Dynamic Processes in Solids
- 1st Edition - May 26, 2023
- Imprint: Elsevier
- Editor: James E. House
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 8 1 8 8 7 6 - 7
- eBook ISBN:9 7 8 - 0 - 1 2 - 8 1 8 8 7 9 - 8
The results obtained from kinetic studies on reactions in solids often depend on numerous factors. Therefore, it is important for researchers to understand how both chemical fa… Read more
Purchase options
Institutional subscription on ScienceDirect
Request a sales quoteThe results obtained from kinetic studies on reactions in solids often depend on numerous factors. Therefore, it is important for researchers to understand how both chemical factors related to composition and procedural choices may influence outcomes. Dynamic Processes in Solids provides an authoritative overview of reactions in solids and helps readers interpret the results obtained from kinetic studies. In chapters written by active researchers, the reader will learn about choosing appropriate experimental techniques and their limitations for studying various types of reactions. Beginning with an introduction to numerous aspects of rate processes in solids and experimental techniques, information is provided on rate laws, factors affecting rates, diffusion, and sintering. Subsequent chapters deal with electrical conductivity in dispersed phase polymers, thermochemical reactions for producing solid materials, reactions in coordination compounds, dynamic observations on plastic deformation, light driven phenomena in quantum materials, decomposition of perovskite photovoltaic compounds, and reaction of oxygen radicals with surfaces. This book is a practical introduction to the field for chemists and researchers whose work is directly related to dynamic changes in solids, and additionally for those in related fields whose work would be enhanced by an understanding of these types of rate processes.
- Presents useful discussions of the applications of several experimental techniques
- Describes approaches for synthesis of solid materials by thermochemical reactions
- Presents theoretical interpretation structural dynamics and processes at the molecular level in solids
- Provides information on the relationships between performance and rate processes in several types of materials related to electronic behavior
Chemists, Materials Scientists, Physicists, Chemical Engineers, Geologists, Nucelar Scientists, Pharmaceutical Scientists, Food chemists, and students and researchers in related fields across both academia and industry
- Cover image
- Title page
- Table of Contents
- Copyright
- List of contributors
- Preface
- Chapter 1. Some aspects of dynamic processes in solids
- Abstract
- 1.1 Basic concepts related to dynamic processes in solids
- 1.2 Rate laws for dynamic processes in solids
- 1.3 Factors affecting reaction rates in solids
- 1.4 Reactions produced by mechanical forces
- 1.5 Phase transitions
- 1.6 Sintering
- 1.7 Diffusion
- References
- Chapter 2. Thermochemical reaction strategies for the rapid formation of inorganic solid-state materials
- Abstract
- 2.1 Introduction and background on general solid-state synthesis approaches
- 2.2 Summary and future outlook
- References
- Chapter 3. Structural dynamics in amorphous oxide semiconductors and its role in defect formation, electron transport and optical transparency
- Abstract
- 3.1 Introduction
- 3.2 Time-resolved structural properties of AOS at room temperature
- 3.3 Structure–property relationships of defects in AOS
- 3.4 Structural dynamics at room temperature
- 3.5 Transformation of the electronic states in AOS
- 3.6 Conclusion
- Acknowledgment
- References
- Chapter 4. Metastability in complex alloys: controlling transformations and microstructure for properties
- Abstract
- 4.1 Introduction
- 4.2 Brief review of chemical equilibrium and transformation kinetics
- 4.3 Thermodynamics and diffusion in high entropy alloys
- 4.4 Metallic glasses
- 4.5 Microstructural metastability
- 4.6 Conclusion/outlook
- Acknowledgments
- References
- Chapter 5. Oxide thermoelectrics: a review and a case study
- Abstract
- 5.1 Experimental details
- 5.2 Results and discussion
- 5.3 Conclusion
- References
- Chapter 6. Electrical conduction in dispersed phase solid polymer electrolytes: the dielectric and electric modulus approach
- Abstract
- 6.1 Introduction
- 6.2 Experimental
- 6.3 Impedance analysis
- 6.4 Dielectric study
- 6.5 Electric modulus
- 6.6 AC conductivity
- 6.7 Transport properties
- 6.8 Summary
- References
- Chapter 7. Aspects of oxygen radical interactions with surfaces: effects of relative flux and kinetic energy
- Abstract
- 7.1 Introduction
- 7.2 Methods of O(3P) production
- 7.3 O(3P) versus O(1D) collision reaction from ab initio dynamics simulations
- 7.4 Results and discussion
- 7.5 O(3P)-assisted atomic layer deposition: O/O2 flux ratio dependencies
- 7.6 Summary and conclusion
- References
- Chapter 8. Reactions of coordination compounds in the solid state
- Abstract
- 8.1 Introduction
- 8.2 Cis/trans-isomerization reactions
- 8.3 Linkage isomerization reactions
- 8.4 Anation reactions
- 8.5 Racemization reactions
- 8.6 Synthesis of coordination compounds by mechanochemical methods
- 8.7 Conclusion
- References
- Chapter 9. Dynamic processes in decomposition of solid perovskite photovoltaic compounds
- Abstract
- 9.1 Introduction
- 9.2 Hydrogen bonding
- 9.3 Perovskite compounds containing substituted ions
- 9.4 Phase transitions
- 9.5 Instability of methylammonium lead halides
- 9.6 Kinetic and thermodynamic influences
- 9.7 Effect of external influences
- 9.8 Kinetic studies on methylammonium lead iodide
- 9.9 Some results of studies from application of thermal analysis methods
- 9.10 Perovskite photovoltaic compounds containing formamidinium ions
- 9.11 Conclusion
- References
- Chapter 10. In situ electron microscopy: modalities of dynamic measurements to capture fundamental physical or chemical processes down to the atomic scale
- Abstract
- 10.1 Introduction
- 10.2 Dynamic observation
- 10.3 Integration with data analytics
- 10.4 Future work
- References
- Chapter 11. Light-driven phenomena in quantum materials
- Abstract
- 11.1 Introduction
- 11.2 Floquet engineering in quantum materials
- 11.3 Quantum materials
- 11.4 Technological advances for experiments
- 11.5 Light-driven quantum materials
- 11.6 Summary and outlook
- Acknowledgment
- References
- Index
- Edition: 1
- Published: May 26, 2023
- Imprint: Elsevier
- No. of pages: 350
- Language: English
- Paperback ISBN: 9780128188767
- eBook ISBN: 9780128188798
JH
James E. House
James E. House is Emeritus Professor of Chemistry at Illinois State University, USA, and Scholar in Residence at Illinois Wesleyan University, USA. He received B.S. and M.A. degrees from Southern Illinois University and the Ph.D. from the University of Illinois, Urbana. In over 50 years of teaching, he taught numerous courses in inorganic and physical chemistry and several special topics courses. His research resulted in over 150 publications in professional journals, many dealing with reactions of solids. He has authored several books on kinetics, quantum mechanics, and inorganic chemistry for Elsevier. He is the Series Editor for Developments in Physical & Theoretical Chemistry for Elsevier and has also edited volumes in the series. House was elected as a Fellow of the Illinois State Academy of Science and he has done extensive consulting in the chemical industry. He was selected as Professor of the Year in 2011 by the student body at Illinois Wesleyan University and in 2018 he was inducted into the Southern Illinois University Chemistry Alumni Hall of Fame.
Affiliations and expertise
Emeritus Professor of Chemistry, Illinois State University and Scholar in Residence, Illinois Wesleyan University, USARead Dynamic Processes in Solids on ScienceDirect