Homogeneous Isomerization, Amination and Silicon Compounds Reactions

1st Edition - November 20, 2024
Editors: Mohammad Reza Rahimpour, Mohammad Amin Makarem, Tayebeh Roostaie, Maryam Meshksar
Language: English
Paperback ISBN:
9 7 8 - 0 - 4 4 3 - 1 5 7 1 2 - 7
eBook ISBN:
9 7 8 - 0 - 4 4 3 - 1 5 7 1 3 - 4

Homogeneous Isomerization, Amination and Silicon Compounds Reactions, a volume in the Advances in Homogeneous Catalysis series, is separated into three parts to provide comprehe… Read more

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Homogeneous Isomerization, Amination and Silicon Compounds Reactions, a volume in the Advances in Homogeneous Catalysis series, is separated into three parts to provide comprehensive coverage of isomerization, amination, and silicon compounds reactions with homogeneous catalysts. The first part presents isomerization of functionalized and non-functionalized alkenes. Homogeneous amination and hydroamination reactions are investigated in the second, while the final part covers homogeneous reactions of silicon compounds. The comprehensive coverage of the subject means this volume will be particularly useful to help bridge the gap between chemists and engineer’s knowledge and use of homogeneous catalysis.

Title of Book
Cover image
Title page
Table of Contents
Copyright
Contributors
About the editors
Preface
Reviewer acknowledgments
Part I. Homogeneous isomerization reactions
Chapter 1. Overview of homogeneous isomerization catalytic systems
1 Introduction
2 Principles and procedures
3 Processes
4 Current application and cases
4.1 Homogeneous catalytic isomerization of glucose to fructose
4.2 Homogeneous catalytic isomerization of allylic alcohol
4.3 Homogeneous catalytic isomerization of alkene
4.4 Homogeneous isomerization-hydroformylation
5 Conclusion and future outlooks
Abbreviations and symbols
Chapter 2. Homogeneous isomerization of alkenes
1 Introduction
1.1 Isomerization of olefins with the homogeneous metal catalyst
2 Catalyst and deuterium oxide for homogeneous isomerization of alkenes
3 Natural and synthetic terpenic compounds for homogeneous isomerization of alkenes
4 Conclusion and future outlooks
Abbreviations and symbols
Part II. Homogeneous amination and hydroamination
Chapter 3. Introduction to homogeneous amination and hydroamination
1 Introduction
2 Homogeneous and heterogeneous reactions
3 Chirality and stereoselectivity
4 Amination
5 Reductive amination
6 Borrowing hydrogen amination or hydrogen auto-transfer amination
7 Enzymatic and biocatalytic amination
8 Synthesis of alkaloids with amination methods
9 Conclusion and future outlooks
Abbreviations and symbols
Chapter 4. Hydroamination of alkenes using homogeneous catalysts
1 Introduction
1.1 Hydroamination of ethylene with homogeneous catalysts
2 Homogeneous metal catalysts in hydroamination
2.1 Transition metal catalysts of hydroamination of alkenes with homogeneous catalysts
2.2 Rare-earth metal complexes of hydroamination of alkenes with homogeneous catalysts
2.3 Gold-catalyzed hydroamination of alkenes with homogeneous catalysts
2.4 Silver-catalyzed hydroamination of alkenes with homogeneous catalysts
3 Conclusion and future outlooks
Abbreviations and symbols
Chapter 5. Homogeneous reductive amination and hydroaminomethylation
1 Introduction
2 Homogeneous reductive amination
2.1 Mo-catalyzed homogeneous reductive amination
2.2 Mn-catalyzed homogeneous reductive amination
2.3 Fe-catalyzed homogeneous reductive amination
2.4 Co-catalyzed homogeneous reductive amination
2.5 Ir-catalyzed homogeneous reductive amination
2.6 Rh-catalyzed homogeneous reductive amination
2.7 Ru-catalyzed homogeneous reductive amination
3 Homogeneous hydroaminomethylation
3.1 Rh-catalyzed hydroaminomethylation
3.2 Ru-catalyzed hydroaminomethylation
3.3 Ir-catalyzed hydroaminomethylation
3.4 Co-catalyzed hydroaminomethylation
4 Conclusion and future outlooks
Abbreviations and symbols
Chapter 6. Homogenous amination in bio-based chemistry
1 Introduction
2 Hydrogen borrowing catalysis for the amination of bio-based alcohols
3 Furfural transformation into high-quality chemicals and sustainable solvents
4 Reactivity of hydroxymethylfurfural
5 Epoxy resins
6 Lignin-based polyurethanes
7 Amination
8 Conceptual biorefinery platform: Glycolaldehyde as a bio-based C2 platform molecule
9 Acetals
10 Nitrogen-containing derivatives
11 Triazoles
12 Glycosides
13 Conclusion and future outlooks
Abbreviations and symbols
Chapter 7. Environmental impacts and economic assessment of homogeneous amination processes
1 Introduction
2 Environmental impact of homogeneous amination
2.1 Toxicity of amines
2.2 Toxicity of solvents
2.3 Toxicity of catalysts
3 Analysis of different types of catalysts and reactions
3.1 Catalysis by ammonium ion
3.2 Catalysis by amide ion
3.3 Catalysis by organolanthanides
3.4 Catalysis by enzymes
3.5 Photocatalysis
3.6 Catalysis by metals
3.6.1 Cobalt catalyst
3.6.2 Palladium catalysts
3.6.3 Ruthenium catalysts
3.6.4 Rhodium catalysts
3.6.5 Molybdenum catalyst
3.6.6 Manganese catalyst
3.6.7 Iron catalyst
3.6.8 Iridium catalyst
3.6.9 Copper catalyst
3.6.10 Nickel catalyst
4 Conclusion and future outlooks
Abbreviations and symbols
Chapter 8. Homogenous amination in polymer chemistry
1 Introduction
2 Homogeneous amination
3 Synthesis and fabrication methods
4 Advanced technologies to intensify the homogeneous amination process
5 Commercial use of homogeneous amination
6 Analysis of the flexibility of homogenous amination in polymer chemistry
7 Economic considerations for homogeneous amination reactions in polymer chemistry
8 Conclusion and future outlooks
Abbreviations and symbols
Part III. Homogeneous silicon compounds reactions
Chapter 9. Hydrosilylation reactions with homogeneous catalysts
1 Introduction
1.1 Alkene hydrosilylation with homogeneous catalysts
2 Transition metal catalysts for hydrosilylation
2.1 Platinum catalysts for hydrosilylation
2.2 Iron catalysts for hydrosilylation
2.3 Manganese catalysts for hydrosilylation
2.4 Cobalt catalysts for hydrosilylation
3 Non-metal catalysts for hydrosilylation reactions
4 Conclusion future and outlooks
Abbreviations and symbols
Index

Mohammad Reza Rahimpour

Prof. Mohammad Reza Rahimpour is a professor in Chemical Engineering at Shiraz University, Iran. He received his Ph.D. in Chemical Engineering from Shiraz University joint with University of Sydney, Australia 1988. He started his independent career as Assistant Professor in September 1998 at Shiraz University. Prof. M.R. Rahimpour, was a Research Associate at University of California, Davis from 2012 till 2017. During his stay in University of California, he developed different reaction networks and catalytic processes such as thermal and plasma reactors for upgrading of lignin bio-oil to biofuel with collaboration of UCDAVIS. He has been a Chair of Department of Chemical Engineering at Shiraz University from 2005 till 2009 and from 2015 till 2020. Prof. M.R. Rahimpour leads a research group in fuel processing technology focused on the catalytic conversion of fossil fuels such as natural gas, and renewable fuels such as bio-oils derived from lignin to valuable energy sources. He provides young distinguished scholars with perfect educational opportunities in both experimental methods and theoretical tools in developing countries to investigate in-depth research in the various field of chemical engineering including carbon capture, chemical looping, membrane separation, storage and utilization technologies, novel technologies for natural gas conversion and improving the energy efficiency in the production and use of natural gas industries.

Affiliations and expertise

Professor, Department of Chemical Engineering, Shiraz University, Shiraz, Iran

Mohammad Amin Makarem

Dr. Mohammad Amin Makarem is a research associate at Taylor's University, Malaysia. He former worked at Shiraz University. His research interests are gas separation and purification, nanofluids, microfluidics, catalyst synthesis, reactor design and green energy. In gas separation, his focus is on experimental and theoretical investigation and optimization of pressure swing adsorption process, and in the gas purification field, he is working on novel technologies such as microchannels. Recently, he has investigated methods of synthesizing bio-template nanomaterials and catalysts. Besides, he has collaborated in writing and editing various books and book-chapters for famous publishers such as Elsevier, Springer and Wiley, as well as guest editing journals special issues.

Affiliations and expertise

Taylor's University, Malaysia

Tayebeh Roostaie

Tayebeh Roostaie is a research associate at Shiraz University. Her research has focused on catalyst, clean energy, biofuel, demulsification and membrane. In the clean energy field, she has worked on hydrogen production. She has also synthesized novel catalysts for this process which are tested in a laboratory reactor. Recently, she has written various book chapters for famous publishers such as Elsevier.

Affiliations and expertise

Department of Chemical Engineering Shiraz University, Shiraz, Iran

Maryam Meshksar

Maryam Meshksar is a research associate at Shiraz University. Her research has focused on gas separation, clean energy, and catalyst synthesis. In gas separation, she is working on membrane separation process, and in the clean energy field, she has worked on reforming-based processes for hydrogen production from methane experimentally. She has also synthesized novel catalysts for this process which are tested in for the first time. Recently, she has written various book chapters for famous publishers such as Elsevier, Springer and Wiley

Affiliations and expertise

Department of Chemical Engineering Shiraz University, Shiraz, Iran

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Homogeneous Isomerization, Amination and Silicon Compounds Reactions

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Mohammad Reza Rahimpour

Mohammad Amin Makarem

Tayebeh Roostaie

Maryam Meshksar