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Liquid Metal Corrosion
Fundamental Theory and Applications
- 1st Edition - June 7, 2023
- Author: Jinsuo Zhang
- Language: English
- Paperback ISBN:9 7 8 - 0 - 3 2 3 - 9 8 8 2 2 - 3
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 9 8 6 2 2 - 9
Liquid Metal Corrosion: Fundamental Theory and Applications is designed to help scientists, engineers and students working on liquid metal (sodium, lead, lead-bismuth) to fundam… Read more
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Request a sales quoteLiquid Metal Corrosion: Fundamental Theory and Applications is designed to help scientists, engineers and students working on liquid metal (sodium, lead, lead-bismuth) to fundamentally understand liquid metal corrosion. Coverage includes a discussion of corrosion mechanisms, fundamental corrosion processes, and corrosion products’ behaviors as well as methods on how to calculate corrosion rates. The book concludes with models designed to predict the corrosion/precipitation distribution in a primary corrosion loop. This book will be a useful resource for researchers in their efforts to determine appropriate materials selection and reactor design.
- Discusses liquid metal corrosion mechanisms
- Includes models to estimate/calculate corrosion rates
- Presents liquid metal corrosion controls and mitigation methods
University professors, engineers, laboratory scientists, and graduate students, and other scientific and engineering communities involved in the development of liquid metal reactors and fusion reactors
- Cover image
- Title page
- Table of Contents
- Copyright
- Preface
- Chapter 1: General introduction
- Abstract
- 1.1: Types and mechanisms of liquid metal corrosion
- 1.2: Factors that affect liquid metal corrosion
- 1.3: Experimental liquid metal corrosion techniques
- 1.4: Methods for mitigating liquid metal corrosion
- 1.5: Corrosion phenomena in liquid lead
- 1.6: Corrosion and oxidation
- References
- Chapter 2: Metal dissolution
- Abstract
- 2.1: Thermodynamic function of binary liquid-liquid metal
- 2.2: Thermodynamic analysis of materials dissolution
- 2.3: Dissolution kinetics
- References
- Chapter 3: Liquid metal corrosion-general theory
- Abstract
- 3.1: Basic equations
- 3.2: Mass exchanges at the interface
- 3.3: General models for liquid metal corrosion
- 3.4: Multiple corrosion products in the liquid metal
- References
- Chapter 4: Transport in liquid metal-isothermal cases
- Abstract
- 4.1: Static cases
- 4.2: Flow-induced material degradation
- 4.3: Mass transfer controlled corrosion-steady state cases
- 4.4: Mass transfer controlled corrosion-unsteady cases
- References
- Chapter 5: Transport in nonisothermal liquid metal loop
- Abstract
- 5.1: General description
- 5.2: Estimation of the corrosion rate at the hottest section
- 5.3: Models for corrosion and precipitation distribution along the loop
- 5.4: Particulate model
- References
- Chapter 6: Transport in solids
- Abstract
- 6.1: Selective corrosion without surface recession
- 6.2: Corrosion with surface recession
- 6.3: Two region problems
- References
- Chapter 7: Corrosion coupling at liquid/slide interfaces
- Abstract
- 7.1: Corrosion of pure metal
- 7.2: Corrosion of binary alloy
- 7.3: Corrosion of a multicomponent alloy
- References
- Chapter 8: Oxygen behavior in liquid metal
- Abstract
- 8.1: Thermodynamic properties
- 8.2: Oxygen distribution between liquid and solid materials
- 8.3: Oxygen measurements in liquid metal
- 8.4: Oxide and metal activity in liquid metal
- 8.5: Oxygen control
- 8.6: Water, hydrogen, and carbon oxide behaviors
- 8.7: Formation of ternary oxides
- References
- Chapter 9: Corrosion and protection of the oxide layer
- Abstract
- 9.1: Protective oxide layer in liquid lead and lead-bismuth
- 9.2: Rate control process
- 9.3: Oxide dissolution
- 9.4: Wagner theory for oxide growth
- 9.5: Oxide layer thickness-single-layer oxide structure
- 9.6: Oxide layer thickness-duplex-layer oxide structure
- 9.7: Single-layer structure with selective corrosion
- 9.8: Oxide layer stabilities
- 9.9: Oxide layer erosion
- References
- Chapter 10: Corrosion inhibition
- Abstract
- 10.1: Metallic inhibitors for corrosion by liquid heavy metals
- 10.2: Nonmetallic inhibitor for corrosion by liquid heavy metals
- 10.3: Scavenging inhibitor for corrosion by liquid alkaline metals
- 10.4: Surface coatings and treatment for corrosion by liquid heavy metals
- 10.5: Surface coatings and treatment for corrosion by liquid alkaline metals
- References
- Chapter 11: Review of corrosion tests in liquid heavy metals
- Abstract
- 11.1: Al-containing steels
- 11.2: Si-enriched steels
- 11.3: Long-term flow-induced corrosion tests
- 11.4: Mechanical effects on corrosion
- References
- Chapter 12: Corrosion tests and modeling in liquid sodium and sodium-potassium
- Abstract
- 12.1: Books and handbooks
- 12.2: Review articles on liquid metal corrosion
- 12.3: Review articles on liquid Na/Na-K corrosion
- 12.4: Modeling development
- 12.5: Experiments in liquid Na-K
- 12.6: Experiments with sodium corrosion
- Nomenclature
- Appendices
- Appendix I: Material properties
- Appendix II: Gibbs free energy of formation of some oxides
- Appendix III: Material solubility in liquid metal
- Index
- No. of pages: 276
- Language: English
- Edition: 1
- Published: June 7, 2023
- Imprint: Woodhead Publishing
- Paperback ISBN: 9780323988223
- eBook ISBN: 9780323986229
JZ
Jinsuo Zhang
Prof. Jinsuo Zhang is a professor of the Nuclear Science and Engineering Program at the Virginia Tech. His research interests are material degradation (corrosion) and coolant chemistry for advanced nuclear reactors including liquid metal and molten salt reactors. He has been working on liquid metal corrosion since 2001. He has published more than 130 journal papers relevance to materials corrosion.
Before Prof. Zhang joined the Virginia tech, he was an associate professor at The Ohio State University from 2012 to 2017, and was staff scientist at the Los Alamos National Laboratory from 2004 to 2012. Porf. Zhang got his Ph.D from Zhejiang University in 2001.
Affiliations and expertise
Professor, Nuclear Engnieering Program, Virginia Tech, Blacksburg, VA, USARead Liquid Metal Corrosion on ScienceDirect