Porous Coordination Polymers

From Fundamentals to Advanced Applications

1st Edition - January 23, 2024
Imprint: Elsevier
Editors: Nidhi Goel, Ki-Hyun Kim
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 9 5 5 3 5 - 5
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 5 5 3 6 - 2

Porous Coordination Polymers: From Fundamentals to Advanced Applications offers a comprehensive coverage the latest advances in porous coordination polymers for cutting-e… Read more

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Porous Coordination Polymers: From Fundamentals to Advanced Applications offers a comprehensive coverage the latest advances in porous coordination polymers for cutting-edge applications. Porous Coordination Polymers are gaining increasing interest due to their attractive properties, such as structural flexibility, large surface area, tailorable pore size, and functional tunability, in turn enabling a wide range of possible applications which this book aims to highlight and to elucidate.

The book begins by introducing porous coordination polymers, highlighting their structure, chemistry, basic properties, and design approaches. This is followed by a chapter focusing on synthetic methods and mechanical properties. Subsequent chapters provide in-depth coverage of specific target applications, explaining the preparation of porous coordination polymers for areas including catalysis and photocatalysis, environmental remediation, gas storage and separation, energy storage and conversion, new generation magnets, nanocarriers in therapeutics, and biomedical imaging. Finally, current challenges and future developments are considered in detail.

Cover image
Title page
Table of Contents
Copyright
List of Contributors
About the editors
Chapter 1. Porous coordination polymers: a brief introduction
Abstract
1.1 Introduction
1.2 Classification of PCPs
1.3 Structural aspects
1.4 Properties
1.5 Conclusions
Acknowledgment
References
Chapter 2. Approaches toward the synthesis and mechanical properties of porous coordination polymers
Abstract
2.1 Introduction
2.2 Design and analysis
2.3 Synthetic methods
2.4 Factors affecting the synthesis of PCPs
2.5 Mechanical properties of porous coordination polymers
2.6 Conclusion
Acknowledgments
References
Chapter 3. Progressive approach of porous coordination polymers toward catalysis and photocatalysis
Abstract
3.1 Introduction
3.2 PCPs as catalysts and their modification strategies
3.3 Approaches for the modification of PCPs as photocatalysts
3.4 Concluding remarks
Acknowledgments
References
Chapter 4. Role of porous coordination polymers as chemical and bio-sensors in the remediation of environmental contaminants
Abstract
4.1 Introduction
4.2 Contaminants and their chemo-sensed remediation by coordination polymers
4.3 Principles on the selection of a coordination polymer for sensing and remediation of contaminants
4.4 Ion-exchange and selectivity for remediation of toxic ions
4.5 Adsorptions through supramolecular assembling of contaminants with CPs and recovery
4.6 Photochemical chemo-sensed remediation
4.7 Electrochemical remediation
4.8 Membranes of CPs for contaminant remediation
4.9 CPs of environmentally benign degradable biomaterials
4.10 Conclusions
References
Chapter 5. Magnetic nanocomposite of sugarcane bagasse/HKUST-1 for pesticide removal
Abstract
Graphical abstract
5.1 Introduction
5.2 PCPs in composites
5.3 Natural lignocellulosic materials and nanoparticles for pesticide removal
5.4 Synthesis and characterization of new magnetic sugarcane bagasse and PCP composites
5.5 Adsorption of pesticides by the composites
5.6 Conclusions and outlook
Acknowledgments
References
Chapter 6. Investigation of porous coordination polymers for gas storage and separation
Abstract
6.1 Hydrogen storage
6.2 Methane storage
6.3 Carbon dioxide capture
6.4 Toxic and harmful gas capture and enrichment
6.5 Low-carbon hydrocarbon adsorption and separation
6.6 Volatile organic compounds’ adsorption and separation
6.7 Water vapor adsorption and stability
6.8 Selective adsorption and separation of other gases
6.9 Summary and outlook
Abbreviations
Acknowledgments
Conflicts of interest
References
Chapter 7. A new advanced approach of ultrafast synthesis of ultrahigh Brunauer–Emmett–Teller surface area crystalline/noncrystalline porous coordinated polymers
Abstract
7.1 Introduction
7.2 Synthetic approaches toward the preparation of PCPs
7.3 Structural measurements: structure identification and characterization of Cu++, Ni++, Zn++, and Mg-PCPs
7.4 Gas capture efficiency for PCPs
7.5 Conclusions and perspectives
Acknowledgments
References
Chapter 8. Porous coordination polymers in energy storage and conversion
Abstract
8.1 Introduction
8.2 Synthesis and modification of the porous coordination polymers
8.3 PCP applications in energy storage and conversion
8.4 Conclusion and future perspectives
Acknowledgment
References
Chapter 9. Ions and electron conductive porous coordination polymers for energy applications
Abstract
9.1 Introduction
9.2 Ionic conductive porous coordination polymers
9.3 Electronic conductive porous coordination polymers
9.4 Conclusion and perspectives
Acknowledgment
References
Chapter 10. Conductive properties of triphenylene porous coordination polymers
Abstract
10.1 Molecular and supramolecular properties
10.2 Synthetic approaches
10.3 Chemical structures
10.4 Functional applications of TP PCPs
10.5 Conclusions
Acknowledgments
Abbreviations
References
Chapter 11. Development of new generation magnets based on porous coordination polymers
Abstract
11.1 Introduction
11.2 Types of bridging ligands used to design porous coordination polymer-based molecular magnets
11.3 Magnetic properties of porous coordination polymers
11.4 Conclusion and Outlook
Acknowledgment
References
Chapter 12. Importance of porous coordination polymers as nanocarriers in therapeutics
Abstract
12.1 Introduction
12.2 PCPs’ surface modification as nanocarriers
12.3 PCPs for cancer and drug delivery (chemotherapy and photodynamic therapy [PDT])
12.4 Nucleic acid transfer
12.5 Delivery of nitric oxide
12.6 Drug delivery of other drugs
12.7 Conclusions
Abbreviations
Acknowledgments
References
Chapter 13. Potentiality of nanoscale coordination polymers in biomedical imaging
Abstract
13.1 Functional nanoscale coordination polymers as molecular imaging probes and theranostics
13.2 Porous coordination polymers for therapies
13.3 Biological porous coordination polymers for medical imaging and therapies
13.4 Conclusions and outlooks
Acknowledgments
References
Further reading
Chapter 14. Future prospects and grand challenges for porous coordination polymers
Abstract
14.1 Introduction
14.2 Challenges in the synthesis of PCPs
14.3 Catalysis
14.4 Electric conductivity
14.5 Batteries
14.6 Gas storage and separation
14.7 Vaccines
14.8 PCP’s toxicity
14.9 Conclusions
Acknowledgments
References
Index

Nidhi Goel

Dr. Nidhi Goel received her doctorate in Chemistry, Indian Institute of Technology Roorkee, India. After postdoctoral research from Indian Institute of Science Bangalore, Karnataka, India, she started her independent academic career as Assistant Professor, Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi, India. Her research focuses on developing strategies, based on supramolecular building approaches, for rational construction of functional coordination polymers, Metal-Organic Frameworks and their prospective uses include magnetic, luminescence, and sensing applications. She is also working on drug design, medicinal chemistry natural products chemistry, and chemical biology. Dr. Goel has published more than fifty peer-reviewed research papers and book chapters in reputed international journals and books. She has 15 years research experience along with six years teaching experience at UG and PG level. She has been the Principal Investigator on three research projects from the Government of India. She is also a regular reviewer of a variety of international journals, and has also received several prestigious fellowships and research awards. Moreover, Dr. Goel is editing several books in CRC press Taylor & Francis group, Springer, and Elsevier. She is also acting as Guest Associate Editor in reputed journals.

Affiliations and expertise

Assistant Professor, Department of Chemistry, Institute of Science, Banaras Hindu University, Uttar Pradesh, India

Ki-Hyun Kim

Prof. Ki-Hyun Kim, Ph.D., is a Professor based at the Air Quality and Materials Application Lab, in the Department of Civil and Environmental Engineering, Hanyang University, Korea. His research areas cover various aspects of research incorporating Air Quality & Environmental Engineering into Material Engineering, with an emphasis on advanced novel materials such as Metal-Organic Frameworks (MOFs). Prof. Kim was named as one of the top 10 National Star Faculties in Korea in 2006 and became an Academician of the Korean Academy of Science and Technology in 2018. He was recognized as ‘Highly Cited Researcher (HCR)’ for 2019 and 2020 in the Environment & Ecology field by Clarivate Analytics. He currently serves as associate editor of Environmental Research, Sensors, and Critical Reviews in Environmental Science & Technology, and has published more than 840 articles, many in leading scientific journals.

Affiliations and expertise

Professor, Air Quality and Materials Application Lab, Department of Civil and Environmental Engineering, Hanyang University, Korea

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