Advanced Applications of Ionic Liquids

1st Edition - November 2, 2022
Imprint: Elsevier
Editors: Jamal Akhter Siddique, Shahid Pervez Ansari, Aftab Aslam Parwaz Khan, Abdullah M. Asiri
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 9 9 9 2 1 - 2
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 8 4 0 0 - 3

Advanced Applications of Ionic Liquids discusses the intersection of nanotechnology with ionic liquids (ILs) and materials, along with opportunities for advanced engineeri… Read more

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Advanced Applications of Ionic Liquids discusses the intersection of nanotechnology with ionic liquids (ILs) and materials, along with opportunities for advanced engineering applications in various research fields. Novel materials at nano scales with ILs creates an upsurge in the thermal and electrochemical constancy of the nano scale particles, making them ideal for industrial applications. The implementation of ILs at nano scale includes an interaction of constituents, which is beneficial for electron transfer reactions. These new composites can be implemented as sensors, electronics, catalysts and photonics. Including ILs in polymer composites enhance electrochemical consistency, govern particle size, upsurge conductivity, reduce toxicity, and more.

This book is a comprehensive reference for researchers working with IL based technologies for environmental and energy applications.

Cover image
Title page
Table of Contents
Copyright
Dedication
List of contributors
About the editors
Preface
Part 1: Catalysis and electrochemistry
Chapter 1. Progressions in ionic liquid-based electrochemical research
Abstract
1.1 Introduction
1.2 Physical properties of ionic liquids
1.3 Electrochemical properties
1.4 Applications of ionic liquids in electrochemistry
1.5 Conclusion
References
Chapter 2. Recapitulation on the separation and purification of biomolecules using ionic liquid-based aqueous biphasic systems
Abstract
2.1 Introduction
2.2 Applications of ionic liquids-based aqueous biphasic system in separation and purification of biomolecules
2.3 Conclusion
Acknowledgments
Nomenclature
References
Chapter 3. Current trends and applications of ionic liquids in electrochemical devices
Abstract
3.1 Introduction
3.2 Ionic liquids in energy storage devices and conversion materials
3.3 Ionic liquid in energy sustainability and CO2 sequestration
3.4 Ionic liquids as a novel electrolyte medium for advanced electrochemical devices
3.5 Ionic liquids’ electrochemical sensing properties
3.6 Applications of room-temperature ionic liquids
3.7 Ammonium, pyrrolidinium, phosphonium, and sulfonium-based ionic liquids and electrochemical properties
3.8 Current and future prospects
3.9 Conclusions
References
Chapter 4. Green chemistry of ionic liquids in surface electrochemistry
Abstract
4.1 Introduction
4.2 Role of ionic liquids in surface electrochemistry
4.3 Conclusions
References
Chapter 5. An evolution in electrochemical and chemical synthesis applications in prospects of ionic liquids
Abstract
5.1 Introduction
5.2 Electrochemical oxidation reactions using room-temperature ionic liquids
5.3 Electrochemical reduction reactions using room-temperature ionic liquid
5.4 Electrochemical polymerization reactions using room-temperature ionic liquids
5.5 Electrochemical partial fluorination using room-temperature ionic liquids
5.6 Other electrochemical reactions using room-temperature ionic liquids
5.7 Conclusions
Abbreviations
References
Chapter 6. Recent changes in the synthesis of ionic liquids based on inorganic nanocomposites and their applications
Abstract
6.1 Introduction
6.2 Synthesis of inorganic nanocomposite materials using ionic liquid
6.3 How organic-inorganic is different from inorganic nanocomposites?
6.4 Recent advancements and advantages of inorganic nanocomposites with ionic liquids
6.5 Current applications and their future perspective
6.6 Reaction mechanism of ionic liquids-based synthesized nanocomposite materials
6.7 Conclusions
Abbreviations
Author contributions
Conflicts of interest
References
Chapter 7. Ionic liquids as green and efficient corrosion-protective materials for metals and alloys
Abstract
7.1 Introduction
7.2 Ionic liquids as corrosion protector for metals and alloy
7.3 Corrosion protection mechanism
7.4 Conclusions and future perspectives
References
Part 2: Separation technology
Chapter 8. Ionic liquids as valuable assets in extraction techniques
Abstract
8.1 Introduction
8.2 Ionic liquids
8.3 Ionic liquids for the extraction of natural products from the plants
8.4 Ionic liquids in extraction of pharmaceuticals from biological and environmental samples
8.5 Ionic liquids for the extraction of contaminants from wastewater
8.6 Ionic liquids for the extraction of soil contaminants and soil organic matter
8.7 Extraction of rare earth metals
8.8 Ionic liquids for the extraction of food contaminants
8.9 Applications of ionic liquids
8.10 Conclusion and future prospective
Acknowledgments
References
Chapter 9. An involvement of ionic liquids and other small molecules as promising corrosion inhibitors in recent advancement of technologies in chemical industries
Abstract
Graphical abstract
9.1 Consequences of corrosion
9.2 Economic effects
9.3 Methods to control corrosion
9.4 Inhibitors
9.5 Anodization
9.6 Cathodic protection
9.7 Structure of electrical double layer
9.8 Influence of temperature on the action of Inhibitors
9.9 Corrosion inhibition—an inevitable arena of research
9.10 Importance of ionic liquids (ILs)
9.11 Corrosion is a costly problem to the world
9.12 Ionic liquids as promising coating agents and inhibitors
9.13 Other corrosion inhibitors
9.14 Conclusion
References
Chapter 10. Role of ionic liquids in bioactive compounds extractions and applications
Abstract
10.1 Introduction
10.2 Bioactive compound extraction from biomass
10.3 Applications of ionic liquids
10.4 Conclusions and future prospects
Acknowledgments
References
Part 3: Sensors and biosensors
Chapter 11. Developments in gas sensing applications before and after ionic liquids
Abstract
11.1 Introduction
11.2 Layout of the chapter
11.3 Electrochemical gas sensors
11.4 Optical gas sensors
11.5 Piezoelectric gas sensors
11.6 Other forms of gas sensors
11.7 Conclusions
References
Chapter 12. Ionic liquids: a tool for CO2 capture and reduced emission
Abstract
12.1 Introduction
12.2 Aqueous amines used in postcombustion
12.3 Ionic liquids as solvents for CO2 capture
12.4 Regeneration of CO2 from ionic liquids
12.5 Designing ionic liquids for CO2 capture
12.6 Conclusions
Acknowledgments
Abbreviations
References
Part 4: Electronic applications
Chapter 13. Applications of ionic liquids in fuel cells and supercapacitors
Abstract
13.1 Introduction
13.2 The bonding in ionic liquids
13.3 Ionic liquids: evolution
13.4 Ionic liquids in fuel cells
13.5 Ionic liquids in supercapacitors
13.6 Conclusion
13.7 Future scope
References
Chapter 14. Role of polymeric ionic liquids in rechargeable batteries
Abstract
14.1 Introduction
14.2 Classification of ionic liquids based on their chemical structure
14.3 Introduction to Li batteries
14.4 Basics of ionic liquids
14.5 Organic and inorganic ionic liquids in electrical storage systems
14.6 Ionic liquid-based polymers electrolytes historical background
14.7 Polymeric ionic liquids for rechargeable lithium-ion batteries
14.8 Li/Na-ion battery electrolyte
14.9 Polymer-electrolytes classification
14.10 Ionic liquid-based gel polymer electrolytes application in lithium batteries
14.11 Low melting point alkaline salts in lithium batteries
14.12 Conclusion
Abbreviations
References
Chapter 15. Progress in optoelectronic applications of ionic liquids
Abstract
15.1 Introduction
15.2 Principle and structure of dye-sensitized solar cell
15.3 Role of ionic liquids as an electrolyte in dye-sensitized solar cells
15.4 Challenges and future prospects
References
Part 5: Miscellaneous applications
Chapter 16. Role of ionic liquids and their future alternative toward protein chemistry
Abstract
16.1 Introduction
16.2 Antibacterial and antitumor activities of ionic liquids
16.3 Protein instability and its influencing factors as well as analytical monitoring
16.4 Effect of alkyl chain length of cations of ionic liquids on the stability of proteins
16.5 Effect of cations and anion of ionic liquids on the stability of proteins
16.6 Effect of hydrophobicity of ionic liquids on the stability of proteins
16.7 Effect of viscosity of ionic liquids on the stability of proteins
16.8 Protein folding in ionic liquids
16.9 Enzymes with ionic liquids
16.10 Application of ionic liquids as biocatalysis
16.11 Ionic liquids do not inactivate enzymes like polar organic solvents
16.12 Increased stability of enzymes in ionic liquids
16.13 Cytotoxicity of ionic liquids
16.14 What are neoteric solvents?
16.15 Role of deep eutectic solvents on protein chemistry
16.16 Conclusion
References
Chapter 17. Ionic liquids in metrological analysis and applications
Abstract
17.1 Introduction
17.2 Wide-ranging ionic liquids
17.3 Protic and aprotic ionic liquids
17.4 Physicochemical properties of ionic liquids defining metrological parameters
17.5 Electrochemical constancy and conductivity
17.6 Ionic liquids-centered devices
17.7 Configuration of ionic liquids in biosensors
17.8 Aspects of ionic liquids as promoters in biodiesel fabrication
17.9 Affinity attributed to ionic liquids in nanomaterials
17.10 The implication of green diluents in space mechanics
17.11 Space energy
17.12 Compost properties
17.13 Life support techniques
17.14 Hypergolic solutions
17.15 Space emollients
17.16 Lunular fluid-glass contract
17.17 Conclusion
References
Chapter 18. Antibacterial properties of silver nanoparticles synthesized in ionic liquids
Abstract
18.1 Introduction
18.2 Silver nanoparticles’ antimicrobial properties and activities
18.3 Discussions and final remarks
Declaration of competing interest
Acknowledgment
References
Part 6: Future applications and studies
Chapter 19. Progressive function of ionic liquids in polymer chemistry
Abstract
19.1 Introduction
19.2 Ionic liquid
19.3 Structure of ionic liquid
19.4 Some important advantages and characteristics of ionic liquid
19.5 Common methods of making ionic liquids
19.6 The function of ionic liquid in polymer
19.7 Polymer-doped ionic liquid
19.8 Polymerization of vinyl monomer in ionic liquid
19.9 Polymerizable ionic liquid
19.10 Adsorbed and covalently linked ionic liquids
19.11 Microwave absorbing ionic liquid polymer
19.12 Ionic liquid-polymer composite
19.13 Summary
Conflict of interests
References
Chapter 20. Potential hazards of ionic liquids: a word of caution
Abstract
20.1 Introduction
20.2 Environmental concerns of ionic liquids
20.3 Factors affecting the toxicity of ionic liquids
20.4 Fate and transfer of ionic liquids to the environment
20.5 Conclusion and future perspectives
Conflict of interest
References
Index

Jamal Akhter Siddique

Jamal Akhter Siddique is an Associate Professor at the School of Basic and Applied Sciences (SBAS), Lingayas University, India. He successfully completed multiple Postdoctoral Research tenures around the globe in renowned universities. He earned his Ph.D on “Physico-chemical studies of biological/biochemical systems” in 2007 from the Department of Chemistry, Aligarh Muslim University. Apart from direct involvement in research he has also contributed his experience to multiple journals as editorial member and worked as a Guest-Editor for a Special Issue entitled “Nanostructure Materials as a Promising Route for Efficient Renewable Energy Production, Storage, and Conversion”, Journal of Nanomaterials; as a Guest-Editor for a Special Issue entitled “Academic Research for Multidiscipline” in International Journal of Science Technology and Society; and as an Assistant-Editor for Journal of Medical Imaging and Health Informatics.

Affiliations and expertise

Assistant Professor, Department of Chemistry Gandhi Faiz-E-Aam College (M.J.P, Rohelkhand University,) Shahjahanpur, India

Shahid Pervez Ansari

Prior to joining AMU, Dr. Ansari worked as researcher at the Umm Al Qura University, Makkah, Kingdom of Saudi Arabia. He co-authored one textbook “Faiz’s Polymer Chemistry: A problem solving approach”. He has contributed several chapters in books published by Elsevier, Springer, Wiley. He has also published several research papers in the field of conducting polymers, nanocomposites, and photocatalysis in journals of high repute. He has been granted one patent in India. Dr. Ansari obtained his PhD in Applied Chemistry in 2011 and presently, he is engaged in teaching of M.Sc (Polymer Science and Technology) and B.Tech. students.

Affiliations and expertise

Assistant Professor, Center of Excellence for Advanced Materials Research and Chemistry Department, King Abdulaziz University

Aftab Aslam Parwaz Khan

Dr. Aftab Aslam Parwaz Khan is presently working as an Assistant Professor in the Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Kingdom of Saudi Arabia. He earned his Ph.D. in Chemistry from Aligarh Muslim University, Aligarh, India in 2011. He has authored 3 books, 15 chapters and more than 130 research papers published in journals of international repute. He is also an Editorial Board Member, as well as a reviewer of many reputed international journals. His research encompasses all aspects of nanomaterials, synthesis, and characterization as well as application in chemical sensing, biosensing environmental remediation of pollution, and drug delivery system for mechanistic and interaction studies using a wide range of spectroscopic techniques and thermodynamic parameters.

Affiliations and expertise

Assistant Professor, Chemistry Department, Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia

Abdullah M. Asiri

Prof. Abdullah M. Asiri is the Head of the Chemistry Department at King Abdulaziz University since October 2009 and he is the founder and the Director of the Center of Excellence for Advanced Materials Research (CEAMR) since 2010 till date. He is the Professor of Organic Photochemistry. His research interest covers color chemistry, synthesis of novel photochromic and thermochromic systems, synthesis of novel coloring matters and dyeing of textiles, materials chemistry, nanochemistry and nanotechnology, polymers and plastics. A major achievement of Prof. Asiri is the discovery of tribochromic compounds, a class of compounds which change from slightly or colorless to deep colored when subjected to small pressure or when grind. This discovery was introduced to the scientific community as a new terminology published by IUPAC in 2000. This discovery was awarded a patent from European Patent office and from UK patent. He is also a member of the Editorial Board of various journals of international repute. He is the Vice- President of Saudi Chemical Society (Western Province Branch). He holds four USA patents, more than 800 Publications in international journals, seven book chapters, and ten books

Affiliations and expertise

Chemistry Department, Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia

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Advanced Applications of Ionic Liquids

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Jamal Akhter Siddique

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