
NOx Related Chemistry
- 1st Edition, Volume 67 - January 8, 2015
- Imprint: Academic Press
- Editors: Rudi van Eldik, José A. Olabe
- Language: English
- Hardback ISBN:9 7 8 - 0 - 1 2 - 8 0 1 7 3 5 - 7
- eBook ISBN:9 7 8 - 0 - 1 2 - 8 0 1 8 3 7 - 8
NOx Related Chemistry is a volume of a series that presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemis… Read more

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Request a sales quote- Best-qualified scientists write on their own recent results dealing with basic fundamentals of NO-chemistry, with an eye into biological and environmental issues
- Editors and authors are recognized scientists in the field
- Features comprehensive reviews on the latest developments
- An indispensable reference to advanced researchers
Bioinorganic, inorganic, supramolecular and organometallic chemists
- Preface
- Chapter One: NOx Linkage Isomerization in Metal Complexes
- Abstract
- 1 Introduction
- 2 Linkage Isomerism in Non-Porphyrin NOx Complexes
- 3 Linkage Isomerism in NOx-Coordinated Metalloporphyrins
- 4 Conclusion
- Acknowledgment
- Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution
- Abstract
- 1 Introduction: General Scope
- 2 Complexes with n = 6
- 3 Complexes with n = 7
- 4 Complexes with n = 8
- 5 Conclusions
- Chapter Three: Recent Progress in Photoinduced NO Delivery With Designed Ruthenium Nitrosyl Complexes
- Abstract
- 1 Introduction
- 2 Photoactive Ru Nitrosyls: What We Knew Before Our Work
- 3 Photoactive {RuNO}6 Nitrosyls Derived from Pentadentate Polypyridine Ligands
- 4 Tuning the Photosensitivity of Ru Nitrosyls to Light of Longer Wavelengths
- 5 Incorporation of Ru Nitrosyls into Polymeric Matrices
- 6 Enhancement of Light Absorption of {Ru–NO}6 Nitrosyls Through Direct Attachment of Dyes
- 7 Conclusion
- Acknowledgments
- Chapter Four: Metal-Assisted Activation of Nitric Oxide—Mechanistic Aspects of Complex Nitrosylation Processes
- Abstract
- 1 Introduction
- 2 Nitric Oxide Activation by Iron(II)/(III) Centers
- 3 Nitric Oxide Activation by Ruthenium(III) Centers
- 4 Reductive Nitrosylation Reactions
- 5 Concluding Remarks
- Acknowledgments
- Chapter Five: New Insights on {FeNO}n (n = 7, 8) Systems as Enzyme Models and HNO Donors
- Abstract
- 1 Background
- 2 {FeNO}7 Complexes as Models for Nonheme Oxygenase Enzymes
- 3 {FeNO}7 Complexes as Precursors to {FeNO}8 Complexes
- 4 Diiron Complexes Containing {FeNO}7 Unit(s)
- 5 Summary and Outlook
- Chapter Six: Design, Reactivity, and Biological Activity of Ruthenium Nitrosyl Complexes
- Abstract
- 1 Introduction
- 2 Tetraaza Ruthenium Complexes
- 3 Polypyridine Ruthenium Complexes as NO Delivery Systems
- 4 UV–Vis Electronic Spectrum
- 5 Electrochemistry
- 6 FTIR
- 7 Photochemical Reactivity
- 8 Vasorelaxation
- 9 Cytotoxicity
- 10 Neglected Tropical Diseases
- 11 Trinuclear Oxo-Centered Ruthenium Carboxylates
- Chapter Seven: Complete and Partial Electron Transfer Involving Coordinated NOx
- Abstract
- 1 Introduction and Presentation of NOx Oxidation States
- 2 Nitrosylmetal Complexes Without Additional Redox-Active Ligands
- 3 Nitrosylmetal Complexes with Additional Redox-Active Ligands
- 4 Noninnocent Ligand Potential of the NO2−/NO2• Redox System
- 5 Conclusions
- Acknowledgments
- Chapter Eight: Oxidation Mechanism of Hydroxamic Acids Forming HNO and NO: Implications for Biological Activity
- Abstract
- 1 Introduction
- 2 HXs Oxidation In Vitro and In Vivo
- 3 Conclusions
- Acknowledgment
- Chapter Nine: Reaction Steps in Nitrogen Monoxide Autoxidation
- Abstract
- 1 History
- 2 Gas-Phase Reaction and Atmospheric Chemistry
- 3 Liquid-Phase Reaction and Biology
- 4 Thermochemistry and Kinetics
- 5 Mechanisms
- 6 Conclusions
- Acknowledgments
- Index
- Contents of Previous Volumes
- Edition: 1
- Volume: 67
- Published: January 8, 2015
- Imprint: Academic Press
- No. of pages: 388
- Language: English
- Hardback ISBN: 9780128017357
- eBook ISBN: 9780128018378
Rv
Rudi van Eldik
JO
José A. Olabe
Name: José Antonio OLABE
Position: Research staff of CONICET
Laboratory or research group: Coordination Chemistry Tel: 5411 4576-3378/89 ext.115
Fax: 5411 4576-3341 E-mail: [email protected]
Born in 1941, San Sebastián, Spain
Studies in Chemistry:
- Doctor in Chemistry (1968), University of La Plata
- Postdoc: Inorganic Chemistry (Prof. P.J.Aymonino), La Plata (1969-70)
- Teaching Positions: Emeritus Professor, Facultad de Cs. Exactas y Nat., UBA
- Position at CONICET: Class I Researcher
Topic of interest: Coordination Chemistry – Activation of small molecules - Catalysis
Awards and Recognitions: Konex Award in Inorganic Chemistry, 2003. President of the Argentine Phys.Chem.Research Society, 2003-2005. Vice-Dean: Facultad de Cs. Exactas y Nat., UBA, 1990-1998. Invited Lecturer in National and International Meetings and Symposia.
Selected Recent Publications
- “Three Redox States of Nitrosyl: NO+, NO• and NO–/HNO Interconvert Reversibly on the Same Pentacyanoferrate(II) Platform”, A.C.Montenegro, V.T.Amorebieta, L.D.Slep, D.F.Martín, F.Roncaroli, D.H.Murgida, S.E.Bari, J.A.Olabe, Angew. Chem. Int. Ed. 2009, 48/23, 4213-4216.
- “Addition and Redox Reactivity of Hydrogen Sulfides (H2S/HS-) with Nitroprusside: New Chemistry of Nitrososulfide Ligands”, S.L.Quiroga, A.E.Almaraz, V.T.Amorebieta, L.L.Perissinotti, J.A.Olabe, Chem. Eur. J., 2011, 17, 4145-4156.
- “Disproportionation of O-Methylhydroxylamine catalyzed by aquapentacyanoferrate(II)”, M.M.Gutiérrez, J.A.Olabe, V.T.Amorebieta, Inorg. Chem. 2011, 50, 8817-8825.
- “Nucleophilic Addition Reactions of the Nitroprusside Ion – The Case of O-Methylhydroxylamine”, M.M.Gutiérrez, J.A.Olabe, V.T.Amorebieta, Eur.J.Inorg.Chem. 2012, 4433-4438.
- “Nitrosyl-Centered Redox and Acid-Base Interconversions in [Ru(Me3[9]aneN3)(bpy)(NO)]3,2,1+. The pKa of HNO for its Nitroxyl Derivative in Aqueous Solution”, N. Osa Codesido, T. Weihermüller, J. A. Olabe, L. D. Slep, Inorg. Chem. 2014, 53, 981-997.
Other important Publications
- “Reactivity of Reduced Nitroprusside, [Fe(CN)5NO•]3−, toward Oxygen”, M.Videla, F.Roncaroli, L.D.Slep, J.A.Olabe, J. Am. Chem. Soc., 2007, 129, 278-279.
- “Release of NO from Reduced Nitroprusside Ion. Iron-Dinitrosyl Formation and NO-Disproportionation Reactions”, F.Roncaroli, R.van Eldik, J.A.Olabe, Inorg. Chem. 2005, 44, 2781-2790.
- “Metal Catalyzed Anaerobic Disproportionation of Hydroxylamine. Role of Diazene and Nitroxyl Intermediates in the Formation of N2, N2O, NO+ and NH3”, G.E.Alluisetti, A.E.Almaraz, V.T.Amorebieta, F.Doctorovich, J.A. Olabe, J. Am. Chem. Soc. 2004, 126, 13432-13442.
Reviews and Book Chapters
- “Chemistry of Bound Nitrogen Monoxide and Related Redox Reactions”, J. A. Olabe, en Physical Inorganic Chemistry: Reactions, Processes, and Applications, A. Bakac, Ed., Wiley, 2010, Cap. 7, (ISBN 0470224207).
- “The coordination chemistry of nitrosyl in cyanoferrates. An exhibit of bioinorganic relevant reactions”,(Perspective Article), JA.Olabe, Dalton Transactions, 2008, 3633-3648.
- “New Features on the Redox Coordination Chemistry of Metal Nitrosyls {(M-NO+; M-NO•; M-NO/HNO)}”, F. Roncaroli, M. Videla, L.D. Slep, J.A. Olabe, Coord. Chem. Rev., 2007, 251, 1903-1930.
- “Redox Reactivity of Coordinated Ligands in Pentacyano(L)Ferrate Complexes”, J.A. Olabe, Adv. Inorg. Chem. 2004, 55, 61-126.
- “Reactivity and Structure of Complexes of Small Molecules: Nitric and Nitrous Oxide”, J.A. Olabe, L.D.Slep, in: Comprehensive Coordination Chemistry II, From Biology to Nanotechnology, J.A. Mc Cleverty y T.J. Meyer, Eds., Pergamon, Vol. 1, Section III, Cap. 1.31, 2003, 603-623.