Heterogeneous Catalysis

Materials and Applications

1st Edition - April 27, 2022
Imprint: Elsevier
Editors: Moises Romolos Cesario, Daniel Araujo de Macedo
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 8 5 6 1 2 - 6
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 8 5 6 3 2 - 4

Heterogeneous Catalysis: Materials and Applications focuses on heterogeneous catalysis applied to the elimination of atmospheric pollutants as an alternative solution for producing… Read more

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Heterogeneous Catalysis: Materials and Applications focuses on heterogeneous catalysis applied to the elimination of atmospheric pollutants as an alternative solution for producing clean energy and the valorization of chemical products. The book helps users understand the properties of catalytic materials and catalysis phenomena governing electrocatalytic/catalytic reactions, and – more specifically – the study of surface and interface chemistry. By clustering knowledge in these fields, the book makes information available to both the academic and industrial communities. Further, it shows how heterogeneous catalysis applications can be used to solve environmental problems and convert energy through electrocatalytic reactions and chemical valorization. Sections cover nanomaterials for heterogeneous catalysis, heterogeneous catalysis mechanisms, SOX adsorption, greenhouse gases conversion, reforming reactions for hydrogen production, valorization of hydrogen energy, energy conversion and biomass valorization.

Cover image
Title page
Table of Contents
Copyright
Contributors
Chapter 1: Understanding heterogeneous catalysis: A brief study on performance parameters
Abstract
Conflict of interest
1.1: Introduction
1.2: Catalysis fundamentals
1.3: Performance parameters
1.4: Conclusions
References
Chapter 2: Use of CO2 as a source for obtaining value-added products
Abstract
Acknowledgments
2.1: Introduction
2.2: Background
2.3: Catalytic transformations of CO2
2.4: Neural kinetic models
2.5: Outlook
References
Chapter 3: Transition metal-based catalysts for CO2 methanation and hydrogenation
Abstract
3.1: Introduction
3.2: Thermodynamic aspects of CO2 methanation and CO2 hydrogenation
3.3: Transition metal-based catalysts in CO2 methanation and CO2 hydrogenation
3.4: Proposed reaction mechanisms of CO2 methanation
3.5: Future prospects: Assisted nickel catalysts for CO2 reduction: From photocatalysis to assisted plasma catalysis
3.6: Conclusion
References
Chapter 4: Sorption enhanced catalysis for CO2 hydrogenation towards fuels and chemicals with focus on methanation
Abstract
Acknowledgments
4.1: Introduction
4.2: Sorption enhanced catalysis for CO2 methanation
4.3: Conclusions and outlook
References
Chapter 5: Hydrogenation of CO2 by photocatalysis: An overview
Abstract
5.1: Introduction
5.2: Photocatalytic hydrogenation of CO2
5.3: Mechanism for photocatalytic hydrogenation of CO2
5.4: Important criteria for photocatalytic hydrogenation of CO2
5.5: Types of photocatalytic hydrogenation of CO2
5.6: Reported heterogeneous photocatalysts for hydrogenation of CO2
5.7: Methods of reduction or hydrogenation of CO2
5.8: Limitations and important aspects for future perspectives
5.9: Conclusion
References
Further reading
Chapter 6: The role of CO2 sorbents materials in SESMR for hydrogen production
Abstract
Acknowledgments
Conflict of interest
6.1: Introduction
6.2: The steam methane reforming process
6.3: The SESMR process
6.4: Adsorbents
6.5: Reactors
6.6: Conclusions
References
Further reading
Chapter 7: Catalysts for syngas production by dry reforming of methane
Abstract
7.1: Introduction
7.2: DRM heterogeneous catalysts
7.3: Final considerations
References
Further reading
Chapter 8: Dry reforming of methane for catalytic valorization of biogas
Abstract
8.1: Introduction
8.2: Biogas production, composition, and valorization
8.3: Dry reforming of methane reaction: Advantages and disadvantages
8.4: Catalytic reforming of biogas
8.5: Conclusions and perspectives
References
Chapter 9: Catalysts for steam reforming of biomass tar and their effects on the products
Abstract
Acknowledgments
9.1: Introduction
9.2: Tar classification and properties
9.3: Theoretical approach of biomass tar reforming
9.4: Reactor characteristics
9.5: Catalysts for catalytic steam reforming
9.6: Catalytic steam reforming of methane and light hydrocarbons
9.7: Catalytic steam reforming of bio-oil compounds
9.8: Conclusion
References
Chapter 10: Heterogeneous catalysts for biomass-derived alcohols and acid conversion
Abstract
Acknowledgments
10.1: Introduction
10.2: Alcohol conversion
10.3: Diols
10.4: Carboxylic acids
10.5: Conclusions
References
Chapter 11: Zinc oxide or molybdenum oxide deposited on bentonite by the microwave-assisted hydrothermal method: New catalysts for obtaining biodiesel
Abstract
Conflict of interest
Acknowledgments
11.1: Introduction
11.2: Methods
11.3: Recent advances
11.4: Conclusions
References
Chapter 12: Assisted catalysis: An overview of alternative activation technologies for the conversion of biomass
Abstract
12.1: Introduction
12.2: Synergistic effect between catalysis and mechanical forces: Cellulose as a case study
12.3: Sonocatalysis for the conversion of biomass
12.4: Electroconversion of biomass
12.5: Conclusions
References
Chapter 13: Regenerable adsorbents for SOx removal, material efficiency, and regeneration methods: A focus on CuO-based adsorbents
Abstract
13.1: Introduction
13.2: Role of the CuO support
13.3: Influence of the textural properties of the support
13.4: Influence of the preparation protocol and support treatment
13.5: Influence of active-phase loading
13.6: Doping CuO-based adsorbents with other metal oxides
13.7: Influence of the operational conditions of the adsorption step
13.8: Influence of the regeneration conditions
13.9: Aging and stability of the SOx adsorbents over time
13.10: Conclusions
References
Chapter 14: Solid oxide cells (SOCs) in heterogeneous catalysis
Abstract
Acknowledgments
14.1: Introduction
14.2: Background of separation processes in heterogeneous catalysis
14.3: Electrode materials
14.4: Conclusions
References
Chapter 15: Electrocatalytic oxygen reduction and evolution reactions in solid oxide cells (SOCs): A brief review
Abstract
Acknowledgments
15.1: Introduction
15.2: Oxygen reactions
15.3: Mixed ionic-electronic conductors
15.4: Experimental techniques to determine oxygen kinetics
15.5: Anode degradation in SOECs
15.6: Oxygen electrode materials
15.7: Conclusions
References
Chapter 16: Catalysts for hydrogen and oxygen evolution reactions (HER/OER) in cells
Abstract
Acknowledgments
16.1: Introduction
16.2: Hydrogen (H2) production by water splitting
16.3: Improving electrocatalyst materials
16.4: Perspectives
16.5: Conclusions
References
Chapter 17: Zeolitic imidazolate framework 67 based metal oxides derivatives as electrocatalysts for oxygen evolution reaction
Abstract
17.1: Introduction
17.2: Recent advances
17.3: Conclusions
References
Chapter 18: Electrochemical ammonia synthesis: Mechanism, recent developments, and challenges in catalyst design
Abstract
Acknowledgments
18.1: Introduction
18.2: Electrochemical synthesis of ammonia
18.3: Basics of N2 reduction reaction
18.4: Outlook
18.5: Conclusions
References
Chapter 19: Non-faradaic electrochemical modification of catalytic activity: A current overview
Abstract
Acknowledgments
19.1: Introduction
19.2: Phenomenology and key aspects
19.3: Parameters to evaluate the NEMCA effect
19.4: Solid electrolytes
19.5: Metal catalyst preparation
19.6: Measurement techniques
19.7: Summary of performed EPOC studies
19.8: Scaling up
19.9: Final remarks
References
Index

Moises Romolos Cesario

Moisés Romolos Cesario is currently Guest Professor at the Federal University of Paraiba (Brazil). He obtained a PhD in physical chemistry from a Joint PhD program between the University of Strasbourg (UNISTRA), France, and the Federal University of Rio Grande do Norte (UFRN), Brazil. His scientific expertise encompasses synthesis methods (Pechini, microwave assisted self-combustion, hydrothermal, solid-state reaction), ceramic materials processing, catalytic processes (steam and dry methane reforming), electrocatalysis. His technical expertise encompasses gas chromatography – mass spectroscopy (GC-MS), electrochemical impedance spectroscopy (EIS), thermogravimetric analysis (TGA). X-ray diffraction (XRD), X-ray photoelectron spectrometry, Fourier transform infrared spectroscopy (FTIR), scanning and transmission electron microscopy (SEM, TEM), temperature-programmed desorption, reduction and oxidation (TPD, TPR, TPO), and N2 physisorption. He is the author of two books – M.R. Cesário, D.A. Macedo, C. Gennequin, and E. Abi-Aad, Catalytic Materials for Hydrogen Production and Electrooxidation Reactions (2018), and M.R. Cesário and D.A. Macedo, Frontiers in Ceramic Science: Functional Materials for Solid Oxide Fuel Cells: Processing, Microstructure and Performance (2017). He wrote 5 book chapters and holds 1 patent.

Affiliations and expertise

Guest Professor, Federal University of Paraiba, Brazil.

Daniel Araujo de Macedo

Prof. Daniel Macedo has devoted the last decade of his academic career to the study and improvement of ceramic and composite, catalytic materials for energy conversion in electrochemical devices. He is author of several scientific papers published in conferences and journals of international circulation, book chapters, and patents. He is an adjunct professor at the Department of Materials Engineering of the Federal University of Paraíba (Brazil).

Affiliations and expertise

Department of Materials Engineering, Federal University of Paraíba, Paraíba, Brazil

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