Fundamentals of Soft Interfaces in Colloid and Surface Chemistry
- 1st Edition, Volume 37 - September 2, 2024
- Author: Hiroyuki Ohshima
- Language: English
- Paperback ISBN:9 7 8 - 0 - 4 4 3 - 1 6 1 1 6 - 2
- eBook ISBN:9 7 8 - 0 - 4 4 3 - 1 6 1 1 7 - 9
Fundamentals of Soft Interfaces in Colloid and Surface Chemistry, Volume 37 explains and summarizes the fundamentals of soft interfaces and soft particles from a colloid and surfa… Read more
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Request a sales quoteFundamentals of Soft Interfaces in Colloid and Surface Chemistry, Volume 37 explains and summarizes the fundamentals of soft interfaces and soft particles from a colloid and surface chemistry standpoint, bringing knowledge together into a single resource for the first time. The book provides detailed mathematical descriptions of colloidal and interfacial systems, with a particular emphasis on ionic, electrokinetic, and electrostatic phenomena. The author covers the most recent theoretical advances in the field of electrostatic interactions between soft interfaces, electrophoresis, diffusiophoresis, gel electrophoresis of soft particles including ionic size effects, ion-partitioning effects, and the effects of hydrodynamic slip on hydrophobic surfaces.
This book will help readers by providing a range of approximate analytic formulas which can be used to interpret various interfacial phenomena of soft interfaces and analyze experimental data in various fields. It is written for graduate students and researchers chiefly in chemistry but also chemical engineering, physics, and materials science.
- Utilizes rigorous theories and various useful approximate analytical formulas based upon them
- Provides a detailed mathematical description of colloidal and interfacial systems, with a particular emphasis on ionic and electrostatic phenomena
- Describes basic theories for various electrostatic and electrokinetic phenomena of soft interfaces
- Presents many formulas used to interpret and analyze experimental data of soft interfaces
Scientists, engineers, and graduate students chiefly in materials chemistry but also chemical engineering, physics, and materials science who want to study soft interfaces. It is designed to help scientists, engineers, and graduate students study the fundamentals and current developments in this field. Scientists, engineers, and graduate students in the field of chemistry, biology, biotechnology, and pharmaceutical sciences. Graduate students in chemistry, physical chemistry, biophysical chemistry, and pharmaceutical sciences
Part I: Charge and potential at soft interfaces
1. Poisson-Boltzmann equation for a potential distribution around a charged surface
1.1. Introduction
1.2. Hard surface without surface structures
1.3. Soft interfaces: Role of Donnan potential
1.4. Liquid-layer coated surface
2. Effects of ionic size: modified Poisson-Boltzmann equation
2.1. Introduction
2.2. Carnahan-Starling model
2.3. Simplified model
3. Ion size effect on charge and potential relationship
3.1. Introduction
3.2. Hard surface
3.3. Soft surface. Modified Donnan potential
4. Discrete charge effect
4.1. Introduction
4.2. Potential distribution on a hard surface
4.3. Potential distribution in and around a soft particle
Part II: Interaction between two colloidal particles
5. Electrostatic interaction between two hard particles
5.1. Introduction
5.2. Two parallel plates:
5.3. Two spheres
5.4. Two cylinders
5.5. Two spheroids
6. Ionic size effect on the electrostatic interaction between two particles
6.1. Introduction
6.2. Interaction at large separations
6.3. Interaction at small separations
7. Electrostatic Interaction between two soft particles
7.1. Introduction
7.2. Two parallel soft plates: Donnan-potential regulated interaction
7.3. Two soft spheres
7.4. Two soft cylinders
7.5. Interaction between two soft particles after contact: Compression and interdigitation
7.6. Interpenetration interaction
8. van der Waals interaction between two particles
8.1. Introduction
8.2. Two hard particles: Hamaker constant
8.3. Two soft particles
9. DLVO theory of colloid stability
9.1. Introduction
9.2. Total interaction energy between two particles
9.3. Stability ratio
10. Non-DLVO interactions
10.1. Introduction
10.2. Steric interaction between two polymer-coated particles
10.3. Depletion effect
11. Total interaction energy between two polymer-coated particles
11.1. Introduction
11.2. Total interaction energy between two particles
11.3. Stability ratio
Part III: Electrokinetics of soft particles
12. Electrophoresis: motion of colloidal particles in an electric field
12.1. Introduction
12.2. Electrophoretic mobility of rigid particles
12.3. Ion size effect
13. General theory of electrophoresis of soft particles
13.1. Introduction
13.2. Brinkman-Debye-Bueche model
13.2. Relaxation effect
14. Electrophoresis of a soft particle: Analytic approximations
14.1. Introduction
14.2. General mobility expression
14.3. Approximate analytic mobility expression
15. Effects of hydrodynamic liquid slip-on hydrophobic surfaces
15.1. Introduction
15.2. Hard surface
15.3. Soft surface
16. Transient electrophoresis and dynamic electrophoresis
16.1. Introduction
16.2. Hard particle
16.3. Soft particle
17. Gel electrophoresis: electrophoresis of colloidal particles in a polymer gel medium
17.1. Introduction
17.1. Hard particle
17.2. Soft particle
18. Gel electrophoresis of a soft particle: Analytic approximations
18.1. Introduction
18.2. General mobility expression
18.3. Approximate analytic mobility expression
19. Diffusiophoresis: motion of colloidal particles in an electrolyte concentration gradient
19.1. Introduction
19.1. Hard sphere
19.2. Hard cylinder
19.3. Effect of ionic size
19.4. Mercury drop
20. Diffusiophoresis of soft particles
20.1. Introduction
20.1. Weakly charged soft particle
20.2. Highly charged soft particle
Part IV: Ion transport and ion adsorption at soft interfaces
21. Membrane transport with time delay
21.1. Introduction
21.2. Membrane transport with time delay
21.3. Overshoot phenomena in membranes
21.4. Adsorption kinetics with time delay
22. Membrane potential
22.1. Introduction
22.2. Membrane potential and Donnan potential
22. 3. Time-dependent membrane potential
23. Ion-adsorption effect on the interfacial tension at soft interfaces
23.1. Introduction
23.2. Surface tension of a lipid-monolayer-coated air/water interface
23. 3. Divalent-cation-induced membrane fusion
1. Poisson-Boltzmann equation for a potential distribution around a charged surface
1.1. Introduction
1.2. Hard surface without surface structures
1.3. Soft interfaces: Role of Donnan potential
1.4. Liquid-layer coated surface
2. Effects of ionic size: modified Poisson-Boltzmann equation
2.1. Introduction
2.2. Carnahan-Starling model
2.3. Simplified model
3. Ion size effect on charge and potential relationship
3.1. Introduction
3.2. Hard surface
3.3. Soft surface. Modified Donnan potential
4. Discrete charge effect
4.1. Introduction
4.2. Potential distribution on a hard surface
4.3. Potential distribution in and around a soft particle
Part II: Interaction between two colloidal particles
5. Electrostatic interaction between two hard particles
5.1. Introduction
5.2. Two parallel plates:
5.3. Two spheres
5.4. Two cylinders
5.5. Two spheroids
6. Ionic size effect on the electrostatic interaction between two particles
6.1. Introduction
6.2. Interaction at large separations
6.3. Interaction at small separations
7. Electrostatic Interaction between two soft particles
7.1. Introduction
7.2. Two parallel soft plates: Donnan-potential regulated interaction
7.3. Two soft spheres
7.4. Two soft cylinders
7.5. Interaction between two soft particles after contact: Compression and interdigitation
7.6. Interpenetration interaction
8. van der Waals interaction between two particles
8.1. Introduction
8.2. Two hard particles: Hamaker constant
8.3. Two soft particles
9. DLVO theory of colloid stability
9.1. Introduction
9.2. Total interaction energy between two particles
9.3. Stability ratio
10. Non-DLVO interactions
10.1. Introduction
10.2. Steric interaction between two polymer-coated particles
10.3. Depletion effect
11. Total interaction energy between two polymer-coated particles
11.1. Introduction
11.2. Total interaction energy between two particles
11.3. Stability ratio
Part III: Electrokinetics of soft particles
12. Electrophoresis: motion of colloidal particles in an electric field
12.1. Introduction
12.2. Electrophoretic mobility of rigid particles
12.3. Ion size effect
13. General theory of electrophoresis of soft particles
13.1. Introduction
13.2. Brinkman-Debye-Bueche model
13.2. Relaxation effect
14. Electrophoresis of a soft particle: Analytic approximations
14.1. Introduction
14.2. General mobility expression
14.3. Approximate analytic mobility expression
15. Effects of hydrodynamic liquid slip-on hydrophobic surfaces
15.1. Introduction
15.2. Hard surface
15.3. Soft surface
16. Transient electrophoresis and dynamic electrophoresis
16.1. Introduction
16.2. Hard particle
16.3. Soft particle
17. Gel electrophoresis: electrophoresis of colloidal particles in a polymer gel medium
17.1. Introduction
17.1. Hard particle
17.2. Soft particle
18. Gel electrophoresis of a soft particle: Analytic approximations
18.1. Introduction
18.2. General mobility expression
18.3. Approximate analytic mobility expression
19. Diffusiophoresis: motion of colloidal particles in an electrolyte concentration gradient
19.1. Introduction
19.1. Hard sphere
19.2. Hard cylinder
19.3. Effect of ionic size
19.4. Mercury drop
20. Diffusiophoresis of soft particles
20.1. Introduction
20.1. Weakly charged soft particle
20.2. Highly charged soft particle
Part IV: Ion transport and ion adsorption at soft interfaces
21. Membrane transport with time delay
21.1. Introduction
21.2. Membrane transport with time delay
21.3. Overshoot phenomena in membranes
21.4. Adsorption kinetics with time delay
22. Membrane potential
22.1. Introduction
22.2. Membrane potential and Donnan potential
22. 3. Time-dependent membrane potential
23. Ion-adsorption effect on the interfacial tension at soft interfaces
23.1. Introduction
23.2. Surface tension of a lipid-monolayer-coated air/water interface
23. 3. Divalent-cation-induced membrane fusion
- No. of pages: 368
- Language: English
- Edition: 1
- Volume: 37
- Published: September 2, 2024
- Imprint: Academic Press
- Paperback ISBN: 9780443161162
HO
Hiroyuki Ohshima
Hiroyuki Ohshima is Professor Emeritus at the Tokyo University of Science, Japan. He received the B.S. (1968), M.S. (1970), and Ph.D. (1974) degrees in physics from the University of Tokyo. He spent his post-doc study at University of Melbourne, Australia (1981-1983), State University of New York at Buffalo, USA (1983-1984), and University of Utah, USA (1984-1985). He has worked at the Tokyo University of Science, Japan since 1985. He was previously a Professor of Pharmaceutical Sciences at the Tokyo University of Science (1994-2012) and is now a Professor Emeritus and a Visiting Professor.
He is the author of Theory of Colloid and Interfacial Electric Phenomena (Elsevier, 2006) and Biophysical Chemistry of Biointerfaces (Wiley, 2010). He edited Electrical Phenomena at Interfaces and Biointerfaces (Wiley, 2012) and Encyclopedia of Biocolloid and Biointerface Science (Wiley, 2016). He co-edited Electrical Phenomena at Interfaces. 2e (Marcel Dekker, 1998) and Colloid and Interface Science in Pharmaceutical Research and Development (Elsevier, 2014).
He is also the author or co-author of over 400 book chapters and journal publications, reflecting his research interests in colloid and interface science. He was an Editor of the journal Colloids and Surfaces B: Biointerfaces (1994-2012, Elsevier) and currently he is an Associate Editor of Colloid and Polymer Science (2002-present, Springer).
In 2016, Ohshima was awarded the 29th Khwarizmi International Award by the Iranian Research Organization for Science and Technology for his contribution to the theory of colloid and interfacial electric phenomena. In 2017, he was selected as one of Asia's top 100 scientists for 2017 (The Asian Scientist Magazine, June 2017). In 2022, he was awarded Fellow of Japan Oil Chemists' Society. On January 13, 2021, the layman's summary of Ohshima’s research article: Gel Electrophoresis of a Soft Particle (Adv. Colloid Interface Sci., 271, 101977, 2019) was published on the Atlas of Science website (https://atlasofscience.org/soft-particle-gel-electrophoresis/).
Affiliations and expertise
Professor Emeritus, Faculty of Pharmaceutical Sciences, Tokyo University of Science, Japan