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2D Materials-Based Electrochemical Sensors
1st Edition - June 22, 2023
Editor: Chandra Sekhar Rout
Paperback ISBN:9780443152931
9 7 8 - 0 - 4 4 3 - 1 5 2 9 3 - 1
eBook ISBN:9780443152948
9 7 8 - 0 - 4 4 3 - 1 5 2 9 4 - 8
2D Materials-Based Electrochemical Sensors presents electrochemical and biosensor applications of 2D materials and addresses their fundamental properties, sensing mechanisms and… Read more
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2D Materials-Based Electrochemical Sensors presents electrochemical and biosensor applications of 2D materials and addresses their fundamental properties, sensing mechanisms and fabrication approaches. The book also includes recent theoretical and experimental investigations. Other sections cover the development of sensors and biosensors from the fabrication of two dimensional layered materials to sensing applications and address recent developments and future perspectives on electrochemical sensors based on a wide variety of 2D materials such as graphene, MXene, boron nitride (h-BN), transition metal dichalcogenides (TMDs) and black phosphorous.
This will be a useful resource for researchers and scientists in the areas of analytical chemistry. This book will serve as a reference book both to the beginners and experienced researchers who are pursuing their research in 2D layered materials and their electrochemical sensing applications.
Provides basic working principles and sensing mechanisms of electrochemical sensors based on 2D materials
Addresses recent developments and future perspectives on electrochemical sensors and wearable/flexible sensors based on different 2D materials
Adopts a unique engineering approach of experimental techniques for the fabrication of modern and advanced electrochemical sensors based on 2D material
Analytical chemists, Electrochemists, particularly those working in field of electrochemistry, electrochemical sensors and analytical chemistry, R&D in electrochemical and bio-sensors, Materials Scientists and Engineers with background of 2D materials research
Cover image
Title page
Table of Contents
Copyright
Dedication
Contributors
About the editor
Preface
Acknowledgments
1. Introduction
1. Unique properties of 2D materials for sensing
2. Working principle and sensing mechanism of electrochemical sensors
1. Sensing mechanism in potentiometric sensors
2. Ionophore-free ISE
3. Neutral-ionophore-based ISE
4. Charged ionophore-based ISE
5. The phase-boundary potential model
6. Sensing mechanism in amperometric sensors
7. Working mechanism of dissolved-oxygen sensors
8. Amperometric biosensors
9. Amperometric glucose biosensors
10. First-generation glucose biosensor
11. Second-generation glucose biosensor
12. Working mechanism of non-enzymatic glucose biosensors
13. Oxidation of glucose on platinum electrode at neutral pH (phosphate buffer)
14. Oxidation of glucose on platinum electrode in alkaline medium
15. Conductometric sensors
16. Mechanism for conductometric sensing
17. Conductance measurement
18. Enzyme based conductometric sensors
19. Polymer based conductometric sensors
20. 2D materials based conductometric sensors
21. Conductometric immunosensors
3. Two-dimensional materials (2DMs): classification, preparations, functionalization and fabrication of 2DMs-oriented electrochemical sensors
1. Introduction
2. Classification of 2DMs based on their intrinsic chemistry
3. Strategies for synthesis of two-dimensional materials
4. Functionalization of 2DMs systems
5. Fabrication of 2D heterostructures (2DHs)
6. Defects in vdWHs
7. Characterization of two-dimensional materials
8. 2D materials oriented electrochemical sensors (ES) and their fabrication
9. Special area of 2DMs and van der waals heterostructures
10. Perspectives, challenges, and future directions
4. Importance of 2D materials for electrochemical sensors: theoretical perspectives
1. Introduction
2. Importance of theoretical simulation for sensing application
3. Overview of theoretical methods
4. Insights of theoretical simulations for sensing application
5. Procedure and precautions in simulating 2D material
6. Recent theoretical work on
7. Sensitivity of theoretical work
8. Conclusion
5. Graphene based materials for electrochemical sensing
1. Introduction
2. Types of graphene materials based electrochemical (EC) sensors
3. Summary
6. Transition metal dichalcogenides and hybrids for electrochemical sensing
1. Introduction
2. Packages used
3. Techniques for simulations of 2D material for sensing application
4. Sensing parameters
5. Adsorption configuration
6. Adsorption site
7. Charge transfer
8. Literature
9. Doped/defected TMDs sensors
10. Role of TMDCs in biosensing
11. Hybrid TMDC sensors
12. Energy cut off
13. K-points
14. Exchange correlation functional
15. Dispersion corrections
16. Conclusion and future directions
7. MXene based materials for electrochemical sensing
1. Introduction
2. Fundamental properties of MXenes
3. Synthesis of MXenes
4. Importance of MXene's towards electrochemical sensing applications
5. Electrochemical sensing devices using MXene and its hybrid materials
6. Conclusion and future perspective
8. Two-dimensional hexagonal boron nitride (2D h-BN) and its hybrid structures for electrochemical sensing
1. Introduction
2. Two-dimensional h-BN
3. Electrochemical sensing applications
4. Challenges and future trends
9. 2D black phosphorous based electrochemical sensors
1. Introduction
2. Structural properties, characterizations and synthesis methods
3. Electrochemical sensors based on BP
4. Conclusion and future prospects
10. Recent development on self-powered and portable electrochemical sensors: 2D materials perspective
1. Introduction
2. Unique characteristics and properties of 2D materials
3. Efficient biomarkers for early disease diagnosis
4. 2D material-based sensor for environmental contaminants
5. Conclusion
11. 2D materials-conducting polymers-based hybrids for electrochemical sensing
1. Introduction
2. Structure and properties of different conducting polymers
3. Synthesis of conducting polymers
4. Recent work on electrochemical sensing of gas/biomolecules with conducting polymers
5. Recent work on electrochemical sensing of gas/biomolecules with conducting polymers-2D material hybrids
6. Electrochemical sensing of gas/biomolecules on polymer based ternary compounds
7. Challenges and issues in optimizing gas/bio-molecule sensing performance of conducting polymers-based layered hybrids
8. Conclusions and future scopes
12. Flexible and wearable electrochemical biosensors based on 2D materials
1. Introduction
2. Role of 2D nanomaterials in the electrochemical biosensor
3. Types of biosensor
4. Components of biosensor
5. Electrochemical biosensors
6. Wearable and flexible biosensors technology
7. Conclusion
13. Advanced wearable microfluidic electrochemical sensors based on 2D materials
1. Introduction
2. Parameters of sensor performances
3. Material selection and fabrication techniques
4. Wearable microfluidic sensors based on 2D materials
5. Conclusion
14. Conclusion and future perspectives
Index
No. of pages: 432
Language: English
Published: June 22, 2023
Imprint: Elsevier
Paperback ISBN: 9780443152931
eBook ISBN: 9780443152948
CR
Chandra Sekhar Rout
Dr. Chandra Sekhar Rout is a member of the faculty at the Indian Institute of Technology Bhubaneswar, India. He did his postdoctoral research at National University of Singapore (2008-2009), Purdue University, USA (2010-2012) and UNIST, South Korea (2012-2013). He joined IIT Bhubaneswar in 2013 and he is actively involved in both research and teaching of undergraduate and graduate students there. His research interests include preparation and characterization of two-dimensional layered nanomaterials and their nanocarbon hybrids for chemical sensors and biosensors, supercapacitors and energy storage devices, field emitters and electronic devices. He has authored or co-authored more than 100 research papers in international journals. He has been awarded prestigious Ramanujan Fellowship and Young Scientist award of Department of Science and Technology, Govt. of India in 2013, Young researcher award from Venus International Foundation, India in 2015, IAAM medal 2017 and emerging investigator award 2017. He is an associate editor of “RSC Advances” a journal of Royal Society of Chemistry and “American Journal of Engineering and Applied Sciences” of Science Publications.
Affiliations and expertise
Member of the Faculty, Indian Institute of Technology Bhubaneswar, India