. B and Heliyon. He has recently been appointed as Series Editor for the Vacuum and Thin-Film Deposition Technologies series and the Aerospace Fundamentals, Applications, and Exploration series.
Affiliations and expertise
Chief Technologist, Nanotech Innovations LLC and a Science Advisory Board Member, CoreWater Technologies, Inc., Oberlin, OH, USAMD
Moni K. Datta
Moni K. Datta is an Assistant Professor at the Bioengineering Department of the University of Pittsburgh in Pennsylvania, USA.
Affiliations and expertise
Assistant Professor, Bioengineering Department, University of Pittsburgh, PA, USAOV
Oleg I. Velikokhatnyi
Oleg I. Velikokhatnyi is an Assistant Professor in the Bioengineering Department at the University of Pittsburgh, USA. His research includes first-principles and semi-empirical approaches applied to alternative energy sources (rechargeable Li-ion batteries, hydrogen storage materials, fuel cells, water electrolysis) and biodegradable magnesium-based alloys for orthopedic and craniofacial applications.
Affiliations and expertise
Assistant Professor, Bioengineering Department, University of Pittsburgh, USARead Silicon Anode Systems for Lithium-Ion Batteries on ScienceDirect