Pincer-Metal Complexes
Applications in Catalytic Dehydrogenation Chemistry
- 1st Edition - November 9, 2021
- Editor: Akshai Kumar
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 8 2 2 0 9 1 - 7
- eBook ISBN:9 7 8 - 0 - 1 2 - 8 2 2 0 9 2 - 4
Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivativ… Read more
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Request a sales quotePincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry.
In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot.
- Covers applications of pincer-metal complexes in organic transformations
- Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations
- Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations
R&D sectors in petrochemical industry, fine and commodity chemical industry
- Cover image
- Title page
- Table of Contents
- Copyright
- List of contributors
- Foreword
- Preface
- Chapter 1. Application of pincer metal complexes in catalytic transformations
- Abstract
- 1.1 Introduction
- 1.2 Dehydrogenation of ammonia borane and its derivatives
- 1.3 Dinitrogen activation using pincer ligands
- 1.4 Pincer complexes as hydrogenation catalyst
- 1.5 Coupling reaction: C–C bond formation reaction
- 1.6 Redox-Active Pincer Complexes
- 1.7 Conclusion
- References
- Chapter 2. Pincer-group(8) and pincer-group(9) metal complexes for catalytic alkane dehydrogenation reactions
- Abstract
- 2.1 Introduction
- 2.2 Dehydrogenation reactions of alkane using pincer–Ir complexes
- 2.3 Dehydrogenation of alkanes by pincer–metal complexes other than iridium
- 2.4 Applications of alkane dehydrogenation
- 2.5 Summary and outlook
- References
- Chapter 3. Transition metal-catalyzed dehydrogenation of methanol and related transformations
- Abstract
- 3.1 Introduction
- 3.2 Hydrogen production
- 3.3 N-Methylation reactions
- 3.4 N-Formylation reactions
- 3.5 C-Methylation reactions
- 3.6 N-Heterocycles synthesis
- 3.7 Miscellaneous transformations
- 3.8 Conclusion
- References
- Chapter 4. Transition metal pincer complexes in acceptorless dehydrogenation reactions
- Abstract
- 4.1 Introduction
- 4.2 Acceptorless dehydrogenation
- 4.3 Conclusion and future perspective
- Acknowledgments
- References
- Chapter 5. An outlook on the applications of pincer-metal complexes in catalytic dehydrogenation chemistry
- Abstract
- References
- Index
- No. of pages: 244
- Language: English
- Edition: 1
- Published: November 9, 2021
- Imprint: Elsevier
- Paperback ISBN: 9780128220917
- eBook ISBN: 9780128220924
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