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Phase Equilibrium Engineering
- 1st Edition, Volume 3 - April 2, 2013
- Authors: Esteban Alberto Brignole, Selva Pereda
- Language: English
- Hardback ISBN:9 7 8 - 0 - 4 4 4 - 5 6 3 6 4 - 4
- eBook ISBN:9 7 8 - 0 - 4 4 4 - 5 9 4 7 1 - 6
Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering ap… Read more
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Request a sales quoteTraditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs.
Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions.
The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering.
- Methodologies are discussed using relevant industrial examples
- The molecular nature and composition of the process mixture is given a key role in process decisions
- Phase equilibrium diagrams are used as a drawing board for process implementation
Chemical engineers, chemical industry R&D scientists and process engineering professionals, and graduate students in Applied Process Thermodynamics
Series Page
Foreword
Preface
Chapter 1. Phase Equilibrium and Process Development
1.1 The World of Phase Equilibria in Chemical Processes
1.2 Thermodynamic Modeling in Process Development
1.3 Definition of Phase Equilibrium Engineering
1.4 Phase Scenarios in Separation, Materials, and Chemical Processes
1.5 The Phase Design and the Phase Engineering Tools
References
Chapter 2. Intermolecular Forces, Classes of Molecules, and Separation Processes
2.1 Intermolecular Forces
2.2 Classification of Molecules
2.3 Separation Process Technology and Classes of Mixtures
References
Chapter 3. Phase Equilibrium Diagrams
3.1 Gibbs Criteria for Phase Equilibrium: The Phase Rule
3.2 The Phase Regions of Pure Components
3.3 Classification of Binary Fluid-Phase Behavior Diagrams
3.4 Classification of Ternary Fluid-Phase Behavior Diagrams
3.5 Phase Diagrams for Multicomponent Systems
References
Chapter 4. Physical Properties and Thermodynamic Models
4.1 Thermodynamic Modeling and Simulation
4.2 Physical Properties of Pure Compounds
4.3 The Compressibility Factor of Gases
4.4 The Virial EOS
4.5 Corresponding State Correlations
4.6 Prediction of Phase Equilibria
4.7 Predictive Models
4.8 Semiempirical Models
4.9 Selection of Thermodynamic Models
4.10 Problems
Appendix 4A
Appendix 4B
References
Chapter 5. A General Approach to Phase Diagrams for Binary Systems
5.1 Introduction and Scope
5.2 A Case That Required Special Analysis and New Tools
5.3 Some Problems and Solutions Regarding the Automated Calculation of Phase Diagrams
5.4 Different Projections of ULPEDs
5.5 Restricted Phase Diagrams (Beyond the Typical Cases)
5.6 Remarks and Conclusions
5.7 Problems
References
Chapter 6. Phase Equilibrium Engineering Principles
6.1 Case Study: Biphenyl Recovery from the Bottoms of the Toluene Column
6.2 Case Study: Natural Gas Liquid Extraction from Natural Gas
6.3 Case Study: Supercritical Biodiesel Production Process
6.4 Principles of Phase Equilibrium Engineering
References
Chapter 7. Phase Equilibrium Engineering in Distillation
7.1 Distillation and Class of Phase Behavior
7.2 Fractional Distillation Principles
7.3 Thermodynamic Tuning of Fractional Distillation Columns
7.4 Thermodynamic Tuning of a Multicomponent Distillation Train
7.5 Case Study: Parameterization of the Ethylene Plant Recovery Section
7.6 Phase Equilibrium Engineering Guidelines for Thermodynamic Tuning of Fractional Distillation
7.7 Energy and Thermodynamic Sensitivity in Distillation
7.8 Summary
Appendix: Mathematical Modeling of Multistage Fractional Distillation
References
Chapter 8. Separation of Azeotropic Mixtures
8.1 Solvents or Entrainers as Separating Agents
8.2 Homogeneous Azeotropic Distillation
8.3 Heterogeneous Azeotropic Distillation
8.4 Selection of Solvents for Separation Processes
8.5 Synthesis of Solvents by CAMD
8.6 Solvent Design in Liquid–Liquid Extraction
8.7 Solvent Selection or Design in EXD
8.8 Case Study: Solvent and Process Design for the Recovery of the Aromatic Fraction of Reforming Naphtha
8.9 Summary
8.10 High-Pressure Azeotropic Distillation
Appendix 8A
References
Chapter 9. Green Processes and High-Pressure Solvents
9.1 SCF Solvents
9.2 Solvent Tuning in Type V Phase Behavior
9.3 Solvent Tuning in Type III Phase Behavior
9.4 Supercritical Solvent Mixtures
9.5 Particle Micronization with SCFs
9.6 Summary
References
Chapter 10. High-Pressure Fractionation and Extraction of Natural Oils
10.1 Supercritical Fractionation
10.2 Supercritical Fractionation Phase Design
10.3 Phase Equilibria of Natural Oils in SCFs
10.4 Case Studies of Fractionation of Natural Oils
10.5 Summary
References
Chapter 11. Phase Equilibrium Engineering Principles in Reactive Systems
11.1 Key Physicochemical Attributes of Supercritical Reactors
11.2 Solvent Selection: Phase Behavior of Reactive Mixture and Solvents
11.3 Phase Behavior of SCFs with Homologous Families of Organic Compounds
11.4 Case Study: Solvent Selection
11.5 Experimental Tools for Tracking Phase Behavior in Reactive Systems
11.6 Phase Condition Design: Boundaries of the Reactive System in Gibbs Diagrams
11.7 Phase Conditions Design: Boundaries of the Reactive System in PT Diagrams
References
Chapter 12. Phase Equilibrium Engineering in Conceptual Process Design
12.1 Introduction
12.2 Phase Equilibrium Engineering of the Transesterification Reaction
12.3 Supercritical Fluid Extraction and Dehydration of Alcohols from Water
12.4 Final Remarks
References
Index
- No. of pages: 346
- Language: English
- Edition: 1
- Volume: 3
- Published: April 2, 2013
- Imprint: Elsevier
- Hardback ISBN: 9780444563644
- eBook ISBN: 9780444594716
EB
Esteban Alberto Brignole
Esteban A. Brignole is Professor Emeritus at the Universidad Nacional Sur and Superior Researcher at CONICET PLAPIQUI, Bahai Blanca, Argentina. He is recognized as arguably the most prominent figure in Applied Thermodynamics in Latin America. His major research contributions are the pioneering work on molecular design of solvents and the novel integration of rigorous thermodynamic methods to process engineering, which have gained him international recognition. The leitmotif of his 50-year-long career has been the development of Chemical Engineering in Iberoamerican countries, where he has contributed to the establishment of successful programs of industry/academy collaboration and international cooperation. His idea of organizing EQUIFASE, while still in the early stages of his career, is an example of successful action to promote regional integration. The most prominent characteristic of his personality is his passion for progress and innovation, following Professor Brignole’s favourite quote from George Bernard Shaw: “The reasonable man adapts himself to the world; the unreasonable one persists in trying to adapt the world to himself. Therefore, all progress depends on the unreasonable man.”
Affiliations and expertise
Professor Emeritus, Universidad Nacional Sur and Superior Researcher, CONICET PLAPIQUI, Bahai Blanca, ArgentinaSP
Selva Pereda
Selva Pereda is Principal Researcher at the Argentinean National Research Council (CONICET) and Associate Professor at National South University, Argentina. Her research field of interest is the thermodynamic modelling of complex systems and its application to process and product conceptual design for the development of biorefineries. Her contributions are focused on the systematic application of thermodynamic tools to develop pressure-intensified technologies. She is an Editorial board member of the Elsevier Journal of Supercritical Fluids.
Affiliations and expertise
Principal Researcher, Argentinean National Research Council (CONICET) and Associate Professor, National South University, ArgentinaRead Phase Equilibrium Engineering on ScienceDirect