Calorimetric Methods for the Characterization of Porous Materials
- 1st Edition - April 1, 2024
- Imprint: Elsevier Science
- Authors: Juan Carlos Moreno-Piraján, Liliana Giraldo Gutiérrez, Fernando Gómez-Granados, Diana Cristina Hernández-Monje
- Language: English
- Paperback ISBN:9 7 8 - 0 - 4 4 3 - 1 3 7 9 6 - 9
- eBook ISBN:9 7 8 - 0 - 4 4 3 - 1 3 7 9 7 - 6
Calorimetric Methods for the Characterization of Porous Materials presents calorimetric methods used in the characterization of porous materials using chemical thermodyn… Read more
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Request a sales quoteCalorimetric Methods for the Characterization of Porous Materials presents calorimetric methods used in the characterization of porous materials using chemical thermodynamics. Among these materials, catalysts, supports and adsorbents (such as Activated Carbon, Metal-Organic-Frameworks, SBA-15, Zeolites, Graphene, Graphite, Carbon Foams) are presented. In addition, the use of calorimetry in the study of catalytic reactions in different phases is explored—applicable to air and wastewater treatment, clean and renewable energies, green chemistry, as well as energy production and storage (Carbon dioxide, methane and hydrogen at high pressure). Chapters summarize basic concepts of thermodynamics and kinetics alongside experimental techniques such as thermal analysis and calorimetry. In addition, information is given about different calorimetric methods that can be used in studies aimed at characterizing the physicochemical properties of adsorbents, supports and solid catalysts, as well as the processes related to the adsorption-desorption phenomena of the reactants and/or products of catalytic reactions.
- Addresses the problems involved with the chemical thermodynamics of porous materials, with a significant practical element explaining experimental parameters and how to perform calculations
- Presents, in detail, the main instrumental calorimetric methods, including those that must be carefully considered to avoid experimental errors
- Demonstrates, step-by-step, how to perform calculations using data obtained from instrumentation to achieve reliable results
- Provides novel explanations on how to use calorimetry in catalyst characterization
- Allows readers to broaden the spectrum of the application of calorimetry in the study of materials
Graduate level students and postdoc researchers in chemistry, chemical engineering, and materials science. Professionals working in industries including petroleum, polymers, and alternative energy (storage of gases such as methane, CO2, hydrogen)
- Cover image
- Title page
- Table of Contents
- Copyright
- Preface
- Chapter 1. Calorimetry: overview of historical development, instrumentation design, and construction criteria
- Abstract
- 1.1 Historical development of calorimetry
- 1.2 Criteria for design and construction of calorimeters
- 1.3 Conclusions
- References
- Chapter 2. Calorimetry and thermodynamics conceptualization
- Abstract
- 2.1 From the first civilizations to alchemy: calorimeter development
- 2.2 Concepts of calorimetry and thermodynamics: evolution of the main concepts
- 2.3 Thermoelectric phenomena
- 2.4 Temperature sensors
- 2.5 Modes of heat conduction
- 2.6 Conclusions
- References
- Chapter 3. Instrumental aspects
- Abstract
- 3.1 Electrical calibration
- 3.2 Chemical calibration systems for calorimeters of solutions
- 3.3 Chemical calibration systems for titration calorimeters
- 3.4 Dissolution heat for some gases
- 3.5 Sorption heat
- 3.6 Photocalorimetry
- 3.7 Vaporization and sublimation heats
- 3.8 Conclusions
- References
- Chapter 4. Calorimetry for the solid–liquid interface
- Abstract
- 4.1 Introduction
- 4.2 Immersion energy of a solid into a pure liquid
- 4.3 Adsorption from liquid solutions
- 4.4 Conclusions
- References
- Chapter 5. Study of gas-phase systems by adsorption calorimetry
- Abstract
- 5.1 Introduction to gas adsorption calorimetry
- 5.2 Equipment available
- 5.3 Calorimetric procedures
- 5.4 Gas physisorption isotherm analysis
- 5.5 Density functional theory
- 5.6 Calorimetric methods
- 5.7 Conclusions
- References
- Chapter 6. Application studies using calorimetry for selective gas adsorption systems
- Abstract
- 6.1 Introduction
- 6.2 Definition of selective adsorption
- 6.3 Determination of adsorption entropy and enthalpy from single adsorption isotherms
- 6.4 Determination of coadsorption entropy and enthalpy using calorimetry
- 6.5 Case studies
- 6.6 Conclusions
- References
- Chapter 7. Catalytic and kinetic studies by calorimetry
- Abstract
- 7.1 Introduction
- 7.2 Acid, basic, and amphoteric oxides
- 7.3 Heterogeneous character of oxides
- 7.4 Single oxides, doped and modified oxides, supported oxides, mixed oxides, and complex oxides
- 7.5 Acidity prediction from composition
- 7.6 Intrinsic and effective acidity of oxide surfaces
- 7.7 Characterization of acid–base sites in zeolites
- 7.8 Studies cases
- 7.9 Correlation between adsorption heat and catalytic activity
- 7.10 Conclusion
- References
- Chapter 8. Contributions of calorimetry for the advancement of science
- Abstract
- 8.1 Hydrogen and calorimetry: case studies
- 8.2 Second case study: reversible H2 storage (Mg-based materials)
- 8.3 CO adsorption microcalorimetry on Pt-based materials: literature review
- 8.4 CO2 industrial effluents capture: calorimetric studies
- 8.5 Conclusions
- References
- Chapter 9. Contributions of calorimetry to biology and pharmacy
- Abstract
- 9.1 Introduction
- 9.2 Principles of isothermal titration calorimetry
- 9.3 ITC applications on life sciences
- 9.4 Thermodynamic signatures of noncovalent interactions
- 9.5 Thermodynamic discrimination
- 9.6 ITC as a tool for studying drug–DNA interactions
- 9.7 ITC as a tool for studying protein–DNA interactions
- 9.8 The application of calorimetry for examining hydration effects
- 9.9 The use of ITC for studying the kinetics and thermodynamics of enzyme catalysis
- 9.10 Future prospects
- 9.11 Conclusions
- References
- Index
- Edition: 1
- Published: April 1, 2024
- No. of pages (Paperback): 264
- No. of pages (eBook): 352
- Imprint: Elsevier Science
- Language: English
- Paperback ISBN: 9780443137969
- eBook ISBN: 9780443137976
JM
Juan Carlos Moreno-Piraján
Juan Carlos Moreno-Piraján studied chemistry and obtained its PhD in Chemistry at the Universidad Nacional de Colombia and as of July 1995 he is linked to the chemistry department of the Faculty of Sciences of the Universidad de los Andes (Bogotá, Colombia). Obtaining a Magna Cum Laude grade both in his undergraduate thesis as well as in his PhD thesis. He is Director of the Porous Solids and Calorimetry research group. His area of interest is calorimetry applied to the characterization of porous solids, which he uses in the characterization of special materials. He designs and builds his own calorimeters in particular immersion and adsorption calorimeters. He has more than 350 publications on thermodynamics to his name
Affiliations and expertise
Full Professor, Department of Chemistry, Universidad de los Andes, Bogotá, ColombiaLG
Liliana Giraldo Gutiérrez
Liliana Giraldo Gutierrez studied chemistry and obtained her PhD in Chemistry at the Universidad Nacional de Colombia. She has been linked to this university since 1990, obtaining a Magna Cum Laude grade both in her undergraduate thesis as well as in her PhD thesis. She is director of the Calorimetry Laboratory of the Department of Chemistry. Her area of interest is calorimetry, which she uses in the characterization of special materials. She designs and builds her own calorimeters. She has more than 300 publications on thermodynamics to her name.
Affiliations and expertise
Full Professor, Department of Chemistry, Universidad Nacional de Colombia, Bogotá, ColombiaFG
Fernando Gómez-Granados
Fernando Gómez-Granados graduated from the Universidad Nacional de Colombia, a specialist in Geographic Information Systems from the Instituto Geográfico Agustín Codazzi Universidad Distrital, Ph.D. in Analytical Chemistry of the Environment and Contamination from the Universitat de Barcelona, Spain with research in analytical methodology for the determination of antibiotic residues in environmental samples. Currently, he is an Associate Professor in the Department of Chemistry at the Universidad Nacional de Colombia, teaching in analytical chemistry. Has held academic–administrative positions in the Department of Chemistry (academic coordination) and the Curricular Area of Chemistry (director). He has worked in coal exploitation and characterization research, including petrographic analysis. He also worked in the formulation of mixtures and production of metallurgical coke, as well as in the design of databases and implementation of geographic information systems of the coal resource. His interest is currently focused on the study of adsorption processes of different analytes with activated carbon prepared, characterized, and modified from carbon materials.
Affiliations and expertise
Associate Professor, Department of Chemistry, Universidad Nacional de Colombia, Bogotá, ColombiaDH
Diana Cristina Hernández-Monje
Diana Hernández-Monje obtained her bachelor’s degree in chemistry at Universidad Pedagógica Nacional in 2009, her MSc. degree in Chemistry 2017 (Magna Cum Laude) at Universidad Nacional de Colombia and she obtained her PhD degree in Chemistry in 2022 at Universidad Nacional de Colombia (Summa cum laude). Her interest area is related to porous solids, immersion calorimetric studies, enthalpic characterizations and gas phase adsorption. She performs VOCs adsorption on gas and liquid phase and calorimetric determinations, according to that, she has written 11 scientific publications related to her research activity.
Affiliations and expertise
Research Assistant, Department of Chemistry, Department of Chemistry, Universidad Nacional de Colombia, Bogotá, ColombiaRead Calorimetric Methods for the Characterization of Porous Materials on ScienceDirect