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Organic Functional Group Analysis
International Series of Monographs on Analytical Chemistry, Volume 8
- 1st Edition - January 1, 1963
- Author: F. E. Critchfield
- Editors: R. Belcher, L. Gordon
- Language: English
- Paperback ISBN:9 7 8 - 0 - 0 8 - 0 1 3 5 0 0 - 7
- eBook ISBN:9 7 8 - 1 - 4 8 3 1 - 3 6 1 2 - 7
Organic Functional Group Analysis deals with versatile and reliable chemical methods for the analysis of most of the more common organic functional groups. The minimum number of… Read more
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Request a sales quoteOrganic Functional Group Analysis deals with versatile and reliable chemical methods for the analysis of most of the more common organic functional groups. The minimum number of methods required to solve the maximum number of problems is presented. The scope and known limitations of each method are discussed so that analytical chemists can decide whether the method under consideration can be applied to their particular problem. The methods are either titrimetric or colorimetric in nature. This volume is comprised of 11 chapters and begins with an overview of the analytical methods used for organic functional groups, including both titrimetric and colorimetric methods. The discussion then turns to the properties of acids and bases; selection of the best acid-base method for a particular purpose; and some of the more useful acid-base methods. Subsequent chapters explore methods for the determination of nitrogen compounds such as amines and amides; carbonyl compounds and derivatives; hydroxyl compounds such as tertiary alcohols; unsaturated compounds; 1,2-epoxy compounds; esters and peroxides; carboxylic acid anhydrides; and sulfur compounds. This book is intended for analytical chemists.
Preface
1. Introduction
Techniques
2. Acids and Bases
Selection of Acid-Base Method
Differentiations
Indicators
Methods
References
3. Nitrogen Compounds
Amines
Amides
Miscellaneous
References
4. Carbonyl Compounds and Derivatives
Hydroxylamine Hydrochloride-Triethanolamine Methods
Hydroxylamine Hydrochloride-Dimethylethanolamine Method
Hydroxylammonium Formate
Mercurimetric Determination of Aldehydes
2,4,-Dinitrophenylhydrazine Colorimetric Method
Summary
References
5. Hydroxyl Compounds
Acylation Methods
Cleavage of 1,2-Glycols
Hydrogen Bromide Method for Tertiary Alcohols (and Diols)
Bromination Method for Aromatic Hydroxyl Compounds
Colorimetric Methods
Summary
References
6. Unsaturated Compounds
Halogenation Methods
Morpholine Method
Mercuric Acetate Method
Silver Perchlorate Method
Summary
References
7. 1,2-Epoxy Compounds
Indirect Hydrogen Bromide Method
Direct Hydrogen Bromide Method
Pyridine Hydrochloride Method
Morpholine Method
Colorimetric Method
Summary
References
8. Esters
Saponification with Aqueous Potassium Hydroxide
Saponification in the Presence of Phenylhydrazine
Saponification with Potassium Hydroxide in Diethylene Glycol
Hydroxamic Acid Colorimetric Method
Summary
References
9. Carboxylic acid Anhydrides
Aniline-Sodium Hydroxide Method
Morpholine Method
Morpholine-Carbon Disulfide Method
Hydroxamic Acid Colorimetric Method
Summary
References
10. Peroxides
Sodium Iodide-Acetic Anhydride Method
Hydrogen Iodide-Acetic Acid Method
Ceric Ammonium Sulfate Method
Colorimetric Sodium Iodide-Acetic Anhydride Method
Summary
References
11. Sulfur Compounds
Titration of Mercaptans with Mercuric Perchlorate
Iodometric Method for Mercaptans
Potassium Bromate Method for Sulfides and Disulfides
Acid Hydrolysis of Alkyl Sulfates
Titration of Surface Active Sulfates and Sulfonates with Cetyl Pyridinium Bromide
Colorimetric Method for Surface Active Sulfates and Sulfonates
References
Index
- No. of pages: 196
- Language: English
- Edition: 1
- Published: January 1, 1963
- Imprint: Pergamon
- Paperback ISBN: 9780080135007
- eBook ISBN: 9781483136127