Nanomaterial-Based Metal Organic Frameworks for Single Atom Catalysis
- 1st Edition - May 26, 2023
- Imprint: Elsevier
- Editors: Awais Ahmad, Francis Verpoort, Ikram Ahmad, Sobia Tabassum, Abdur Rahim
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 8 2 4 5 2 4 - 8
- eBook ISBN:9 7 8 - 0 - 1 2 - 8 2 4 5 2 5 - 5
Nanomaterial-Based Metal Organic Frameworks for Single Atom Catalysis covers nanoparticles and their properties, including tunable pore size, efficient reacting capabilit… Read more
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Request a sales quoteNanomaterial-Based Metal Organic Frameworks for Single Atom Catalysis covers nanoparticles and their properties, including tunable pore size, efficient reacting capability, large surface area, and morphology, which make them effective catalytic agents. In addition, the book covers catalytic systems, in which nanomaterial-based metal organic frameworks can be applied efficiently as single atom catalysis to enable enhanced functionalities and activities of the reactions in various applications. This book is an important reference source that will be of use to materials scientists, engineers, chemists and chemical engineers who want to learn more about nanomaterials are being used for catalytic applications.
Metal organic frameworks (MOFs) are hybrid organic–inorganic, porous, crystalline nanomaterials, and have aroused great attention in the field of catalysis because of their crystalized nano- (lt;2 nm) or meso- (2–50 nm) porous structure, extremely high surface area, and significant chemical diversity. This nanomaterial-based metal organic framework, as a single atom catalysis, enhances the catalytic ability of dispersed single atoms.
- Provides information on the reactions catalyzed by single atom catalysts at the nanoscale
- Explains the major applications of metal-organic-framework-derived nanomaterials
- Assesses the major challenges of applying metal organic framework-derived nanomaterials on an industrial scale
Materials Scientists and Engineers
- Cover image
- Title page
- Table of Contents
- Copyright
- Dedication
- List of contributors
- Preface
- 1. Metal–organic frameworks (an overview)
- Abstract
- 1.1 Introduction
- 1.2 Metal–organic frameworks
- 1.3 What are the different types of MOFs?
- 1.4 Metal–organic framework properties
- 1.5 Potential applications of MOFs in single-atom catalysis
- 1.6 Conclusion
- List of abbreviations
- List of abbreviations of MOFs
- References
- 2. Nanomaterials and catalysis
- Abstract
- 2.1 Introduction
- 2.2 Catalytic reactions
- 2.3 Different kinds of nanomaterial-based MOFs
- 2.4 MOF-derived Pd-based nanomaterials
- 2.5 MOF-derived Au-based nanoparticles
- 2.6 MOF-derived carbon-based nanomaterials
- 2.7 MOF-derived Ni–C
- 2.8 Nanomaterial MOFs and their single-atom catalysis applications
- 2.9 Synthetic protocols and identification of MOF-based SACs
- 2.10 Conclusion
- References
- 3. Process and manufacturing of nanomaterial-based metal organic frameworks
- Abstract
- 3.1 Introduction
- 3.2 Functions of MOFs
- 3.3 Types of MOFs
- 3.4 Synthesis of MOFs
- 3.5 Functionalization of MOFs
- 3.6 Characterization of MOFs
- 3.7 MOF-derived nanomaterials
- 3.8 MOF-derived Fe3O4 and composite nanostructures
- 3.9 MOF-derived cobalt phosphide and composite nanostructures
- 3.10 Synthesis routes for MOFs
- 3.11 Conclusion
- References
- 4. Biological methods for fabricating nanomaterial-based metal–organic frameworks
- Abstract
- 4.1 Introduction
- 4.2 What is a metal–organic framework?
- 4.3 What are the different methods used for the fabrications of the metal–organic framework?
- 4.4 Biological methods for fabrications of nanomaterial-based MOF
- 4.5 Metal–organic framework application in single-atom catalysis
- 4.6 Conclusions
- List of abbreviations
- List of abbreviations of MOF
- References
- 5. Development and characterization of nano-MOFs
- Abstract
- Graphical abstract
- 5.1 Introduction
- 5.2 Metal–organic frameworks
- 5.3 History of MOFs
- 5.4 Preparation of MOFs
- 5.5 Linker or organic ligands and metal nodes
- 5.6 Metal nodes
- 5.7 Nanomaterials-based MOFs
- 5.8 Different types of synthesis of NPs@MOFs
- 5.9 Properties of nanomaterial-based MOFs
- 5.10 Hierarchical porous structure
- 5.11 Hollow structures
- 5.12 Core–shell structure
- 5.13 Size effects
- 5.14 Uniform and adjustable pore size
- 5.15 Selectivity ability
- 5.16 Adsorption ability
- 5.17 Photocatalytic ability
- 5.18 Nanomaterial-based MOFs and their application in single-atom catalysis
- 5.19 Potential applications of nanomaterial-based MOFs
- 5.20 Wastewater treatment
- 5.21 Catalytic degradation
- 5.22 Volatile organic compound degradation
- 5.23 MOF-derived nanomaterials for target-specific sensing
- 5.24 Heavy metal ion sensing
- 5.25 Conclusion
- References
- 6. Characterization and theoretical considerations of MOFs
- Abstract
- 6.1 Introduction
- 6.2 Theoretical considerations of MOFs
- 6.3 Structural characterization and stability
- 6.4 Characterization techniques
- 6.5 Conclusion
- References
- 7. Role of metal–organic frameworks in catalysis
- Abstract
- 7.1 Introduction
- 7.2 Events during catalysis by functionalized MOFs
- 7.3 MOFs for catalysis
- 7.4 Functionalized MOFs
- 7.5 Conclusion and future perspectives
- References
- 8. Single-atom catalysts
- Abstract
- 8.1 Introduction
- 8.2 Origins and evolution of single-atom catalysts
- 8.3 Characterization of single-atom catalysts
- 8.4 Synthesis of SACs
- 8.5 Applications of single-atom catalysts
- 8.6 Conclusion and future prospects
- References
- 9. Synthesis and properties of single-atom catalysts
- Abstract
- 9.1 Introduction
- 9.2 Synthesis methods for single-atom catalysts
- 9.3 Properties
- References
- 10. Role of MOFs as single-atom catalysts
- Abstract
- 10.1 Introduction
- 10.2 Single atoms confined in metal–organic frameworks
- 10.3 MOF-based SACs
- 10.4 MOF-based SACs for catalysis
- 10.5 Conclusion and future perspective
- References
- 11. Effects of nanomaterial-based MOFs on single-atom catalysis
- Abstract
- 11.1 Introduction
- 11.2 Compositional manipulation
- 11.3 Basic structure of nanomaterial-based MOFs
- 11.4 Porosity and surface area
- 11.5 Functional role in heterogeneous catalysis
- 11.6 Conclusion
- References
- 12. Applications of MOF-derived single-atom catalysts
- Abstract
- 12.1 Introduction
- 12.2 Properties of nanomaterial-based MOFs
- 12.3 Applications of nanomaterial-based MOFs
- 12.4 Bottlenecks
- 12.5 Conclusions and perspectives
- References
- 13. Nanomaterial-based MOF-derived single-atom catalysts for electrolytic conversion of energy
- Abstract
- 13.1 Introduction
- 13.2 Metal–organic framework nanostructures
- 13.3 MOF-derived SACs for energy conversion
- 13.4 Conclusion and perspectives
- References
- 14. Advantages of using MOFs as single-atom catalysts
- Abstract
- 14.1 Introduction
- 14.2 Compositional manipulation
- 14.3 Morphology control
- 14.4 Power of SACs and recent advances
- 14.5 Conclusion
- References
- Index
- Edition: 1
- Published: May 26, 2023
- No. of pages (Paperback): 358
- No. of pages (eBook): 358
- Imprint: Elsevier
- Language: English
- Paperback ISBN: 9780128245248
- eBook ISBN: 9780128245255
AA
Awais Ahmad
Dr. Awais Ahmad is a Researcher at the Department of Organic Chemistry, University of Cordoba in Spain. He completed his graduation from Government College University Faisalabad, Pakistan, and obtained his master's degree from the University of Lahore, Pakistan. Dr. Ahmad's research focuses on various areas including nanomaterials, composite materials, coated materials, heterogeneous catalysis, MOF, self-sacrifice MOF, single atom catalysis, photocatalysis, and electrochemical sensor formulations. He has applied these materials to address challenges in wastewater treatment, heavy metal removal, organic pollutant degradation, CO2 conversion, supercapacitors, dye-sensing solar cells, gel electrolytes, hazardous metal sensing in wastewater, conversion of hazardous gases, nitrogen fixation, catalysis for organic transformation, Li-S batteries, GCE nafion fiber, and water splitting.
Affiliations and expertise
Researcher, University of Cordoba, SpainFV
Francis Verpoort
For about two decades, Prof. Francis Verpoort has carried out broad and fruitful teaching and research activity at Ghent University in various areas of materials chemistry, including organometallics, catalysis, molecular spectroscopy, related with notable applications in the production of fine chemicals and advanced polymeric materials. He has developed an extensive international scientific cooperation with scientists worldwide, taking part as an active member in different international scientific organizations, as well as in numerous successful bilateral collaboration projects with foreign academic institutions and universities across Europe, China, Russia, India, and in the UAE. In 2011, he was also appointed as Chair Professor at Wuhan University of Technology, China, where he established a research group covering organometallics and materials chemistry. Prof. Verpoort’s main research interests concern the structure and mechanisms of organometallic material chemistry, homogeneous and heterogeneous catalysis, MOFs and MOPs, Porous Organic Polymers (POPs), water splitting, olefin metathesis and its applications in fine chemicals and polymers, CO2 conversion, polymers. A particular specialism is the application of MOFs, POPs for the environment, water purification, and downstream upgrading applications.
Affiliations and expertise
Professor, Inorganic and Physical Chemistry, Ghent University, Ghent, BelgiumIA
Ikram Ahmad
Dr. Ikram Ahmad is an assistant professor in the Department of Chemistry at the University of Sahiwal, Pakistan. His research interests are inorganic material chemistry, catalysis, nanomaterials and their application in organic synthesis, organic transformations, degradation, sensing, and photocatalysis.
Affiliations and expertise
Assistant Professor, Department of Chemistry, The University of Sahiwal, Sahiwal, PakistanST
Sobia Tabassum
Sobia Tabassum is Associate Professor in the Department of Biological Science at the International Islamic University, Islamabad, Pakistan. Her research interests are in molecular biotechnology and pharmaceutical chemistry, focusing on efficient combinatorial therapies using combination analysis of natural epigenetic drugs and nanoparticles for targeted drug delivery system in cancer.
Affiliations and expertise
Assistant Professor, Department of Applied Chemistry, GC University Faisalabad, PakistanAR
Abdur Rahim
Abdur Rahim is Assistant Professor in the Interdisciplinary Research Centre in Biomedical Materials, COMSATS University Islamabad, Pakistan. His research areas include synthesis and characterization of 2D nanomaterials for sensors and biosensors applications, functionalization of mesoporous/nano-materials and application as sensors and biosensors, hybrid organic-inorganic materials synthesis for sensing and bio-sensing applications, biomimetic nanomaterials for biosensors applications, and plasmonic nanomaterials for sensors and biosensors applications.
Affiliations and expertise
Assistant Professor, Interdisciplinary Research Centre in Biomedical Materials, COMSATS University Islamabad, PakistanRead Nanomaterial-Based Metal Organic Frameworks for Single Atom Catalysis on ScienceDirect