Green Analytical Chemistry
Current Status and Future Perspectives in Sample Preparation
- 1st Edition - October 5, 2024
- Imprint: Elsevier
- Editors: Marcello Locatelli, Savaş Kaya
- Language: English
- Paperback ISBN:9 7 8 - 0 - 4 4 3 - 1 6 1 2 2 - 3
- eBook ISBN:9 7 8 - 0 - 4 4 3 - 1 6 1 2 3 - 0
Green Analytical Chemistry: Current Status and Future Perspectives in Sample Preparation presents the state-of-the-art in the field of GAC sample preparation procedures. With a fo… Read more
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Request a sales quoteGreen Analytical Chemistry: Current Status and Future Perspectives in Sample Preparation presents the state-of-the-art in the field of GAC sample preparation procedures. With a focus on green chemistry, the book highlights how new techniques make it possible to observe a lower environmental impact without sacrificing the performance of the procedure. By proving a theoretical background of novel green technologies and proposing new protocols, this book addresses innovative methodologies in analytical chemistry and sample preparation following the requirements of green analytical chemistry demands. It is a valuable resource for researchers, chemist, students, and all those interested in the allied field.
- Presents the state-of-the-art in GAC sample preparation procedures
- Offers a step-by-step method description and application of procedures
- Provides a theoretical background of novel green technologies and proposes new protocols
Industries, laboratories, Pharmaceutical, as Researchers in the fields of analytical chemistry, method development and validation, Medicinal Chemistry, Phytochemistry, and Students in Department of Pharmacy, and Chemistry Technicians, clinical laboratories, experts in chemistry
- Title of Book
- Cover image
- Title page
- Table of Contents
- Copyright
- Contributors
- About the editors
- Acknowledgments
- Chapter 1. Green chemistry and green analytical chemistry
- 1 Introduction
- 2 Green chemistry
- 3 Green analytical chemistry
- 4 Conclusions
- Declaration of interests
- Author contributions
- Funding
- Chapter 2. Principal concepts and guidelines for GAC applied in sample preparation
- 1 Introduction
- 2 Green chemistry
- 2.1 Green chemistry metrics
- 3 Green analytical chemistry
- 3.1 Background of green analytical chemistry
- 4 Key steps used in sample reparation
- 5 The principles of green sample preparation in the context of GAC
- 6 The main components of green analytical methods: Core principles of GAC
- 6.1 Sample collection
- 6.2 Analytical process and quantification techniques
- 6.3 Reagents safety and secure operation
- 6.4 Waste generation
- 7 Conclusion
- Chapter 3. Conceptual density functional theory–based applications in extraction studies
- 1 Introduction
- 2 Hard and soft acid-base principle
- 3 Hard acids
- 4 Soft acids
- 5 Hard bases
- 6 Soft bases
- 7 Maximization and minimization in stable states of hardness, polarizability, electrophilicity, and magnetizability
- 8 Conceptual DFT-based applications in extraction studies
- 9 Conclusion
- Chapter 4. Sorbent-based extraction procedures
- 1 Introduction
- 1.1 Solid phase extraction
- 1.1.1 A brief history of SPE
- 1.1.2 Principle of SPE
- 1.1.3 SPE efficiency-related parameters
- 1.2 Solid phase microextraction
- 1.2.1 Principle of SPME
- 1.2.2 Advantages of SPME
- 1.2.3 Drawbacks of SPME (based on fiber)
- 1.2.4 Applications of SPME
- 1.2.5 Sorbents in SPME
- 1.2.6 Future trends of SPME
- 1.2.7 Classification of SPME
- 1.3 Fiber solid phase extraction
- 1.3.1 Sorbent type
- 1.4 In-tube solid phase microextraction
- 1.4.1 Principles of in-tube SPME
- 1.4.2 Comparison between conventional SPME and in-tube SPME
- 1.4.3 Differences between fiber and in-tube methods
- 1.5 Matrix-dispersed solid phase extraction
- 1.6 Sorbent-based dynamic extraction
- 1.7 Stir bar sorptive extraction
- 1.7.1 Principles of stir bar sorptive extraction
- 1.7.2 Future trends of stir bar sorptive extraction
- 1.8 Rotating disk solid phase extraction
- 1.8.1 Principles of RDSPE
- 1.8.2 Applications of RDSPE
- 1.8.3 Advantages and disadvantages of RDSPE
- 1.8.4 Future trends of RDSPE
- 1.9 Magnetic solid phase extraction
- 1.9.1 Principle of MSPE
- 1.9.2 Applications of MSPE
- 1.9.3 Comparison of MSPE with other methods
- 1.9.4 Future trends of MSPE
- 1.10 Thin film microextraction
- 1.10.1 Principles of thin film microextraction
- 1.10.2 Comparison and applications of TFME
- 1.10.3 Future trends of TFME
- 1.11 Dispersive solid phase extraction
- 1.11.1 Principles of DSPE
- 1.11.2 Advantages and disadvantages of DSPE
- 1.11.3 Future trends of DSPE
- 1.12 Packed sorbent microextraction
- 1.12.1 Principles of PSME
- 1.12.2 Differences between PSME and SPE
- 1.13 Micro solid phase extraction
- 1.14 Fabric phase sorptive extraction
- 1.14.1 Principles, advantages and disadvantages, and future trends of FPSE
- 1.15 Air-assisted solid phase extraction
- 1.15.1 Principles of air-assisted SPE
- 1.15.2 Advantages and disadvantages air-assisted SPE
- 1.15.3 Future trends of air-assisted SPE
- 1.16 Summary and outlook
- Chapter 5. Membrane-based extraction techniques
- 1 Introduction
- 2 Membrane-based solid-phase microextraction and associated techniques
- 2.1 Fabric phase sorptive extraction
- 2.1.1 Different implementations of fabric phase sorptive extraction
- 2.1.2 Applications of fabric phase sorptive extraction
- 2.2 Capsule phase microextraction
- 2.3 Micro solid phase extraction
- 2.4 Carbon nanomaterial-based solid phase extraction
- 2.5 Biofluid sampler
- 2.6 Membrane-protected molecularly imprinted materials
- 2.7 Membrane-protected solid phase microextraction
- 2.8 Thin film microextraction
- 3 Membrane-based liquid phase microextraction
- 3.1 Porous membrane–based liquid phase microextraction techniques
- 3.1.1 Dialysis
- 3.1.2 Electrodialysis
- 3.1.3 Filtration
- 3.2 Nonporous membranes
- 3.3 Hollow-fiber based liquid phase microextraction
- 3.4 Electromembrane extraction
- 3.5 Bulk membrane extraction
- 4 Conclusions
- Chapter 6. Introduction and overview of applications related to green solvents used in sample preparation
- 1 Introduction
- 2 Amphiphilic solvents
- 3 Supramolecular solvents
- 4 Hydrophilicity switchable solvent
- 5 Ionic liquids
- 6 Deep eutectic solvents
- 7 Conclusions and prospects for the future
- Chapter 7. Advancements and innovations in solvent-based extraction techniques
- 1 Introduction
- 2 Dispersive liquid liquid microextraction
- 2.1 Innovations in the use of extracting solvents
- 2.2 Ionic liquids (ILs)
- 2.3 Supramolecular solvents (SUPRASs)
- 2.4 Reverse micelles based SUPRAS
- 2.5 Deep eutectic solvents (DES) in DLLME
- 2.5.1 Applications of DES
- 2.6 Switchable solvents for micro extraction
- 3 Pressurized fluid extraction (PFE)
- 3.1 Instrumentation and principles of pressurized fluid extraction
- 3.2 Solvent used in PFE
- 4 Dispersive solid phase extraction
- 4.1 Applications of dispersive solid phase extraction (DLPE)
- 5 Micellar-assisted extraction or microvawe assisted extraction
- 5.1 Applications of micelle-assisted extractions
- 6 Supercritical fluid extraction (SFE)
- 6.1 Properties of supercritical fluid
- 6.2 Solvent used in SFE
- 6.3 Instrumentation used in SFE
- 6.4 Applications of supercritical fluid
- 7 Liquid liquid extraction (LLE)
- 7.1 Principle of LLE
- 7.2 The history of LLE
- 7.3 Solvents used in LLE
- 8 Liquid phase microextraction (LPME)
- 8.1 Specific extraction media in SPME
- 8.2 Solvent used in LPME
- 9 Conclusion
- 10 Future recommendations
- Chapter 8. Solvent free extraction procedures
- 1 Introduction
- 1.1 Principles of solvent-free extraction [3,8–10]
- 2 Methods of solvent-free extraction
- 2.1 Grinding
- 2.2 Pressing
- 2.3 Gas-assisted mechanical methods
- 2.4 Subcritical water extraction
- 2.5 Pressurized liquid extraction (PLE)
- 2.6 Supercritical fluid extraction
- 2.7 Microwave-assisted extraction (MAE)
- 2.8 Ultrasound-assisted extraction
- 2.9 Ohmic heating extraction
- 2.10 Ionic liquids
- 2.11 Biocompatible extractions
- 2.12 Solid phase microextraction (SPME)
- 2.12.1 Headspace solid phase microextraction (HS-SPME)
- 3 Advantages
- 4 Considerations
- 5 Applications
- 6 Conclusion
- Chapter 9. How to evaluate the greenness and whiteness of analytical procedures?
- 1 Introduction
- 2 A brief history of greenness evaluation tools in analytical chemistry
- 3 Classification of greenness evaluation tools
- 4 Summary of the chosen greenness evaluation tools
- 4.1 National environmental method index (NEMI)
- 4.1.1 NEMI principles
- 4.1.2 Strengths and weaknesses of NEMI
- 4.2 The developed NEMI tool
- 4.3 The Eco-scale tool
- 4.3.1 The Eco-scale principles
- 4.3.2 Strengths and weaknesses
- 4.4 Analytical eco-scale tool
- 4.4.1 The analytical Eco-scale principles
- 4.4.2 Strengths and weaknesses of AES
- 4.5 Green analytical procedure index (GAPI) tool
- 4.5.1 GAPI tool principles
- 4.5.2 Strengths and weaknesses of GAPI
- 4.6 Complex green analytical procedure index (ComplexGAPI)
- 4.6.1 The ComplexGAPI principles
- 4.6.2 Strengths and weaknesses of ComplexGAPI
- 4.7 Analytical method greenness score (AMGS)
- 4.7.1 The AMGS principles
- 4.7.2 The strengths and weakness of AMGS
- 4.8 Hexagon-CALIFICAMET scale
- 4.8.1 Hexagon-CALIFICAMET principles
- 4.8.2 The strengths and weakness of hexagon-CALIFICAMET
- 4.9 The analytical GREEness (AGREE) scale
- 4.9.1 The AGREE principles
- 4.9.2 The strengths and weakness of AGREE scale
- 4.10 The AGREEprep scale
- 4.10.1 The AGREEprep principles
- 4.10.2 The strengths and weakness of AGREE scale
- 4.11 White analytical chemistry (WAC) scale
- 4.11.1 White analytical chemistry (WAC) scale principles
- 4.11.2 The strengths and weakness of WAC scale
- 5 Applications of the studied greenness evaluation methods' publications
- 6 Conclusions
- 7 Visions for the future
- Chapter 10. The CUPRAC method, its modifications and applications serving green chemistry
- 1 Importance of green analytical chemistry
- 2 Oxidative stress and antioxidants
- 3 CUPRAC method and its advantages
- 3.1 Main advantages of the CUPRAC assay
- 4 Modifications and applications of CUPRAC method serving green chemistry
- 4.1 Optical sensors based on CUPRAC method
- 4.1.1 CUPRAC based optrode sensors
- 4.1.2 CUPRAC based optical nanosensors
- 4.2 CUPRAC microplate- and flow injection-based methods
- 4.3 Online HPLC-CUPRAC methods
- 4.4 Electroanalytical CUPRAC methods
- 4.5 Green solvents used in the CUPRAC method
- 4.6 Quencher CUPRAC methods
- Chapter 11. Conclusion and future perspectives
- Declaration of interests
- Author contributions
- Funding
- Index
- Edition: 1
- Published: October 5, 2024
- No. of pages (Paperback): 530
- No. of pages (eBook): 530
- Imprint: Elsevier
- Language: English
- Paperback ISBN: 9780443161223
- eBook ISBN: 9780443161230
ML
Marcello Locatelli
Prof. Locatelli is Associate Professor in Analytical Chemistry and his research activity is aimed at the development and validation of chromatographic methods for the qualitative and quantitative determination of biologically active molecules in human and animal, cosmetics, food, and environmental complex matrices. These procedures have been applied to different analytes and drug associations also finding application in clinical and pre-clinical studies, to characterize new delivery systems of the active principle to improve their pharmacological properties. In the development of the method are predictive models and chemometrics applied both for the optimization of extraction protocols and for final data processing. Particular attention is given to innovative (micro)-extraction techniques and new instrumental configurations for the quantitative analysis of complex matrices.
Affiliations and expertise
Associate Professor, University "G. d'Annunzio" of Chieti-Pescara, ItalySK
Savaş Kaya
Savaş Kaya is associate professor at Sivas Cumhuriyet University, Turkey. His research interests lie in theoretical chemistry, computational chemistry, materials science, corrosion science, physical inorganic chemistry, and coordination chemistry.
Affiliations and expertise
Associate Professor, Sivas Cumhuriyet University, Turkey.Read Green Analytical Chemistry on ScienceDirect