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Molecular Properties V4
1st Edition - January 28, 1970
Editor: Douglas Henderson
eBook ISBN:9780323142205
9 7 8 - 0 - 3 2 3 - 1 4 2 2 0 - 5
Physical Chemistry: An Advanced Treatise, Volume IV: Molecular Properties provides the aspects of the properties of single molecules and physical methods available for their… Read more
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Physical Chemistry: An Advanced Treatise, Volume IV: Molecular Properties provides the aspects of the properties of single molecules and physical methods available for their determination. This book discusses linear polyatomic molecules, quantum-mechanical theory of vibrations, spectra of organic molecules, production and detection of free radicals, and force constants and molecular structure. The Hund's coupling cases for diatomic molecules, methods of measuring dipole moments, NMR spectra, and ESR spectra of organic species are also elaborated. This publication likewise covers the applications of the Mössbauer effect, electric deflection experiments, and effects of intramolecular motions on diffraction patterns. This volume is intended for graduate and physical chemistry students interested in molecular properties.
List of Contributors
Foreword
Preface
Contents of Previous and Future Volumes
Chapter 1 / The Variety of Structures Which Interest Chemists
I. Introduction
II. The Dynamic Aspects of Molecular Structures
References
Chapter 2 / Rotation of Molecules
I. Introduction
II. Diatomic Molecules
III. Linear Polyatomic Molecules
IV. Symmetric Tops
V. The Asymmetric Top; IA < IB < Ic
VI. Internal Rotation
VII. Spectroscopic Determination of Molecular Structure
VIII. The Stark Effect
IX. Quadrupole Hyperfine Structure
X. Instrumentation
References
Chapter 3 / The Vibrations of Molecules
I. The Classical Theory of Molecular Vibrations
II. Introductory Group Theory
III. The Quantum-Mechanical Theory of Vibrations
IV. Vibrational Spectra of Polyatomic Molecules
References
Chapter 4 / Vibrational Spectra of Molecules
I. Introduction
II. Spectra of Inorganic Molecules
III. Spectra of Organic Molecules
IV. Conclusion
References
Chapter 5 / Spectra of Radicals
I. General Discussion
II. Production and Detection of Free Radicals
III. Gas-Phase Spectra
IV. Matrix-Isolation Spectra
References
Chapter 6 / The Molecular Force Field
I. Introduction
II. The General Force Field
III. Model Force Fields
IV. Force Constants and Molecular Structure
Appendix. Internal Coordinates and F- and G-Matrices of Some Molecules
References
Chapter 7 / Interactions among Electronic, Vibrational, and Rotational Motions
I. Introduction
II. Hund's Coupling Cases for Diatomic Molecules
III. The Renner and Jahn-Teller Effects
IV. Rotation-Vibration Interaction
V. Concluding Remarks
References
Chapter 8 / Electric Moments of Molecules
I. Introduction
II. Methods of Measuring Dipole Moments
III. Methods of Measuring Quadrupole Moments
IV. Interpretation of Electric Moments
References
Chapter 9 / Nuclear Magnetic Resonance Spectroscopy