S-scheme Heterojunction Photocatalysts

Fundamentals and Applications

1st Edition, Volume 35 - June 15, 2023
Authors: Jiaguo Yu, Liuyang Zhang, Linxi Wang, Bicheng Zhu
Language: English
Paperback ISBN:
9 7 8 - 0 - 4 4 3 - 1 8 7 8 6 - 5
eBook ISBN:
9 7 8 - 0 - 4 4 3 - 1 8 7 8 7 - 2

S-scheme Heterojunction Photocatalysts Fundamentals and Applications clearly describes photocatalytic processes and mechanisms, reviews the history of traditional heterojun… Read more

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S-scheme Heterojunction Photocatalysts Fundamentals and Applications clearly describes photocatalytic processes and mechanisms, reviews the history of traditional heterojunction, discusses the problems of charge transfer in some heterojunctions, states the necessity in proposing S-scheme photocatalyst, and provides, in detail, the design principles and characterization protocols for the emerging S-scheme heterojunction. Examples of S-scheme heterojunctions classified by material types are summarized, and the book provides a comprehensive discussion on design, fabrication, principle, mechanism, characterization, and application of S-scheme heterojunction photocatalyst.

This book provides state-of-art research frontiers in this area that will appeal to experienced researchers and graduate students, as well as research and development scientists in the nanosized-composite-related industry.

Chapter 1 Principles of photocatalysis

1.1 Introduction

1.1.1 Catalysis and photocatalysis

1.1.2 Photosynthesis

1.1.3 Molecular photocatalysis

1.1.4 Semiconductor photocatalyst

1.2 History of semiconductor photocatalysis

1.3 Photocatalysis principles

1.3.1 Solar spectrum

1.3.2 Bandgap and light absorption

1.3.3 Oxidation and reduction potentials
(including CB and VB position (or values) determined experimentally)

1.3.4 Transfer and separation of carriers

1.3.5 Activity and quantum efficiency

1.4 Classification of photocatalysts

1.4.1 Oxidation and reduction photocatalysts

1.4.2 Oxide photocatalysts

1.4.3 Sulfide photocatalysts

1.4.4 Polymer photocatalysts

1.4.5 MOF and COF photocatalysts

1.4.6 Heterojunction photocatalysts

1.4.7 S-scheme heterojunction photocatalysts

1.5 Application

1.5.1 Water splitting and hydrogen production
(including overall water splitting, photocatalytic oxygen evolution and photocatalytic hydrogen production)

1.5.2 CO2 reduction and solar fuel production

1.5.3 Pollutant degradation and environmental purification

1.5.4. Photocatalytic N2 fixation

1.5.5 H2O2 production

1.5.6 Sterilization and disinfection

1.5.7 Superhydrophilic and self-cleaning

1.5.8 Organic synthesis

1.6 The scope of this book

Chapter 2 Proposal of S-scheme photocatalyst

2.1 Single photocatalyst

2.2 Type II photocatalyst

2.3 Z-scheme photocatalyst

2.4 S-scheme photocatalyst

2.5 Summary

Chapter 3 Characterization methods of S-scheme photocatalyst

3.1 Work function measurement

3.2 In-situ irradiation XPS

3.3 Surface potential (KPFM)

3.4 EPR

3.5 Oxygen active species

3.6 Selective deposition

3.7 Summary

Chapter 4 TiO2-based S-scheme photocatalyst

4.1 TiO2 photocatalyst

4.2 TiO2/CsPbBr3 S-scheme photocatalyst

4.3 TiO2/Ce2S3 S-scheme photocatalyst

4.4 TiO2/WO3 S-scheme photocatalyst

4.5 TiO2/In2S3 S-scheme photocatalyst

4.6 TiO2/polydopamine S-scheme photocatalyst

4.7 Summary

Chapter 5 CdS-based S-scheme photocatalyst

5.1 CdS photocatalyst

5.2 CdS/polymer S-scheme photocatalyst

5.3 CdS/TiO2 nanofiber S-scheme photocatalyst

5.4 CdS/ TiO2 hollow miscosphere S-scheme photocatalyst

5.5 Summary

Chapter 6 C3N4-based S-scheme photocatalyst

6.1 C3N4 photocatalyst

6.2 C3N4/WO3 S-scheme photocatalyst

6.3 C3N4/CeO2 S-scheme photocatalyst

6.4 C3N4/TiO2 S-scheme photocatalyst

6.5 C3N4/ZnO S-scheme photocatalyst

6.6 Summary

Chapter 7 Other S-scheme photocatalyst

7.1 Introduction

7.1 ZnMn2O4/ZnO S-scheme photocatalyst

7.2 BiOBr/NiO S-scheme photocatalyst

7.3 Phosphorus/g-C3N4 S-scheme photocatalyst

7.4 BiOBr/Sulphur-Doped g-C3N4 S-scheme photocatalyst

7.5 ZnO@Polydopamine S-scheme photocatalyst

7.6 ZnO/WO3 S-scheme photocatalyst

7.7 Summary

Jiaguo Yu

Professor Jiaguo Yu received his BS and MS degrees in Chemistry from Central China Normal University and Xi’an Jiaotong University, respectively, and his PhD degree in materials science in 2000 from Wuhan University of Technology. In 2000, he became a Professor at Wuhan University of Technology. He was a postdoctoral fellow at the Chinese University of Hong Kong from 2001 to 2004, a visiting scientist from 2005 to 2006 at the University of Bristol, and a visiting scholar from 2007 to 2008 at University of Texas at Austin. He has won world renown due to his great accomplishments in scientific research by publishing over 600 high-impact SCI papers (149 highly cited ones) and five books, obtaining an H-index of 171. He is a Member of Academia Europaea (2020), a Fellow of the European Academy of Sciences (2020) and a Fellow of Royal Society of Chemistry (2015). He is also one of the 30 Highly Cited Researchers from Clarivate Analytics in three disciplines, i.e. Materials Science, Chemistry and Engineering from 2014 to 2022 worldwide, and the Thomson Reuters "Hottest Researcher" of 2012 in the world.

Affiliations and expertise

Professor, Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, China.

Liuyang Zhang

Professor Liuyang Zhang received her Bachelor of Science degree (2012) from Shanghai Jiao Tong University. Subsequently, she received her Ph.D degree in Materials Science and Engineering from National University of Singapore (NUS) in 2016. She worked as Research Fellow in NUS before joining the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing at Wuhan University of Technology as an associate professor. She has been a professor at China University of Geosciences since 2021. Her main research background lies in the area of photocatalysis and electrochemical energy storage. She has published more than 90 SCI papers and edited one book. She was chosen as one of the Highly Cited Researchers from Clarivate Analytics in 2022.

Affiliations and expertise

Professor, Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, China

Linxi Wang

Linxi Wang received his Bachelor of Science degree (2013) from Wuhan University, PR China, Master of Engineering degree (2015) from Cornell University, USA, and Ph.D. degree (2020) from the Pennsylvania State University, USA. Currently, he is a postdoctoral fellow in Prof. Jiaguo Yu’s group at the China University of Geosciences, PR China. His research interests are the design and fabrication of novel photocatalysts for H2O2 production and water splitting.

Affiliations and expertise

Postdoc, Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, China

Bicheng Zhu

Bicheng Zhu is an associate professor at China University of Geosciences (Wuhan), PR China. He received his bachelor and doctor degrees in materials science from Wuhan University of Technology. His current research focuses on the synthesis, photocatalytic activity, and first-principles investigation of g-C3N4-based photocatalyst.

Affiliations and expertise

Associate Professor, Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, China