Advances in Polymer Reaction Engineering

1st Edition, Volume 56 - October 30, 2020
Imprint: Academic Press
Editors: Davide Moscatelli, Mattia Sponchioni
Language: English
Hardback ISBN:
9 7 8 - 0 - 1 2 - 8 2 0 6 4 5 - 4
eBook ISBN:
9 7 8 - 0 - 1 2 - 8 2 1 5 2 2 - 7

Advances in Polymer Reaction Engineering, Volume 56 in the Advances in Chemical Engineering series is aimed at reporting the latest advances in the field of polymer synthesis. Ch… Read more

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Advances in Polymer Reaction Engineering, Volume 56 in the Advances in Chemical Engineering series is aimed at reporting the latest advances in the field of polymer synthesis. Chapters in this new release include Polymer reaction engineering and composition control in free radical copolymers, Reactor control and on-line process monitoring in free radical emulsion polymerization, Exploiting pulsed laser polymerization to retrieve intrinsic kinetic parameters in radical polymerization, 3D printing in chemical engineering, Renewable source monomers in waterborne polymer dispersions, Importance of models and digitalization in Polymer Reaction Engineering, Recent Advances in Modelling of Radical Polymerization, and more.

Cover image
Title page
Table of Contents
Copyright
Contributors
Chapter One: Perspectives, pillars, and examples of polymer reaction engineering in the 21st century
Abstract
1: The evolution of polymer reaction engineering
2: The question and request for perspectives
3: Excerpts from the responses
4: Kinetic rate coefficients as a core element of PRE
5: Why are the propagation rate coefficients for the homologous series of methacrylates different?
6: Pulsed-laser polymerization (PLP) and coupled with size exclusion chromatography (PLP-SEC)
7: An approach to rate parameter estimation for reactive sites on sidechains pendent to the primary chain backbone
8: Concluding remarks
Chapter Two: On-line monitoring and control of emulsion polymerization reactors
Abstract
1: Introduction
2: On-line monitoring and estimation of polymer latex characteristics
3: On-line control of polymer characteristics in emulsion polymerization
4: Conclusions and outlook
Chapter Three: Exploiting the pulsed laser polymerization-size exclusion chromatography technique to retrieve kinetic parameters in radical polymerization: State-of-the-art and future challenges
Abstract
1: Introduction
2: One mode propagation reactivities from PLP inflection point data
3: Multi-mode propagation reactivities from PLP inflection point data
4: Bulk vs solution PLP inflection point data
5: Determination of quantum yield and other chemical reactivities from the complete PLP-SEC trace
6: Conclusions and perspectives
Chapter Four: 3D printing as chemical reaction engineering booster
Abstract
1: Introduction
2: Equipment and technology
3: 3D printed equipment
4: Reactors and reactions
5: Conclusion and outlook
Chapter Five: Renewable feedstocks in emulsion polymerization: Coating and adhesive applications
Abstract
1: Introduction
2: Renewable resource reagents in waterborne polymeric dispersions for coatings and adhesives applications
3: Conclusions and future perspectives
Chapter Six: Toward a digital polymer reaction engineering
Abstract
1: What is digitalization and why do we need it?
2: Digital twins for polymer reaction engineering
3: Toward digital twins
4: Outlook
5: Conclusions
Chapter Seven: From batch to continuous free-radical polymerization: Recent advances and hurdles along the industrial transfer
Abstract
1: General features of continuous polymerization processes
2: Homogeneous polymerization
3: Heterogeneous polymerization
4: Microreactors
5: Successful case studies
6: Conclusions
Chapter Eight: Perspectives from industry
Abstract
1: News in polyolefin production
2: News in rubber production
3: News in bio polymer and process
4: News in polymer coating
5: News in polymer composites
6: News in polymer plants
7: News in polymer compositions
8: News in flow chemistry
9: News in emulsion/suspension polymerization
10: News in polymer extrusion
Index

Davide Moscatelli

Davide Moscatelli received his Laurea cum laude in Chemical Engineering at the Politecnico di Milano in 2002, and his PhD in Chemical Engineering in 2006. He is full professor of Applied Physical Chemistry at Politecnico di Milano and he collaborates with ETH Zurich since 2007. His main research interests are in the material synthesis for technological applications, with particular emphasis on polymer materials, nanomaterials and chemical compounds for biomedical and oil&gas applications. The general aim of his research is the development of new approaches to synthesize and functionalize innovative, efficient, and tunable smart materials. Davide Moscatelli is co-author of more than 120 papers on international journals and more than 10 patents. H-index: 26. Davide Moscatelli serves as lecturer of Petroleum Technologies and Refining Processes course at Politecnico di Milano. Davide Moscatelli supervised more than 100 Bachelor thesis students in Chemical Engineering, more than 100 Master thesis students in Chemical Engineering and Material Engineering, and more than 10 PhD theses in Industrial Chemistry and Chemical Engineering. He is ViceDirector of the PhD course of Industrial Chemistry and Chemical Engineering at Politecnico di Milano (http://phd.chem.polimi.it/staff/) and, since 2017, he is Member of the Faculty Committee for the strategic plan Polimi2040 at Politecnico di Milano. Davide Moscatelli is a member of the editorial board and advisory panel of several international scientific journals. He is co-founder of Captive Systems srl, a spin-off company of Politecnico di Milano active in use of smart nanomaterials for wastewater treatments.

Affiliations and expertise

Full Professor, Politecnico di Milano, Italy

Mattia Sponchioni

Mattia Sponchioni received his MSc cum laude in Chemical Engineering in 2015 and his PhD cum laude in Industrial Chemistry and Chemical Engineering in 2018, both at Politecnico di Milano. He is now working as a Research Associate at Politecnico di Milano, after having spent one year of Post-Doc at ETH Zürich. The main research interests of Mattia Sponchioni include the synthesis of thermo-responsive polymers and functional polymer nanoparticles for biomedical applications. During his career, Mattia gained expertise in the so-called controlled radical polymerization (CRP) techniques and in particular in the reversible addition-fragmentation chain transfer (RAFT) polymerization to impart highly controlled molecular architecture and chain length distribution to the polymers produced in his research. It is in this context that in 2017 Mattia spent six months as a visiting researcher at the University of Sheffield, in the group of Prof. Steven P. Armes, where he became expert in the RAFT-mediated polymerization-induced self-assembly (PISA) for the simultaneous synthesis of well-defined and amphiphilic block copolymers and their self-assembly into nanoparticles. Mattia Sponchioni is currently participant contact for the EU H2020 Marie-Curie innovative training network “Continuous Downstream Processing of Bioproducts” (https://www.researchgate.net/project/CODOBIO-Continuous-Downstream-Processing-of-Biologics) and teaching assistant of “Polymer Reaction Engineering” and “Applied Physical Chemistry” at Politecnico di Milano.

Affiliations and expertise

Research Associate, Politecnico di Milano, Italy

Life Sciences

Physical Sciences & Engineering

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