Molecular and Laser Spectroscopy

Advances and Applications: Volume 3

1st Edition - August 21, 2022
Editor: V.P. Gupta
Language: English
Paperback ISBN:
9 7 8 - 0 - 3 2 3 - 9 1 2 4 9 - 5
eBook ISBN:
9 7 8 - 0 - 3 2 3 - 9 1 4 7 0 - 3

Molecular and Laser Spectroscopy, Advances and Applications: Volume 3 gives students and researchers an up-to-date understanding of the fast-developing area of molecular and laser… Read more

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Molecular and Laser Spectroscopy, Advances and Applications: Volume 3 gives students and researchers an up-to-date understanding of the fast-developing area of molecular and laser spectroscopy. This book covers basic principles and advances in several conventional as well as new and upcoming areas of molecular and laser spectroscopy. This third volume is an extension of the two previous volumes of the same title and includes all-new topics.

Each chapter is devoted to a particular fast-growing area of research and fills the gap between elementary texts and advanced material found in research articles. Some of the topics covered include: terahertz spectroscopy and its applications in health care· linear and non-linear vibrational optical activity spectroscopy; cascade laser IR-spectroscopy and frequency comb techniques; step-scan infrared spectroscopy (absorption and emission) for detecting reaction intermediates· surface-enhanced (SERS) and tip-enhanced (TERS) Raman scattering; infrared and Raman micro-spectroscopy; time-resolved linear and non-linear infrared spectroscopy using pico-second and femtosecond lasers.

The spectroscopic techniques have been applied to medical sciences, forensics, security, material science, agriculture, food, chemical, pharmaceutical and petrochemical industries and used to study molecular vibrational dynamics, and hydrogen bonding in ground and excited states.

This book serves as a valuable resource for students, teachers, and beginning researchers engaged in the area of molecular and laser spectroscopy. On account of the wide range of applications, researchers and scientific personnel in many industries will find this book useful for learning about the latest techniques and putting them to practical use.

Cover image
Title page
Table of Contents
Copyright
Dedication
Contributors
Preface
Section 1. Molecular spectroscopy—linear and nonlinear
Chapter 1. Introduction and overview
1. Introduction—significance of spectroscopic studies
2. Spectroscopic techniques—background information
3. Overview of chapters
Chapter 2. Advanced spectral analysis of complex molecular system
1. Introduction
2. Multivariate analyses for spectroscopic data
3. “First-principles” spectral analysis
4. Summary
Chapter 3. Tip-enhanced Raman spectroscopy for optical nanoimaging
1. Introduction
2. Optical spectroscopy and plasmonics
3. Plasmonic enhancement of optical field
4. Experimental techniques for TERS
5. Applications of TERS spectroscopy and microscopy
6. Advanced applications of TERS microscopy
7. Summary and outlook
Chapter 4. Coherent chiroptical Raman spectroscopy
1. Introduction
2. Overview of chiral-sensitive techniques
3. Coherent anti-stokes Raman scattering-Raman optical activity
4. Theory of CARS-ROA spectroscopy
5. Polarization geometries for CARS-ROA
6. Heterodyne-detected CARS-ROA
7. Experimental realization of CARS-ROA
8. Applications of CARS-ROA
9. Conclusions and future perspectives
Chapter 5. Miniaturized near-infrared spectroscopy in current analytical chemistry: from natural products to forensics
1. General introduction
2. Practical significance and application potential of portable and handheld NIR spectrometers
3. Principles of the instrumentation
4. Applications
5. Current development trends and the prospects for the future
6. Summary
Chapter 6. Near-infrared spectroscopy for medical, food and forage applications
1. Introduction
2. Medical applications
3. Near-infrared spectroscopy of agricultural products
Chapter 7. Thin-layer chromatography–surface-enhanced Raman scattering
1. Introduction
2. Surface-enhanced Raman scattering
3. Combining TLC with SERS
4. Analysis of pharmaceuticals
5. Dietary and herbal supplements
6. Food quality control
7. Environmental applications: detection of pesticides, aromatic pollutants, and polycyclic aromatic hydrocarbons
8. Forensic applications, dyes, and artist dyestuffs
9. Conclusions
Section 2. Advanced instrumentation and applications
Chapter 8. Raman-integrated optical photothermal infrared microscopy: technology and applications
1. Introduction
2. Methods and instruments
3. Biomedical applications
4. Chemical and material applications
5. Perspectives
Chapter 9. Optical photothermal infrared spectroscopic applications in microplastics—comparison with Fourier transform infrared and Raman spectroscopy
1. Introduction
2. Experimental considerations
3. Spectra of transparent plastic
4. High wavenumber range and spectral libraries for identification
5. Spectra of white and pigmented plastic
6. Thickness and shape dependence
7. Polarized Raman and infrared spectra
8. Microplastic detection in bladder tumors by Raman spectroscopic imaging
9. Summary and conclusions
Chapter 10. Plasmonic nanosensors and their spectroscopic applications—current trends and future perspectives
1. Introduction
2. Theoretical considerations
3. Synthesis and fabrication of plasmonic nanostructures
4. Plasmonic NPs
5. Methods of plasmonic sensing
6. Advances in sensing techniques
7. Applications
8. Summary and outlook
Section 3. Time-resolved and ultrafast spectroscopy
Chapter 11. Applications of SERS in biochemical and medical analysis
1. Introduction
2. Surface-enhanced Raman scattering
3. Label-free direct (bio)medical SERS analysis
4. Indirect SERS analysis
5. Conclusions and assumed directions in future developments of SERS sensors
Chapter 12. IR spectroscopy and imaging using polarized light with QCLs: instrumentation and applications
1. Introduction
2. Theoretical background
3. Instrumentation
4. Data acquisition
5. Applications
6. Summary
7. Future perspectives
Chapter 13. Terahertz spectroscopy of biological molecules in solid, liquid, and gaseous states
1. Introduction
2. Basics of light–matter interactions at THz frequencies
3. THz spectroscopy techniques for biology and medicine
4. THz spectroscopy of bound water
5. THz spectroscopy of lyophilized samples
Section 4. Biochemical and medical applications
Chapter 14. Step-scan FTIR techniques for investigations of spectra and dynamics of transient species in gaseous chemical reactions
1. Introduction
2. Fundamental theory in step-scan FTIR instruments
3. Instrumentation
4. Reaction dynamics
5. Absorption spectra of transient species
6. Future perspectives
Chapter 15. Quantum cascade lasers and their applications to spectral and kinetic investigations of reactive gaseous intermediate species
1. Introduction
2. Fundamental theories of QCL
3. Instrumentation
4. High-resolution spectra
5. Kinetic investigations
6. Future perspectives
Chapter 16. Real-time tracking of the molecular structural dynamics of photochemical pathways using vibrational spectroscopy techniques
1. Introduction
2. Basic principles and instrumentation
3. Applications of vibrational spectroscopy in the visualization of molecular structural dynamics of photochemical pathways
4. Summary and future perspective
Chapter 17. Application of ultrafast infrared spectroscopy in elucidating electronic processes in materials
1. Introduction
2. Principle and experimental technique
3. Applications
4. Summary and perspective
Index

Life Sciences

Physical Sciences & Engineering

Social Sciences & Humanities

Health

Molecular and Laser Spectroscopy

Advances and Applications: Volume 3

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V.P. Gupta