Limited Offer
Chemical and Biochemical Applications
- 1st Edition - December 2, 2012
- Editor: Pierre Laszlo
- Language: English
- Paperback ISBN:9 7 8 - 0 - 1 2 - 4 3 3 3 2 3 - 9
- eBook ISBN:9 7 8 - 0 - 3 2 3 - 1 5 6 3 4 - 9
NMR of Newly Accessible Nuclei, Volume 1: Chemical and Biochemical Applications is a 10-chapter text that explores the properties, advantages, developments, and chemical and… Read more
Purchase options
Institutional subscription on ScienceDirect
Request a sales quoteNMR of Newly Accessible Nuclei, Volume 1: Chemical and Biochemical Applications is a 10-chapter text that explores the properties, advantages, developments, and chemical and biochemical applications of NMR technique. This book describes first the operation of an NMR spectrometer under its two aspects, namely, the instrumental and the computational aspects. The next chapters are devoted to some of the most important pulse sequences. The discussion then shifts to the various factors determining the position of the observed absorption and those responsible for the various relaxation processes. The last chapters deal with the specific applications of NMR, including in cation salvation, calcium-binding proteins, polyelectrolyte systems, halogens, and antibiotic ionophores. This book is of value to inorganic and analytical chemists, and biophysicists.
Contributors
General Preface
Preface to Volume 1
Contents of Volume 2
A. General Features
1. Multinuclear Instrumentation and Observation
I. Introduction
II. The Multinuclear NMR Spectrometer
III. Multinuclear Observation
References
2. Techniques That Can Enhance Sensitivity, Improve Resolution, Correlate NMR Spectral Parameters, and Lead to Structural Information
I. Introduction
II. Sensitivity Enhancement Techniques
III. The Nuclear Overhauser Effect
IV. Sensitivity Enhancement via Population Transfer
V. How to Determine the Number of Protons Directly Coupled to Heteronucleus
VI. How to Determine the Chemical Shifts of the Protons Directly Coupled to a Heteronucleus
VII. How to Determine Whether a Heteronucleus Is Directly Coupled to a Like Heteronucleus
VIII. How to Determine Whether Two Nuclei Belong to the Same Coupling Network
IX. Resolution Enhancement Techniques
X. Concluding Remarks
References
3. Computational Considerations
I. Data Acquisition
II. Basic Data Reduction
III. Extended Features of FT NMR Processing
IV. Special Problems of Broad Line Spectra
V. Current Trends in NMR Computation
References
4. Factors Contributing to the Observed Chemical Shifts of Heavy Nuclei
I. Introduction
II. Intramolecular Factors
III. Intermolecular Factors
References
5. Quadrupolar and Other Types of Relaxation
I. Introduction
II. Relaxation in the Region of Motional Narrowing
III. The Rotational Correlation of Time
IV. Relaxation Interactions Modulated by Molecular Rotation
V. Relaxation of Quadrupolar Nuclei
VI. The Future
References
B. Selected Features
6. Cation Solvation
I. Introduction
II. Chemical Shift Measurements
III. Nuclear Magnetic Relaxation
References
7. Calcium-Binding Proteins
I. Introduction
II. An Overview of Calcium-Binding Proteins
III. Structure of the Calcium-Binding Site
IV. Nuclear Magnetic Resonance Studies of Calcium-Binding Proteins
V. Future Studies
References
8. Amphiphilic and Polyelectrolyte Systems
I. Polyelectrolytes: Polycharged Macromolecules and Aggregates of Ionic Amphiphiles
II. Counterion Binding: Methods and Theories
III. Counterion Binding: Quadrupole Splittings
IV. Counterion Binding: Quadrupole Relaxation
V. Quadrupole Relaxation Studies on Counterion Binding to Polyelectrolytes
VI. Quadrupole Relaxation and Chemical Shift Studies on Counterion Binding in Amphiphilic Systems
VII. Quadrupole Splitting Studies on Counterion Binding in Amphiphilic Systems
VIII. Hydration in Colloidal Systems: General Aspects and NMR Methods
IX. Deuteron NMR for Phase Diagram Determination in Surfactant Systems
X. 2H- and 17O-NMR Quadrupole Splittings and Hydration in Amphiphilic Mesophases
XI. 17O-NMR Relaxation and the Hydration of Surfactant Micelles and Polyelectrolytes
References
9. Chlorine, Bromine, and Iodine
I. Introduction
II. Halide Ions in Aqueous and Nonaqueous Solutions
III. The ClO4- Ion
IV. Surfactant Systems
V. Macromolecular Systems
VI. Covalently Bonded Halogens
VII. Conclusions
References
10. Antibiotic Ionophores
I. Introduction
II. Solution Conformation
III. Nuclear Magnetic Resonance Studies of Ion-Ionophore Interactions in Solution
IV. Nuclear Magnetic Resonance Studies in Membranal Systems
References
Index
- No. of pages: 316
- Language: English
- Edition: 1
- Published: December 2, 2012
- Imprint: Academic Press
- Paperback ISBN: 9780124333239
- eBook ISBN: 9780323156349
Read Chemical and Biochemical Applications on ScienceDirect