Absorption-Based Post-Combustion Capture of Carbon Dioxide
- 1st Edition - June 20, 2016
- Latest edition
- Editor: Paul Feron
- Language: English
Absorption-Based Post-Combustion Capture of Carbon Dioxide provides a comprehensive and authoritative review of the use of absorbents for post-combustion capture of carbon di… Read more
Absorption-Based Post-Combustion Capture of Carbon Dioxide provides a comprehensive and authoritative review of the use of absorbents for post-combustion capture of carbon dioxide. As fossil fuel-based power generation technologies are likely to remain key in the future, at least in the short- and medium-term, carbon capture and storage will be a critical greenhouse gas reduction technique.
Post-combustion capture involves the removal of carbon dioxide from flue gases after fuel combustion, meaning that carbon dioxide can then be compressed and cooled to form a safely transportable liquid that can be stored underground.
- Provides researchers in academia and industry with an authoritative overview of the amine-based methods for carbon dioxide capture from flue gases and related processes
- Editors and contributors are well known experts in the field
- Presents the first book on this specific topic
Research and development professionals in the power generation industry as well as postgraduate researchers in academia working on carbon capture.
- Related titles
- List of contributors
- Woodhead Publishing Series in Energy
- Part One. Introductory issues
- 1. Introduction
- 1.1. Climate change and greenhouse gas emissions
- 1.2. Factors influencing CO2 emissions
- 1.3. Reducing emissions by CO2 capture and storage
- 1.4. The case for post-combustion CO2 capture
- 1.5. Amine-based processes for post-combustion CO2 capture
- 1.6. Book structure
- 1.7. The future of post-combustion capture
- 2. The fundamentals of post-combustion capture
- 2.1. Introduction
- 2.2. The physics of absorption
- 2.3. The chemistry of absorption
- 2.4. Putting it all together
- 3. Conventional amine scrubbing for CO2 capture
- 3.1. Introduction
- 3.2. History
- 3.3. Basic chemistry and rates
- 3.4. Simple flowsheet
- 3.5. Advanced absorption
- 3.6. Advanced regeneration systems
- 3.7. Energy criteria for amine selection
- 3.8. Absorbent management criteria
- 3.9. Summary of important representative absorption liquids
- 3.10. Capital and energy cost optimization
- 3.11. Conclusions
- 4. Liquid absorbent selection criteria and screening procedures
- 4.1. Introduction
- 4.2. Liquid absorbent selection and criteria
- 4.3. Key absorbent properties
- 4.4. Experimental determination of fundamental chemical properties
- 4.5. Bulk CO2 absorption rates and overall CO2 mass transfer coefficients
- 4.6. Measurement of CO2 equilibrium properties
- 4.7. Fast-track method for the estimation of overall liquid absorbent performance
- 1. Introduction
- Part Two. Capture agents
- 5. Precipitating amino acid solutions
- 5.1. Introduction
- 5.2. Fundamentals of amino acid precipitation
- 5.3. Experimental investigations
- 5.4. Process development and simulations
- 5.5. Conclusions
- 5.6. Research gaps and outlook
- 6. Aminosilicone systems for post-combustion CO2 capture
- 6.1. Introduction
- 6.2. Early work using aminosilicones in CO2 capture
- 6.3. Liquid absorbent-based capture system
- 6.4. Aminosilicone-based phase-change process
- Disclaimer
- 7. Inorganic salt solutions for post-combustion capture
- 7.1. Introduction
- 7.2. Commercial history of the hot potassium carbonate process
- 7.3. Absorption kinetics in K2CO3 systems
- 7.4. Vapor–liquid equilibrium
- 7.5. Solid–liquid equilibrium
- 7.6. Demonstration of potassium carbonate processes for CO2 capture
- 7.7. Conclusions
- 8. Mixed salt solutions for CO2 capture
- 8.1. Introduction
- 8.2. Process description
- 8.3. Process energy requirement
- 8.4. Results of the bench-scale pilot experiments
- 8.5. Process modeling
- 8.6. Summary
- 9. Dual-liquid phase systems
- 9.1. Introduction of dual-liquid phase system
- 9.2. 1,4-Butanediamine (BDA)/N,N-diethylethanolamine (DEEA) dual-liquid phase system
- 9.3. Other dual-liquid systems
- 9.4. Conclusions and outlook
- 10. Enzyme-enhanced CO2 absorption
- 10.1. Introduction
- 10.2. Application of enzymes with reactive absorbents
- 10.3. Impact of enzyme on carbon capture and sequestration process
- 10.4. Concluding remarks
- 10.5. Notation
- 11. Ionic liquids for post-combustion CO2 capture
- 11.1. Introduction
- 11.2. Bench-scale studies using reactive ILs for CO2 absorption
- 11.3. Industrial and pilot studies
- 11.4. Technical and economic hurdles facing ILs
- 11.5. Summary and outlook
- 12. Aqueous ammonia-based post-combustion CO2 capture
- 12.1. Process chemistry
- 12.2. Aqueous NH3-based CO2 capture processes
- 12.3. Performance of aqueous NH3-based post-combustion capture processes
- 12.4. Further advancements in NH3-based processes
- 12.5. Conclusions
- 5. Precipitating amino acid solutions
- Part Three. Process design
- 13. Process modifications for CO2 capture
- 13.1. Introduction
- 13.2. Why process modifications?
- 13.3. Process modifications for investment cost reduction
- 13.4. Process modification for operating cost reduction
- 13.5. Industrial implementation
- 14. Gas–liquid contactors in liquid absorbent-based PCC
- 14.1. Introduction
- 14.2. Contacting principles of gas–liquid devices
- 14.3. Types of gas–liquid contactors
- 14.4. Innovative contactor types
- 14.5. Conclusion
- Notation
- 15. Hybrid amine-based PCC processes, membrane contactors for PCC
- 15.1. Generalities
- 15.2. Membrane contactor modeling
- 15.3. Pilot-plant investigations
- 15.4. Conclusions and outlook
- Nomenclature
- 13. Process modifications for CO2 capture
- Part Four. Solvent degradation, emissions andwaste handling
- 16. Degradation of amine-based solvents
- 16.1. Introduction
- 16.2. Reaction, mechanisms, and products of amine degradation
- 16.3. Measuring amine degradation
- 16.4. Opportunities for controlling amine degradation
- 16.5. Post-combustion CO2 capture plant design and operation aspects
- 16.6. Conclusions and recommendations for future research directions
- 17. Reclaiming of amine-based absorption liquids used in post-combustion capture
- 17.1. Introduction
- 17.2. Stripping, neutralization, and filtration
- 17.3. Thermal reclamation
- 17.4. Ion exchange
- 17.5. Electrodialysis
- 17.6. Economic and environmental considerations
- 17.7. Conclusions
- 18. Assessment of corrosion in amine-based post-combustion capture of carbon dioxide systems
- 18.1. Introduction
- 18.2. Types of corrosion
- 18.3. Experiences from corrosion in amine-based natural gas treatment
- 18.4. Corrosion measurement techniques for amine-based PCC systems
- 18.5. Effect of process conditions on corrosion in amine-based PCC systems
- 18.6. Conclusion
- 18.7. Final comments
- 19. Overview of aerosols in post-combustion CO2 capture
- 19.1. Introduction
- 19.2. Causes and mechanisms
- 19.3. Countermeasures
- 19.4. Future outlook
- 20. Emissions from amine-based post-combustion CO2 capture plants
- 20.1. Introduction
- 20.2. The amine-based post-combustion CO2 capture process
- 20.3. Amine degradation
- 20.4. Atmospheric releases from amine-based post-combustion CO2 capture plants
- 20.5. Atmospheric degradation of post-combustion CO2 capture emissions
- 21. Waste handling in liquid absorbent-based post-combustion capture processes
- 21.1. Introduction
- 21.2. Landfill
- 21.3. Nonhazardous waste landfill
- 21.4. Hazardous waste landfill
- 21.5. Power plant
- 21.6. Suitability of reclaimer waste for firing in coal-fired furnace
- 21.7. Suitability of reclaimer waste for firing in natural gas combined cycle HRSG
- 21.8. Cement manufacturing process
- 21.9. Reclaimer waste suitability in cement kiln
- 21.10. Preprocessing of reclaimer waste for disposal in cement kiln
- 21.11. Selective non-catalytic reduction of NOx removal
- 21.12. Suitability of reclaimer waste as an selective noncatalytic reduction reagent
- 21.13. Wastewater treatment plant
- 21.14. Suitability of reclaimer waste for wastewater treatment plant
- 22. Treatment of flue-gas impurities for liquid absorbent-based post-combustion CO2 capture processes
- 22.1. Introduction
- 22.2. NOX control
- 22.3. Particulate matter control
- 22.4. SOX emission control
- 22.5. Mercury control
- 22.6. Trace elements and other contaminants
- 22.7. Multipollutant control
- 22.8. Conclusion
- 16. Degradation of amine-based solvents
- Part Five. Process integration and operation
- 23. Power plant integration methods for liquid absorbent-based post-combustion CO2 capture
- 23.1. Integrated overall process
- 23.2. Integration approaches
- 23.3. Modeling approach
- 23.4. Power loss of integrated overall process
- 23.5. Power gain by heat integration
- 23.6. Example quantification of an integrated overall process
- 23.7. Summary
- 24. Dynamic operation of liquid absorbent-based post-combustion CO2 capture plants
- 24.1. Introduction
- 24.2. Dynamic operation of post-combustion CO2 capture
- 24.3. Design considerations for dynamic post-combustion CO2 capture operation
- 24.4. Developments in dynamic modeling of post-combustion CO2 capture
- 24.5. Developments in dynamic operation of pilot plants
- 24.6. Concluding remarks and outlook
- 25. Renewable energy integration in liquid absorbent-based post-combustion CO2 capture plants
- 25.1. Introduction
- 25.2. Base case scenario
- 25.3. Model-based analysis of renewable energy integration options
- 25.4. Discussion, conclusions, and future directions
- Nomenclature
- 26. Pilot plant operation for liquid absorption-based post-combustion CO2 capture
- 26.1. Introduction
- 26.2. Purpose of pilot-scale experiments
- 26.3. Design philosophy of pilot-scale facilities
- 26.4. Common measurements and calculations
- 26.5. Challenges of pilot-scale experimentation
- 26.6. Pilot plant experience/results
- 26.7. Conclusions
- 27. Techno-economics of liquid absorbent-based post-combustion CO2 processes
- 27.1. Introduction
- 27.2. Techno-economic evaluation parameters and methodology
- 27.3. Absorption-based process benchmarking and evaluation
- 27.4. Absorption process benchmarking and base case performance
- 27.5. Process potential improvement and cost reduction
- 27.6. Novel absorbents techno-economic evaluation
- 27.7. Conclusions and remarks
- 28. Liquid absorbent-based post-combustion CO2 capture in industrial processes
- 28.1. Introduction
- 28.2. Overview of CO2 emissions from industrial processes
- 28.3. Status of chemical absorption-based post-combustion capture from industrial sources
- 28.4. Utilization of waste heat and heat integration for absorption-based CO2 capture
- 28.5. Economics of chemical absorption-based CO2 capture at industrial processes
- 28.6. Practical limitations and challenges of absorption-based post-combustion capture for industrial processes
- 28.7. Concluding remarks and development outlook
- 29. Commercial liquid absorbent-based PCC processes
- 29.1. Introduction
- 29.2. CO2 separation technological history and background
- 29.3. Vendors/technologies: commercial scale
- 29.4. Vendors/technologies: pilot plant and demonstration scale
- 23. Power plant integration methods for liquid absorbent-based post-combustion CO2 capture
- Index
- Edition: 1
- Latest edition
- Published: June 20, 2016
- Language: English
PF
Paul Feron
With a globally recognised reputation for science excellence in carbon capture technology, Dr Paul Feron leads CSIRO’s post-combustion CO2 capture research program, developing new cost-effective, environmentally-benign technologies to reduce atmospheric emissions from coal-fired power. As one of the pioneers of carbon capture research Dr Feron has been working in the field from the early 1990s, and has made a large contribution to both the technology and international policy of the research.
Affiliations and expertise
CSIRO, AustraliaRead Absorption-Based Post-Combustion Capture of Carbon Dioxide on ScienceDirect