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Introduction to Magnetochemistry
1st Edition - January 1, 1968
Author: Alan Earnshaw
9 7 8 - 1 - 4 8 3 2 - 7 0 6 9 - 2
Introduction to Magnetochemistry provides an introduction to the more important aspects of magnetochemistry. The measurement of magnetic moment has been one of the most… Read more
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Introduction to Magnetochemistry provides an introduction to the more important aspects of magnetochemistry. The measurement of magnetic moment has been one of the most consistently useful to coordination chemists. For teaching purposes it provides a simple method of illustrating the ideas of electronic structure, and in research it can provide fundamental information about the bonding and stereochemistry of complexes. The book contains six chapters covering topics such as free atoms and ions, transition metal complexes, crystal field theory, second and third row transition metal complexes, antiferromagnetism, and spin-pairing of electrons. The final chapter describes important experimental methods and then to shows briefly the way in which the problems of interpretation may be tackled.
PrefaceDefinitions of SymbolsI. Introduction Diamagnetic CorrectionsII. Free Atoms and Ions Single Electron System Multi-Electron SystemIII. Transition Metal Complexes Valence Bond Theory Crystal Field TheoryIV. Crystal Field Theory Van Vleck'S Formula for Susceptibility Strength of Ligand Fields Weak Field Case Strong Field Case Term Splitting and Electron Configuration Spin-Orbit Coupling A and E Terms Spin-Orbit Coupling on T Terms Second Order Zeeman EffectV. Further Topics Second and Third Row Transition Metal Complexes Antiferromagnetism Spin Free-Spin Paired EquilibriaVI. Experimental Measurements InterpretationAppendixReferencesIndex