Advances in Inorganic Chemistry: Recent Highlights

1st Edition, Volume 78 - October 5, 2021
Imprint: Academic Press
Editors: Rudi van Eldik, Colin D. Hubbard
Language: English
Hardback ISBN:
9 7 8 - 0 - 3 2 3 - 8 5 1 1 5 - 2
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 8 5 1 1 6 - 9

Advances in Inorganic Chemistry, Volume 78 presents timely and informative summaries on current progress in a variety of subject areas. Chapters in this new release include C… Read more

Advances in Inorganic Chemistry: Recent Highlights

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Advances in Inorganic Chemistry, Volume 78 presents timely and informative summaries on current progress in a variety of subject areas. Chapters in this new release include Catching reactive species in manganese oxidation catalysis, Mechanistic Puzzles from Iron(III) TAML Activators Including Substrate Inhibition, Zero-Order and Dual Catalysis, Stepping towards C-circular economy: Integration of solar chemistry and biosystems for efficient CO2 conversion into added value chemicals and fuels, Highlighting recent work on metal-coordinated and metallic nanoparticles as NIR imaging probes for biosensing application in living cells, and more.

Users will find this to be a comprehensive overview of recent findings and trends from the last decade that covers various kinds of inorganic topics, from theoretical oriented supramolecular chemistry, to the quest for accurate calculations of spin states in transition metals.

Cover image
Title page
Table of Contents
Copyright
Contributors
Preface
Chapter One: Gallium: New developments and applications in radiopharmaceutics
Abstract
1: Introduction
2: Gallium chelation
3: Gallium as an iron mimic
4: Radiolabeling nanoparticles with gallium-68
5: Use of radionuclide imaging to study gallium anti-cancer drugs
6: Gallium-67 as a therapeutic radionuclide
7: Gallium as a fluoride binding site for fluorine-18 radiopharmaceuticals
8: Summary and future prospects
Acknowledgments
References
Chapter Two: Metallic radionuclides for diagnostic imaging and cancer radiotherapy: The development of theragnostic matched pairs and targeted alpha therapy
Abstract
1: Introduction
2: Theragnostics with gallium-68 and lutetium-177
3: Theragnostics of somatostatin positive tumors with [64/67Cu]CuSARTATE
4: Theragnostics of PSMA overexpressing prostate cancer with [64/67Cu]CubisPSMA
5: A PSMA targeting copper-64/67 complex designed to bind to human serum albumin
6: Theragnostic pretargeted radioimmunotherapy with copper-64/67
7: Targeted alpha therapy with actinium-225
8: Complexes of actinium(III) with macrocyclic ligands
9: In vivo preclinical and clinical studies with actinium-225
10: Concluding remarks and future perspectives
References
Chapter Three: Development of BODIPYS and aza-BODIPYs for molecular imaging applications: From the in vitro to the in vivo
Abstract
1: Introduction
2: Development of bimodal and theranostic probes from BODIPYS emitting in the visible range
3: Optimization of the photophysical properties of BODIPY for in vivo imaging applications
4: Conclusion and perspectives
Acknowledgments
References
Chapter Four: MRI relaxation agents based on transition metals
Abstract
1: Introduction
2: Manganese chelates
3: Iron chelates
4: Conclusions and future perspectives
Acknowledgments
References
Chapter Five: Mechanisms in manganese oxidation catalysis with 1,4,7-triazacyclononane based ligands
Abstract
1: Introduction
2: Oxidation catalysis with N,N′,N″-trimethyl-1,4,7-triazacyclononane (Me3tacn) based manganese complexes
3: Me4DTNE and Pytacn
4: Perspectives and applications
Acknowledgments
References
Chapter Six: Mechanistic puzzles from Iron(III) TAML activators including substrate inhibition, zero-order and dual catalysis
Abstract
1: Introduction
2: Substrate inhibition
3: Zero-order catalysis
4: Dual catalysis
5: Dioxygen instead of hydrogen peroxide
6: Concluding remarks
Acknowledgments
References
Chapter Seven: Advances in gigantic polyoxomolybdate chemistry
Abstract
1: Introduction
2: Synthetic methodology and characterization
3: Manipulation and functionalization of MB wheels
4: Supramolecular chemistry
5: Application in materials
6: Conclusions and future perspectives
Acknowledgments
References
Chapter Eight: Optically detected NMR in a diamond-anvil cell for geochemistry
Abstract
1: Introduction
2: The physics of optically detected NMR (ODNMR)
3: Building an apparatus to reach geochemical pressures
4: Conclusions and future perspectives
Acknowledgments
References
Chapter Nine: Stepping toward the carbon circular economy (CCE): Integration of solar chemistry and biosystems for an effective CO2 conversion into added value chemicals and fuels
Abstract
1: Introduction
2: CO2 as a building block for chemicals
3: Solar driven chemistry: Our future
4: When sun meets biology and material science
5: Conclusions and perspectives
Acknowledgments
References
Index

Rudi van Eldik

Rudi van Eldik was born in Amsterdam (The Netherlands) in 1945 and grew up in Johannesburg (South Africa). He received his chemistry education and DSc degree at the former Potchefstroom University (SA), followed by post-doctoral work at the State University of New York at Buffalo (USA) and the University of Frankfurt (Germany). After completing his Habilitation in Physical Chemistry at the University of Frankfurt in 1982, he was appointed as Professor of Inorganic Chemistry at the Private University of Witten/Herdecke in 1987. In 1994 he became Professor of Inorganic and Analytical Chemistry at the University of Erlangen-Nürnberg, from where he retired in 2010. At present he is Professor of Inorganic Chemistry at the Jagiellonian University in Krakow, Poland, and Visiting Professor of Inorganic Chemistry at the N. Copernicus University in Torun, Poland. His research interests cover the elucidation of inorganic and bioinorganic reaction mechanisms, with special emphasis on the application of high pressure thermodynamic and kinetic techniques. In recent years his research team also focused on the application of low-temperature rapid-scan techniques to identify and study reactive intermediates in catalytic cycles, and on mechanistic studies in ionic liquids. He is Editor of the series Advances in Inorganic Chemistry since 2003. He serves on the Editorial Boards of several chemistry journals. He is the author of over 880 research papers and review articles in international journals and supervised 80 PhD students. He has received honorary doctoral degrees from the former Potchefstroom University, SA (1997), Kragujevac University, Serbia (2006), Jagiellonian University, Krakow, Poland (2010), University of Pretoria, SA (2010), and Ivanovo State University of Chemistry and Technology, Russia (2012). He has developed a promotion activity for chemistry and related experimental sciences in the form of chemistry edutainment presentations during the period 1995-2010. In 2009 he was awarded the Federal Cross of Merit (‘Bundesverdienstkreuz’) by the Federal President of Germany, and the Inorganic Mechanisms Award by the Royal Society of Chemistry (London). His hobbies include music, hiking, jogging, cycling and motor-biking. He is the father of two and grandfather of four children.

Affiliations and expertise

University of Erlangen-Nurnberg, Germany; Professor of Inorganic Chemistry, Jagiellonian University in Krakow, Poland

Colin D. Hubbard

After attending Grammar Schools, Colin D. Hubbard read Chemistry at the University of Sheffield in England, earning honours Bachelors, and Doctor of Philosophy degrees, the latter with R.G. Wilkins and S.F.A. Kettle. Postdoctoral Research followed at MIT and Cornell (G.G. Hammes) and the University of California, Berkeley, (J.F. Kirsch). He accepted a position as Assistant Professor of Chemistry at the University of New Hampshire, Durham in 1967, and proceeded to Associate, Full and Emeritus status. In 1994 he joined the group of Rudi van Eldik as Visiting Professor and Research Associate, first at the University of Witten-Herdecke and subsequently at the University of Erlangen-Nürnberg, Germany. From 1998 – 2001 he served as a Research Manager at Unilever Research, Colworth, England. Since 2002 he has been a co-editor for Advances in Inorganic Chemistry (Volumes 54, 61, 65, 68 & 70), and a writer of review articles principally on the application of high hydrostatic pressure in inorganic chemistry reactions for mechanism diagnosis. He has spent Sabbaticals at the University of Kent, Canterbury, England, (E.F. Caldin), the University of Alberta, Edmonton, Canada, (H.B. Dunford), the University of Leicester, England (J. Burgess) and the University of Seville, Spain, (F. Sanchez).

Affiliations and expertise

Oakham, Rutland, UK

Life Sciences

Physical Sciences & Engineering

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