Perovskite Metal Oxides

Synthesis, Properties, and Applications

1st Edition - May 30, 2023
Editors: Srikanta Moharana, Tanmaya Badapanda, Santosh Kumar Satpathy, Ram Naresh Mahaling, Rajneesh Kumar
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 5 2 9 - 0
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 5 3 0 - 6

Perovskite Metal Oxides: Synthesis, Properties and Applications provides an overview on the topic, including the synthesis of various types of perovskites, their propertie… Read more

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Perovskite Metal Oxides: Synthesis, Properties and Applications provides an overview on the topic, including the synthesis of various types of perovskites, their properties, characterization and application. The book reviews the applications of this category of materials for photovoltaics, electronics, biomedical, fuel cell, photocatalyst, sensor, energy storage and catalysis, along with processing techniques of perovskite metal oxides with a focus on low-cost and high-efficiency methods, including various properties and probable applications in academia and industry. Other sections discuss strategies to improve the functionality of perovskite metal oxide materials, including chemical methods and controlling the size, shape and structure of the materials.

Finally, applications of perovskite metal oxides in energy conversion and storage, sensing and electronics are covered.

Cover
Title page
Table of Contents
Front Matter
Copyright
Contributors
Series editor biography
Preface to the series
Part One: Introduction to perovskite metal oxides
1: Concepts and recent advancements in perovskite metal oxides
Abstract
1.1: Introduction
1.2: Perovskite metal oxide
1.3: Structure–property relationship and role of tolerance factor
1.4: Applications of perovskite-phase metal oxide materials
1.5: Summary and future prospects
References
2: Metal oxide perovskites: Structure and properties
Abstract
2.1: Introduction
2.2: Crystal structure of perovskites
2.3: Different forms of perovskite structures
2.4: Properties of perovskites
2.5: Summary
References
3: An overview and recent progress of single and double perovskite metal oxides
Abstract
3.1: Introduction
3.2: Perovskite structure: A chameleon to material science
3.3: Double perovskites
3.4: Size effect and stability
3.5: Transition-metal oxides
3.6: Synthesis method
3.7: Applications
3.8: Recent achievements in applications
3.9: Prospects and challenges
3.10: Limitations
3.11: Conclusions
References
4: Nonstoichiometric perovskites and derivatives
Abstract
4.1: Introduction
4.2: Barium titanate
4.3: Applications of nonstoichiometric BT compounds
4.4: Various synthesis techniques of BT compounds
4.5: Effects of nonstoichiometry on BT compounds
4.6: Conclusions
References
5: Nonmetal oxide perovskite-based materials (carbon-based perovskites and halide-based perovskites)
Abstract
Conflict of interest
5.1: Introduction
5.2: Structure of nonmetal perovskite materials
5.3: Properties of perovskite materials
5.4: Nonmetal carbon-based perovskite materials
5.5: Nonmetal halide-based perovskite materials
5.6: Synthesis of perovskite materials
5.7: Applications of perovskite materials
5.8: Conclusions and future perspectives
References
Part Two: Synthesis and characterization of metal oxide perovskites
6: Conventional approaches to synthesis and deposition of perovskite metal oxides
Abstract
6.1: Introduction
6.2: Conventional perovskite metal oxide ceramics processing
6.3: Solid-state synthesis of perovskite metal oxide
6.4: General method of preparation of perovskite metal oxide nanoceramics
6.5: High-energy ball milling methods for the synthesis of perovskite metal oxide
6.6: Sol-gel synthesis of perovskite metal oxide
6.7: Chemical solution deposition method of perovskite metal oxides
6.8: Hydrothermal synthesis of perovskite metal oxide
6.9: Electrospinning of perovskite metal oxide
6.10: Flame-based techniques for the synthesis of perovskite metal oxide
6.11: Solvothermal reaction method of perovskite metal oxides
6.12: Conclusion and perspectives
References
7: Synthesis and characterization of perovskite-based QDs, 1D, 2D, and hierarchical nanomaterials
Abstract
7.1: Introduction
7.2: Perovskite nanomaterials
7.3: Literature
7.4: Motivations
7.5: Synthesis methods of perovskite nanomaterials
7.6: Characterizations of perovskite nanomaterials
7.7: Conclusions
7.8: Future prospective
References
Part Three: Perovskite-based composites and their characterization
8: Perovskite metal oxide-based composite materials: Potential candidates for electronics and optoelectronics
Abstract
8.1: Introduction
8.2: Crystal structure
8.3: Applications of MOPs
8.4: Summary and outlook
References
9: Barium zirconate—A simple perovskite with multidimensional applications
Abstract
9.1: Introduction to barium zirconate
9.2: A review on different techniques for synthesis of barium zirconate
9.3: Barium zirconate as a proton conducting electrolyte for solid oxide fuel cell
9.4: Microwave dielectric properties and applications
9.5: Photophysical properties of barium zirconate
9.6: Conclusion
References
10: Effect of rare-earth elements on perovskite composite materials
Abstract
10.1: General introduction: Origin and history of perovskites
10.2: Perovskites: Structure, stability, and classification
10.3: Synthesis methods
10.4: Effect of rare-earth doping on the host perovskite
10.5: Applications: Past, present, and future
References
11: Tuning of physical and chemical properties of perovskite ceramic materials through surface modifications
Abstract
11.1: Introduction
11.2: Experimental details
11.3: Effect of surface hydroxylation on composite film
11.4: Conclusions and future trends
References
12: Perovskite-type dielectric ceramic-based polymer composites for energy storage applications
Abstract
Conflict of interest statement
12.1: Introduction
12.2: Ceramic materials
12.3: Modulation of dielectric and electrical properties of BFO
12.4: Energy storage performance in perovskite-type dielectric ceramics
12.5: Summary
References
Part Four: Applications of perovskites
13: Electronic applications of perovskite
Abstract
13.1: General introduction
13.2: Transition metal oxide
13.3: Ferroelectrics and related materials
13.4: Phase transition
13.5: Diffuse phase transition (DPT)
13.6: Classification of ferroelectric oxides
13.7: Perovskite structure
13.8: Properties of perovskite oxides
13.9: Electronic application
13.10: Conclusions
References
14: Energy storage applications of perovskites
Abstract
14.1: Introduction
14.2: Classifications based on functionalities and their governing properties
14.3: Dielectric capacitors
14.4: Electrochemical capacitors
14.5: Batteries
14.6: Conclusion
References
15: Biomedical applications of perovskite-based materials
Abstract
Acknowledgments
15.1: Introduction
15.2: Perovskite-based materials and devices for biomedical imaging
15.3: Applications of perovskite nanoparticles in biology
15.4: Perovskite-based electrochemical biosensors
15.5: Conclusions
References
16: Perovskites for fuel cell applications
Abstract
16.1: Introduction
16.2: Perovskite as a cathode in SOFC
16.3: Perovskite as an anode in SOFC
16.4: Perovskite as electrolyte in SOFC
16.5: Perovskite as interconnects for SOFC
16.6: Perovskites in PEMFC
16.7: Synthesis and processing of perovskites
16.8: Conclusions
References
17: Perovskite material for photocatalysis
Abstract
Acknowledgment
17.1: Introduction
17.2: Perovskite material
17.3: Mechanism of photocatalysis
17.4: Properties of perovskite materials
17.5: Application of perovskite materials
17.6: Current status and future perspectives
References
Further reading
18: Perovskites in photoelectrochemical water splitting
Abstract
18.1: Introduction
18.2: Fundamentals of photoelectrochemical water splitting
18.3: Perovskite oxide materials for photoelectrochemical water splitting
18.4: Approaches to employ perovskite for photoelectrochemical water splitting
18.5: Literature review of perovskite materials for photoelectrochemical water splitting
18.6: Summary and perspectives
18.7: Conclusion
18.8: Future challenges
References
19: Application of perovskites in solar cells
Abstract
19.1: Introduction
19.2: Perovskites and their suitability in solar cells
19.3: Hybrid organic–inorganic PSCs
19.4: Inorganic PSCs
19.5: Conclusions
References
20: Perovskite-based LEDs and lasers
Abstract
20.1: Introduction
20.2: Perovskite materials for light emission
20.3: Light-emitting devices
20.4: Stability of perovskite material sampling
20.5: Stability of perovskite LEDs
20.6: Perspective: Electrically pumped perovskite lasers
20.7: Inorganic perovskite based laser’s devices
20.8: Conclusion
References
21: Perovskite-based electrochemical sensing of ion and gas molecules: An overview
Abstract
21.1: Introduction
21.2: Metal ions, gases, and their toxic effects
21.3: Perovskite structure
21.4: Sensing mechanism
21.5: Perovskite for gas and ion sensors
21.6: Gas sensing parameters
21.7: Future perspectives on perovskite-based sensors
21.8: Conclusion
References
22: Perovskite in catalysis and electrocatalysis
Abstract
22.1: Introduction
22.2: Perovskite structure and properties
22.3: Catalytic properties of perovskite materials
22.4: Electrocatalytic properties of perovskite materials
22.5: Conclusion
References
23: Ferroelectric perovskite thin films as nonvolatile computer memories
Abstract
23.1: Introduction
23.2: Ferroelectricity in perovskite oxides
23.3: Important parameters in ferroelectric thin films
23.4: Material selection for memory application
23.5: Synthesis of perovskite ferroelectric thin film
23.6: Stability of the thin films
23.7: Working of ferroelectric piezoelectric thin films as nonvolatile computer memories
23.8: Summary
References
24: Ferroelectric perovskites as electro-optic switching devices, modulators and optical memory
Abstract
24.1: Introduction
24.2: Perovskite crystal structure and ferroelectricity
24.3: Spontaneous electric polarization
24.4: Origin of electric field-induced strain behavior
24.5: Electro-optic effect
24.6: Transparent electro-optic perovskites
24.7: Optical switches
24.8: Electro-optic modulators
24.9: Optical memory
24.10: Conclusions and future perspectives
References
25: Development of less toxic perovskite materials for solar cell applications
Abstract
25.1: Introduction
25.2: Material structure
25.3: Pb-based halide perovskites materials
25.4: Current status of lead-free perovskites for solar cell applications
25.5: Conclusions and future prospects
References
26: Perovskite-based light detectors (pyrodetectors)
Abstract
26.1: Introduction
26.2: Fundamentals of light detectors
26.3: Light detection and characterization
26.4: Operating principles
26.5: Fabrication process and material specifications
26.6: Conclusions
References
Index

Srikanta Moharana

Dr. Srikanta Moharana is an Assistant Professor at the Department of Chemistry, School of Applied Sciences, Centurion University of Technology and Management, Odisha, India. He obtained his Ph.D. and M.Phil. degrees in Chemistry from the School of Chemistry, Sambalpur University, India. He has received his M.Sc. degree in Chemistry from National Institute of Technology, Rourkela. He was awarded Prof. GB Behera Best PhD thesis award under the banner of Orissa chemical society, India. His research experience as well as research interests, lies in graphene, carbon nanotubes and ceramic based polymer nanocomposites synthesis and Characterization for advanced energy storage applications. He is a life member of Orissa Chemical Society.

Affiliations and expertise

Assistant Professor, Department of Chemistry, School of Applied Sciences, Centurion University of Technology and Management, Odisha, India

Tanmaya Badapanda

Dr. Tanmaya Badapanda currently works as an Associate Professor in the Department of Applied Physics, C.V. Raman Global University, Bhubaneswar. He has completed his master’s degree and PhD from NIT, Rourkela in the field of Material Science. He has more than 12 years of research and teaching experience and has published around 80 papers in journals of international repute. He was nominated for the Young Scientist Award (2014 & 2015) by the Indian National Science Association, Delhi and a recipient of the Young Scientist Award in 2013 given by the Odisha Physical Society. He is a reviewer of reputed journals published by Elsevier, Springer, Taylor & Francis, Wiley etc. and has received an outstanding reviewer award from Elsevier and the American Ceramic Society. He is a life member of the Indian Association of Physics Teachers and Orissa Physical Society. He is a Principal Investigator of the CSIR-funded project on polymer composites for embedded capacitors. His research interests include: ferroelectric and piezoelectric materials, energy harvesters, polymer composites.

Affiliations and expertise

Associate Professor, Department of Physics, C.V. Raman College of Engineering, Bhubaneswar, Odisha, India

Santosh Kumar Satpathy

Santosh Kumar Satpathy is an Assistant Professor in the Department of Physics at Centurion University of Technology and Management, Odisha, India. His areas of research are ferroelectrics, advanced ceramic materials, multiferroics, polymers, ceramic composites, and other ceramic materials for the application of perovskite materials.

Affiliations and expertise

Assistant Professor, Department of Physics, School of Applied Sciences, Centurion University of Technology and Management, Odisha, India

Ram Naresh Mahaling

Dr. Ram Naresh Mahaling is a Reader in the School of Chemistry, Sambalpur University since 2017. He has received his Ph.D. in Polymeric and Elastomeric Nanocomposites from the Materials Science Centre, Indian Institute of Technology (IIT), Kharagpur, India. He has more than 10 years of teaching and 14 years of research experience and has published more than 55 research papers in peer-reviewed journals and authored three book chapters. His current areas of research include the synthesis of perovskite-type metal oxide (BaTiO3, BiFeO3, CaTiO3, etc) based polymer composite materials for electronic applications and energy storage, nanocomposites and structure-properties relationships. He has visited the Institute of Polymer Research Dresden, Germany, and University of Orleans, France for two-and-half years as a Postdoctoral Fellow. He has received three (03) research projects from different funding agency, (01) Government of Odisha, 01(UGC New Delhi) and 01 (DST SERB, New Delhi). Twelve (12) M.Phil students and two (02) Ph.D students have been awarded under his guidance.

Affiliations and expertise

Associate Professor, School of Chemistry, Sambalpur University, Odisha, India

Rajneesh Kumar

Dr. Rajneesh Kumar is an Associate Professor at Banaras Hindu University, Varanasi, U.P, India since October 2017. He earned his M.Sc from Banaras Hindu University in the specialization of Nuclear Physics and has completed his Ph.D at the Institute for Plasma Research, Gandhinagar, India in the field of plasma antennas. After he earned his Ph.D, he was a post-doctoral fellow at LAPALCE, University of Toulouse France where he worked on plasmas as metamaterials and plasma photonic crystals for microwave invisibility and post-doctoral research associate in Masdar Institute of Science and Technology, Abu Dhabi, UAE where he worked on plasma technology for waste to energy applications. He was a project scientist at the Indian Institute of Technology, Kanpur, U.P. India and worked on pulsed laser deposition systems for thin films and then became an Assistant Professor in Dr. Harisingh Gour Central University, Sagar, M.P., India. He has co-authored 30 articles in reputed international journals. He is a life member of the Plasma Science Society of India.

Affiliations and expertise

Associate Professor, Department of Physics, Banaras Hindu University, Varanasi, U.P., India

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Perovskite Metal Oxides

Synthesis, Properties, and Applications

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Srikanta Moharana

Tanmaya Badapanda

Santosh Kumar Satpathy

Ram Naresh Mahaling

Rajneesh Kumar

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