MXenes as Surface-Active Advanced Materials

From Fundamentals to Industrial and Biomedical Applications

1st Edition - June 25, 2024
Editors: Mumtaz A. Quraishi, Chandrabhan Verma, Elyor Berdimurodov
Language: English
Paperback ISBN:
9 7 8 - 0 - 4 4 3 - 1 3 5 8 9 - 7
eBook ISBN:
9 7 8 - 0 - 4 4 3 - 1 3 5 9 0 - 3

MXenes as Surface-Active Advanced Materials: From Fundamentals to Industrial and Biomedical Applications covers numerous aspects of the basic science and applications of MXenes, i… Read more

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MXenes as Surface-Active Advanced Materials: From Fundamentals to Industrial and Biomedical Applications covers numerous aspects of the basic science and applications of MXenes, including synthesis, classification, structure, and properties, as well as applications in gas storage and separation, environment and catalysis, tribology, biomedicine, and more. The book focuses on the characterization, synthesis and properties of MXenes, including surface/interface chemistry properties and metal- MXenes interaction. Other sections illustrate the current and potential applications of these nanomaterials within industry and biomedicine. These include a through discussion of surface chemistry and surface interaction of MXenes with different materials, along with current and future applications.

This book provides a complete exploration of surface and interface applications of MXenes, highlighting established research and future perspectives, and is a valuable resource to scientists and professionals in the field of material science, nanotechnology, and 2D material chemistry.

Cover image
Title page
Table of Contents
Copyright
List of contributors
About the editors
Preface
Part I: MXenes: basics, surface/interface chemistry properties
1. MXenes: fundamental, properties, and classifications
Abstract
1.1 Introduction
1.2 The rise of MXenes
1.3 Structure
1.4 Property of MXenes
1.5 Property of titanium carbide MXene
1.6 Impacts of MXene modification on its properties
1.7 MXene-based composites
1.8 Classification of MXenes
1.9 Challenges of MXenes
1.10 Crystalline MAX phases and their 2D derivative MXenes
1.11 Exfoliation of MAX phases to MXenes
1.12 Conclusions
Acknowledgments
Notes
Authors contribution
References
2. MXenes synthesis and characterization
Abstract
2.1 What is MXene
2.2 Brief history
2.3 Structure of MXene
2.4 Synthesis of MXene
2.5 Strategies of MXene synthesis
2.6 In-situ electrochemical synthesis
2.7 Urea glass route
2.8 Bottom-up approach
2.9 Exfoliation
2.10 An overview of MXenes applicants (in drug delivery)
2.11 Biomedicine
2.12 Photothermal treatment
2.13 Antibacterial function
2.14 Conclusion and outlooks
References
3. Metal–MXenes interaction: adsorption, bonding, and role of delocalized chemical bonding
Abstract
3.1 Introduction
3.2 Applications of MXenes
3.3 Bonding in MXenes
3.4 Metal–MXene interaction
3.5 Conclusion
3.6 Future perspectives
Acknowledgment
References
Part II: MXenes in industrial applications
4. Role of MXenes in catalysis
Abstract
4.1 Introduction
4.2 MXene-based catalysts for conventional heterogeneous (thermal) catalysis
4.3 MXene-based catalysts for electrocatalysis
4.4 MXene-based catalysts for photocatalysis
4.5 Conclusion and future outlook
References
5. MXenes in phase transfer catalysis
Abstract
5.1 Introduction
5.2 Phase transfer catalysis
5.3 MXenes: a new class of two-dimensional materials for advanced applications
5.4 MXenes as phase transfer catalysts: mechanistic insights
5.5 Conclusions and future perspectives
References
6. MXenes composites in water purification and environmental remediation
Abstract
6.1 Introduction
6.2 Synthesis
6.3 Features of MXenes
6.4 Applications of MXenes
6.5 MXenes for water method purification
6.6 Conclusions and outlooks
References
7. MXenes in toxic metal removal
Abstract
7.1 Introduction
7.2 Toxic metal removal methods
7.3 The synthesis of TiO2/MXenes Ti3C2
7.4 Toxic metals removal by batch adsorption onto TiO2/Ti3C2 MXenes
7.5 Toxic metals removal by fixed-bed column onto TiO2/Ti3C2 MXenes
7.6 Toxic metals removal by electrochemical process using TiO2/Ti3C2 MXenes
7.7 Toxic metals removal by photocatalysis using TiO2/Ti3C2 MXenes
7.8 Conclusion
Acknowledgment
References
8. Tribological applications of MXenes as surface-active advanced materials
Abstract
8.1 Introduction
8.2 MXenens in solid lubricants
8.3 MXenes as additives in lubricants
8.4 MXenes in composite materials
8.5 Conclusion and perspective
References
9. Gas storage applications of MXenes
Abstract
9.1 Introduction
9.2 Fundamentals, classification, synthesis, and modification of MXenes for gas storage
9.3 Challenges, limitations, and future directions
9.4 Conclusion
References
10. Anticorrosive applications of MXenes
Abstract
10.1 Introduction to anticorrosion of MXenes
10.2 Anticorrosive applications of MXenes
10.3 Future directions and potential
10.4 Conclusion
References
11. Applications of MXenes in gas separation and energy storage
Abstract
11.1 Introduction
11.2 Methods for the fabrication of 2D MXene-based membranes for separation
11.3 Application of MXene membranes for gas separation
11.4 MXenes in electrochemical energy storage
11.5 Conclusion and future prospectives
Acknowledgments
References
12. Sensing applications of MXenes
Abstract
12.1 Introduction
12.2 Chemical sensors
12.3 Biosensors
12.4 Electrochemical nonbiosensors
12.5 Physical sensors
12.6 Strain/stress sensors
12.7 Electrochemical sensors
12.8 Optical sensors
12.9 Humidity sensors
12.10 Conclusions
Acknowledgments
Notes
Authors contribution
References
13. MXenes in electrocatalysis
Abstract
13.1 Introduction
13.2 Electrolysis
13.3 Fuel cells
13.4 Conclusions
Acknowledgments
References
14. 2D-MXenes nanosheets/polymer composites’ electromagnetic shields, mechanical and thermal properties
Abstract
14.1 MXene is a new versatile two-dimensional nanomaterial
14.2 MaX electromagnetic interference shielding properties
14.3 MaX thermal properties
14.4 MaX mechanical properties
14.5 Future Prespective of MXene
References
Part III: MXenes in biomedical application
15. MXenes in tissue engineering
Abstract
List of Abbreviations
15.1 Introduction
15.2 Functionalization and modification of MXene surfaces
15.3 Potential biomedical applications of MXenes
15.4 Conclusion and outlook
References
16. Antimicrobial applications of MXenes
Abstract
16.1 Introduction
16.2 Impact of two-dimensional nanomaterials in infectious disease
16.3 The mode of action of MXenes
16.4 Effectors of MXenes antimicrobial activity
16.5 Biocompatibility and cytotoxicity of MXenes
16.6 Applications of MXenes as antimicrobial agents in food packaging and textiles, wound healing and point of use water treatment
16.7 Limitations and future applications
16.8 Conclusions
References
17. MXenes in drug delivery
Abstract
17.1 Introduction
17.2 Cellular uptake
17.3 Biocompatibility
17.4 Biodistribution
17.5 MXene/cobalt
17.6 MXene/agarose hydrogel
17.7 MXene/AuNRs
17.8 Conclusions and future outlook
References
18. MXenes in imaging
Abstract
List of abbreviations
18.1 Introduction
18.2 Fluorescence microscopy
18.3 Photoacoustic imaging
18.4 X-ray computed tomography
18.5 Magnetic resonance imaging
18.6 Mass cytometry and high-dimensional imaging
18.7 MXenes in multimode imaging
18.8 Conclusion and future outlook
References
19. MXenes as the theranostic materials
Abstract
19.1 Introduction
19.2 The manufacturing procedure for MXenes
19.3 MXenes for theranostic materials
19.4 Opportunities and challenges
19.5 Conclusion and future prospects
References
20. Antiviral application of MXenes
Abstract
20.1 Introduction
20.2 Antiviral applications and properties of two-dimensional MXenes
20.3 Some other activities of MXenes unleashing the potential as a promising antiviral nanomaterial
20.4 Conclusions
References
Further reading
21. MXenes in photothermal therapy
Abstract
Abbreviations
21.1 Introduction
21.2 Hyperthermic ablation
21.3 Mechanism of light to heat conversion in MXene
21.4 Photothermal agents
21.5 Why MXene is the better option
21.6 Photothermal therapy using MXenes
21.7 Synergistic multitherapy
21.8 Synergistic photothermal therapy and imaging
21.9 Combined photothermal therapy and bone reconstruction
21.10 Conclusions and future perspectives
Acknowledgments
References
Index

Mumtaz A. Quraishi

Dr. Mumtaz A. Quraishi is a Chair Professor at the Interdisciplinary Center for Research in Advanced Materials at King Fahd University of Petroleum and Minerals, Saudi Arabia. He obtained his Ph.D. in synthetic organic chemistry in 1986 from Kurukshetra University, India, and D.Sc. in corrosion inhibition in 2004 from Aligarh Muslim University, India. He has published more than 400 papers in reputed international journals and has been teaching for over 40 years. He is a fellow of Royal Society of Chemistry, UK. He has received several prestigious awards, including Life Time Achievement Award (International Science Congress Association, ISCA), Meritorious and Excellence in Corrosion Award (NACE, India), MASCOT award (ECI, India), Vigyan Ratna Award (CST, India) and is a member of Editorial Board of many International Journals. His current research area is designing of green corrosion inhibitors.

Affiliations and expertise

Chair Professor, Interdisciplinary Center for Research in Advanced Materials, King Fahd University of Petroleum and Minerals,Dhahran, Saudi Arabia.

Chandrabhan Verma

Chandrabhan Verma, PhD, works at the Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia. He is a member of the American Chemical Society (ACS). His research interests mainly focus on the synthesis and design of environment-friendly corrosion inhibitors used for several industrial applications. Dr. Verma received his PhD degree from the Department of Chemistry at IITBHU, Varanasi, India and MSc degree in organic chemistry (Gold Medalist). Dr. Verma is the author of several research and review articles in peer-reviewed international journals. He has also received several national and international awards for his academic achievements.

Affiliations and expertise

Researcher, Department of Chemical and Petroleum Engineering, Khalifa University, Abu Dhabi, United Arab Emirates

Elyor Berdimurodov

Dr. Elyor Berdimurodov is an Associate Professor at the National University of Uzbekistan. He has studied in the Ph.D. program at Tianjin University and the National University of Uzbekistan. He was a researcher at Tianjin University, Karshi State University, and Changchun Applied Chemistry Institute (Chinese Academy of Science), China. He was a participant in several international and domestic studies and research programs, including Chinese Government Scholarships, Chinese Great Belt program, National Basic Research Program, and more. His research interests include corrosion science, particularly powerful corrosion inhibitors, quantum chemistry, material science, green chemistry, nanochemistry and electrochemistry.

Affiliations and expertise

Associate Professor, Faculty of Natural Sciences, National University of Uzbekistan, Karshi State University, Faculty of Natural Sciences, Karshi, Uzbekistan.

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MXenes as Surface-Active Advanced Materials

From Fundamentals to Industrial and Biomedical Applications

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Mumtaz A. Quraishi

Chandrabhan Verma

Elyor Berdimurodov