ROBOTICS & AUTOMATION
Empowering Progress
Up to 25% off Essentials Robotics and Automation titles
Organic Radicals
- 1st Edition - March 14, 2024
- Editors: Chuanyi Wang, Abdellkader Labidi, Eric Lichtfouse
- Language: English
- Paperback ISBN:9 7 8 - 0 - 4 4 3 - 1 3 3 4 6 - 6
- eBook ISBN:9 7 8 - 0 - 4 4 3 - 1 3 3 4 7 - 3
Organic Radicals summarizes the applications of these materials in several fields, in addition to analyzing challenges, limitations and impacts of materials containing organic r… Read more
Purchase options
Institutional subscription on ScienceDirect
Request a sales quoteOrganic Radicals summarizes the applications of these materials in several fields, in addition to analyzing challenges, limitations and impacts of materials containing organic radicals on human, plants, water, soil, and animals. Sections cover uses of organic radicals as effective precursors for block molecules building and discuss their effectiveness as precursors of organic radical- containing materials synthesis and their applications in medicine, biology, electronics, environmental sciences, plastics synthesis, polymers building and the several impacts after organic radicals uses. In recent years, the rapid development of organic radical-containing materials has afforded an interesting research area in various applications.
- Covers the main proprieties and current techniques in organic radicals’ measurements, advantages, and disadvantages
- Analyzes the lifecycle analysis and the stability of organic radicals, their biodegradability, and biocompatibility
- Provides a comprehensive overview about the chemical synthesis of organic radicals, their physiochemical proprieties, and risks caused by the presence of high amounts of organic radicals
Postgraduate students and researchers in the field of Organic Chemistry and Environmental Chemistry
- Cover image
- Title page
- Table of Contents
- Copyright
- List of contributors
- About the editors
- Preface
- Introduction
- Chapter 1. Biodegradability, life cycle analysis, and biocompatibility of organic radicals
- Abstract
- 1.1 Introduction
- 1.2 Life cycle of organic free radicals
- 1.3 Generation of organic free radicals
- 1.4 Thermal decomposition
- 1.5 Reaction of organic free radicals
- 1.6 Reaction with other free radicals
- 1.7 Reaction with electron-rich molecules
- 1.8 Termination of organic free radicals
- 1.9 Radical–radical combination
- 1.10 Reaction with other molecules
- 1.11 Cage escape
- 1.12 Biodegradation of organic radicals
- 1.13 Biocompatibility of organic free radicals
- 1.14 Conclusion
- References
- Chapter 2. Toxicity of organic radicals for humans, plants, soils, and other living organisms
- Abstract
- 2.1 Toxicity of organic radicals for plants
- 2.2 Toxicity of organic radicals for animals
- 2.3 Toxicity of organic radicals for microbes
- 2.4 Toxicity of organic radicals in soils
- 2.5 Conclusions and future research needs
- References
- Chapter 3. Biological aspects of organic radicals
- Abstract
- 3.1 Introduction
- 3.2 Biological aspects of organic radical
- 3.3 Conclusions
- Acknowledgments
- Conflict of interest
- Funding
- References
- Chapter 4. Fundamental characteristics of organic radicals used in biomedical applications
- Abstract
- 4.1 Introduction
- 4.2 Biomedical applications of organic radical materials
- 4.3 Discussions and conclusions
- Acknowledgments
- Conflict of interest
- Funding
- References
- Chapter 5. Preparation and characterization of magnetic and magnetophotonic materials based on organic free radicals
- Abstract
- 5.1 Introduction
- 5.2 Organic high-spin molecules
- 5.3 Determination of ground state multiplicity in organic high-spin molecules
- 5.4 Synthetic chemistry of stable radicals toward organic high-spin systems
- 5.5 Pure organic magnets
- 5.6 Radical-based redox-switchable materials
- 5.7 Molecular photoswitchable systems that are based on radicals
- 5.8 Magnetophotonic and magnetic materials based on complexes of metals with radicals
- 5.9 Conclusion
- References
- Chapter 6. Luminescent organic radicals toward breakthrough of organic optoelectronics
- Abstract
- 6.1 Introduction
- 6.2 Luminescence mechanism
- 6.3 Key parameters
- 6.4 Molecular design principles
- 6.5 Material types of luminescent organic radicals
- 6.6 Applications
- 6.7 Conclusion and outlook
- References
- Chapter 7. Photocatalyst materials formed using organic radicals for water splitting
- Abstract
- 7.1 Introduction
- 7.2 Insight about the organic radicals
- 7.3 (Photo) catalytic water splitting reaction
- 7.4 Mechanism of water splitting reaction
- 7.5 Current scenario and challenges
- 7.6 Conclusion
- Acknowledgments
- Conflicts of interest
- List of abbreviations
- References
- Chapter 8. Benzotriazole ring cleavage methodology under free radical condition: an ample opportunity in organic synthesis
- Abstract
- 8.1 Introduction
- 8.2 Thermal and photo-induced benzotriazole ring cleavage
- 8.3 Ring cleavage using radical initiator
- 8.4 Reagent-supported ring opening reaction
- 8.5 Transition metal–catalyzed benzotriazole ring cleavage process
- 8.6 Miscellaneous denitrogenative ring opening reaction
- 8.7 Conclusions and future perspectives
- Acknowledgment
- References
- Chapter 9. Free radical functionalization of polyethylene
- Abstract
- 9.1 Introduction
- 9.2 Radical functionalization of polyethylene
- 9.3 Conclusions
- References
- Chapter 10. Materials based on organic radicals used in electrochemical applications
- Absract
- 10.1 Introduction
- 10.2 Organic radical polymers
- 10.3 Battery applications
- 10.4 Battery types
- 10.5 Principle of organic radical batteries
- 10.6 Conclusion
- Declaration of competing interest
- References
- Chapter 11. Materials based on organic radicals for gases capture
- Abstract
- 11.1 Introduction
- 11.2 Synthesis and structure of metal–organic frameworks
- 11.3 Synthesis and structure of covalent organic frameworks
- 11.4 Synthesis and structure of metal–organic polyhedras
- 11.5 Applications of gases capture, activation, and relevant catalytic reaction
- 11.6 Conclusion
- References
- Chapter 12. Organic radicals used to modify materials surface and their application to remove pharmaceutical residues from wastewater
- Abstract
- 12.1 Introduction
- 12.2 Organic radicals
- 12.3 Radical materials for pharmaceutical pollutants removal
- 12.4 Discussion
- 12.5 Conclusion
- Acknowledgments
- Declaration of competing interest
- References
- Chapter 13. Biochar containing persistent free radicals used for soil remediation
- Abstract
- 13.1 Introduction
- 13.2 The formation of persistent free radicals on biochar
- 13.3 Application of biochar-containing persistent free radicals for heavy metals reduction in soil
- 13.4 Application of persistent free radicals in organic pollutants degradation in soil
- 13.5 Conclusions and prospects
- Authors’ contribution
- References
- Chapter 14. Synthesis of and solid-state charge transport in conducting radical polymers
- Abstract
- 14.1 Introduction
- 14.2 Stable open-shell species used in radical polymers and polyradicals
- 14.3 Types of radical-bearing polymers
- 14.4 Synthetic methodologies of stable radical polymers
- 14.5 Charge transport in the radical polymers
- 14.6 Conclusion
- References
- Chapter 15. Organic radicals: formation, classification, and environmental application
- Abstract
- 15.1 Introduction
- 15.2 Overview of gaseous hazards in the atmosphere
- 15.3 Classification of gaseous pollutants removal techniques
- 15.4 Advanced oxidation processes
- 15.5 Organic radicals
- 15.6 Formation and utilization
- 15.7 Organic radicals for removing gaseous pollutants
- 15.8 Perspective
- 15.9 Conclusions
- References
- Index
- No. of pages: 446
- Language: English
- Edition: 1
- Published: March 14, 2024
- Imprint: Elsevier
- Paperback ISBN: 9780443133466
- eBook ISBN: 9780443133473
CW
Chuanyi Wang
Dr. Chuanyi Wang, Fellow of Royal Society of Chemistry, is a distinguished professor at Shaanxi University of Science & Technology (SUST), PR China, serving as an academic dean of the School of Environmental Science and Engineering. Before moving to SUST in 2017, he was a distinguished professor of Chinese Academy of Sciences (CAS), serving as Director of Laboratory of Environmental Science & Technology of Xinjiang Technical Institute of Physics & Chemistry, CAS (2010-2017). He obtained his Ph.D. degree from Institute of Photographic Chemistry (now Technical Institute of Physics and Chemistry) of CAS in 1998, worked in Germany (Institute for Solar Energy Research in Hannover and Free University Berlin) as an Alexander von Humboldt research fellow with Prof. Detlef W. Bahnemann from 1999 to 2000, and then worked in USA (Tufts University and Missouri University-Kansas City) as a research faculty from 2000 to 2010. Currently, Dr. Wang also serves as an associate editor or editorial board member for number of international journals including Environmental Chemistry Letters and Molecular Catalysis. His research interests cover ecomaterials and environmental photocatalysis. He has published over 270 papers in peer reviewed journals with an H-index of 63.
https://www.scopus.com/authid/detail.uri?authorId=55796485900
Affiliations and expertise
School of Environmental Science and Engineering, Shaanxi University of Science and Technology, Weiyang District, Xi'an, Shaanxi, P.R.ChinaAL
Abdellkader Labidi
Abdellkader Labidi obtained his first degree from University of Sciences of Tunis and stayed there to complete his PhD in 2017 under the supervision of Prof. Manef Abderrabba. In 2018, he joined the team of his thesis ‘supervisor as a research scholar in the Laboratory of Materials, Molecules and Applications, IPEST, Preparatory Institute of Scientific and Technical Studies of Tunis, University of Carthage, La Marsa, Tunisia. During four years, he worked as a supervisor of master students and he has an experience of teaching at the Private University of Tunis in 2019. He is now carrying out his postdoctoral research under the supervision of Prof. Chuanyi Wang at Shaanxi University of Science and Technology.
Affiliations and expertise
Shaanxi University of Science and Technology, ChinaEL
Eric Lichtfouse
Eric Lichtfouse is a professor at the Xi’an Jiaotong University. He has invented carbon-13 dating, a molecular-level method allowing to study of the dynamics of organic compounds in temporal pools of complex environmental media. He has discovered temporal pools of individual substances in complex media such as soils. He is a chief editor and founder of the journal Environmental Chemistry Letters. He is the author of the book Scientific Writing for Impact Factor Journals, which includes a new writing tool, the microarticle, allowing to identify results novelty. He has awards in analytical chemistry and scientific editing.
Affiliations and expertise
Xi'an Jiaotong University, ChinaRead Organic Radicals on ScienceDirect