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Alicyclic Compounds
A Modern Comprehensive Treatise
- 2nd Edition - January 1, 1974
- Editor: M. F. Ansell
- Language: English
- Hardback ISBN:9 7 8 - 1 - 4 8 3 1 - 9 6 2 7 - 5
- Paperback ISBN:9 7 8 - 1 - 4 8 3 2 - 0 7 8 7 - 2
- eBook ISBN:9 7 8 - 1 - 4 8 3 2 - 2 1 3 0 - 4
Supplements to the Second Edition of Rodd’s Chemistry of Carbon Compounds, Volume II: Alicyclic Compounds: Part C: Polycarbocyclic Compounds, Excluding Steroids covers the… Read more
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Request a sales quoteSupplements to the Second Edition of Rodd’s Chemistry of Carbon Compounds, Volume II: Alicyclic Compounds: Part C: Polycarbocyclic Compounds, Excluding Steroids covers the classification, natural products, and biogenesis of polycarbocyclic compounds. This book is divided into 11 chapters. Considerable chapters are devoted to the classification and nomenclature of polycarbocyclic compounds, including bicyclic monoterpenoids, sesquiterpenoids, diterpenoids, sesterterpenoids, and triterpenoids. Other chapters deal with the classification and nomenclature of selective steroids, such as steroids, bile acids, sex hormones, saponins, and sapogenins. The concluding chapter highlights the biogenesis of terpenes and sterols. This book is an ideal source for organic chemists and researchers.
Preface
Official Publications; Scientific Journals and Periodicals
List of Common Abbreviations and Symbols Used
Chapter 9. Polycarbocyclic Compounds with Separate Ring-Systems, and Spiro Compounds
1. Introduction
2. Compounds with Rings Joined Directly or through a Carbon Chain
3. Spiro Compounds; Spirans
a. Preparative Methods
b. Properties
Chapter 10. Polycyclic Compounds. Fused or Condensed Cyclic Systems
1. The Bicyclo[1.1.0]Butane Group
2. The Bicyclo[2.1.0]Pentane Group
3. The Bicyclo[3.1.0]Hexane Group
4. The Bicyclo[4.1.0]Heptane Group
5. The Bicyclo[5.1.0]Octane Group
6. The Bicyclo[6.1.0]Nonane Group
7. The Bicyclo[2.2.0]Hexane Group
8. The Bicyclo[3.2.0]Heptane Group
9. The Bicyclo[4.2.0]Octane Group
10. The Bicyclo[6.2.0]Decane Group
11. The Bicyclo[3.3.0]Octane Group
12. The Bicyclo[4.3.0]Nonane Group
13. The Bicyclo[4.4.0]Decane Group
14. Highly Condensed Systems
Chapter 11. Polycarbocyclic Bridged Ring Compounds
1. Introduction
a. General Methods of Synthesis
b. Bredt's Rule
c. Bridged Carbonium Ions
d. Molecular Orbital Theory
e. Nuclear Magnetic Resonance Spectroscopy (n.m.r.)
f. Fluxional Molecules
2. The Bicyclo[1.1.1]Pentane Group
3. The Bicyclo[2.1.1]Hexane Group
Preparation
4. The Bicycloheptane Group
a. The Bicyclo[3.1.1]Heptane Group
b. The Bicyclo[2.2.1]Heptane Group
5. Polycyclic Compounds Derived from Cyclopentadiene
a. Oligomerisation Products of Cyclopentadiene
6. The Bi- and Tri-Cyclooctane Group
Mechanism and Structure
a. The Bicyclo[2.2.2]Octane Group
b. The Bicyclo[3.2.1]Octane Group
c. The Tricyclo[3.3.0.02,8]Octane Group
7. The Polycyclo[3.3.1]Nonane Group
a. The Bicyclo[3.3.1]Nonane Group
b. The Tricyclo[3.3.1.02,8]Nonane Group
c. The Tricyclo[3.3.1.03,7]Nonane Group
d. The Tetracyclo[3.3.1.02,8.04,6]Nonane, Triasterane, Group
8. The Bicyclo[3.2.2]Nonane Group
Preparation
9. The Bicyclo[4.2.1]Nonane Group
Preparation
10. The Bicyclo[4.2.2]Decane Group
Mechanism and Structure
Preparation
11. The Tricyclodecane Group
a. The Tricyclo[3.3.2.02,8]Decane Group
b. The Tricyclo[3.3.1.13,7]Decane, Adamantane, Group
12. The Bicyclo[3.3.3]Undecane Group
Chapter 12. Bicyclic Monoterpenoids
1. Introduction
2. The Thujane Group
3. The Carane Group
4. The Pinane Group
5. The Norbornane Group
a. Camphene and Related Compounds
b. Bornane (Camphane) Derivatives
c. Fenchane Derivatives
Chapter 13. The Sesquiterpenoids
1. Introduction
2. Acyclic Types
(i) Hydrocarbons
(ii) Oxygenated Derivatives
3. Monocyclic Types
4. Cyclopentylcyclohexanes
(i) Hydrocarbons
(ii) Oxygenated Derivatives
5. Bicyclo[4.1.0]Heptanes
(i) Hydrocarbons
(ii) Oxygenated Derivatives
6. Bicyclo[4.4.0]Decanes
(i) Hydrocarbons
(ii) Oxygenated Derivatives
7. Bicyclo[4.3.0]Nonanes
8. Bicyclo[5.3.0]Decanes
(i) Hydrocarbons
(ii) Oxygenated Derivatives
9. Spiro Compounds
(i) Hydrocarbons
(ii) Oxygenated Derivatives
10. Polycyclic Systems
(i) Hydrocarbons
(ii) Oxygenated Derivatives
11. Macrocyclic Sesquiterpenes
(i) Hydrocarbons
(ii) Oxygenated Derivatives
Chapter 14. Diterpenoids, Sesterterpenoids and Triterpenoids
1. Introduction
2. Diterpenoids
a. Bicyclic Diterpenoids
b. Tricyclic Diterpenoids
c. Tetracyclic Diterpenoids
d. The Cembrane Group
e. Eremolactone
3. Sesterterpenoids
4. Triterpenoids
(a) The Fusidanes
(b) Group A
(c) Group B
5. Laboratory Synthesis
a. Diterpenoids
b. Triterpenoids
Chapter 15. Steroids: Sterols and Bile Acids
1. Introduction
2. Geometry of the Steroid Nucleus
3. Structure in Relation to Physical Properties
4. Principal Chemical Reactions
(i) Color Reactions
(ii) The 3,5-Cyclosteroid Rearrangement and Related Reactions
(iii) Backbone Rearrangements and Related Reactions
(iv) Side-Chain Oxidation
(v) Epoxidation of Δ5-Stenols and Related Compounds
(vi) Reactions of 7-Dehydrosterols
(vii) Stanols
(viii) Stanones
(ix) Remote Oxidation
5. individual Sterols and Related Compounds
a. The Cholesterol Series
b. Ergosterol and Related Compounds
c. Other Sterols
d. Miscellaneous Structural Type
6. Bile Acids
Additions
Chapter 16. Steroids: Sex Hormones; Adrenocortical Hormones
1. Sex Hormones and Related Compounds
a. Oestrogens
b. The Gestogens
c. The Androgens
d. Homosteroids
e. Synthesis of Adrenocortical Steroids
2. Adrenocortical Hormones
d. Aldosterone
3. Cyclosteroids
4. Dimeric Steroid Hormones
5. Halogenated Steroids
a. Oestrogens
b. Androgens
c. Gestogens
6. Other Substituted Steroids
b. Pregnane Series
Chapter 17. Steroids: Cardiotonic Glycosides and Aglycons; Toad Poisons
Digoxin Derivatives
Digitoxigenin and Derivatives
Canarigenin (Δ4-Analogue of Digitoxigenin)
Uzarigenin and Related Compounds
Digitalis Glycosides and Aglycons
Digitoxigenone
Toad Poisons, etc
Chapter 18. Steroid Saponins and Sapogenins
1. The Saponins
2. The Sapogenins
Sources and Isolation
Biogenesis
Physical Properties
New Sapogenins
Aminospirostans
Reactions of the Sapogenin Side-Chain
Chapter 19. Biogenesis of Terpenes and Sterols
1. Introduction
2. Biosynthesis of Mevalonate (MVA)
3. Hemiterpenes
4. Monoterpenes
5. Sesquiterpenes
6. Diterpenes
8. Triterpenes
(i) General
(ii) Demethylation Reactions
(iii) Alkylation at C(24)
(iv) Insertion of Double Bonds
(v) Spirostanols
(vi) Cardenolides
(vii) Bufatenolides
(viii) Ecdysones
9. The Tetraterpenoids: the Carotenoids
(i) Prephytoene
(ii) Desaturation of Phytoene
(iii) Cyclisation of Lycopene
(iv) Xanthophyll Formation
(v) C45 and C50 Carotenoids
(vi) Biosynthesis in Photosynthetic Bacteria
10. Terpenoid Quinones
Index
- No. of pages: 336
- Language: English
- Edition: 2
- Published: January 1, 1974
- Imprint: Elsevier
- Hardback ISBN: 9781483196275
- Paperback ISBN: 9781483207872
- eBook ISBN: 9781483221304